Investigation of complex formation between poly(N-vinyl imidazole) and various metal ions using the molar ratio method

The complex formation of poly(N-vinyl imidazole) (PVIm) with various metal ions was studied. UV-vis spectroscopy was employed to study the interaction of PVIm and metal ions in aqueous solution. Formation constants of PVIm-metal complexes were calculated by applying a "mole ratio" method....

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Published in:	Colloid and polymer science Vol. 277; no. 6; pp. 570 - 573
Main Authors:	PEKEL, N, GÜVEN, O
Format:	Journal Article
Language:	English
Published:	Berlin Springer 01-06-1999 Springer Nature B.V
Subjects:	Applied sciences Aqueous solutions Complex formation Complex systems Constants Exact sciences and technology Imidazole Ions Mathematical analysis Metal ions Metals Organic polymers Physicochemistry of polymers Properties and characterization Solution and gel properties Transition metals Stoichiometry Binding capacity Complexing agent Imidazole(vinyl) polymer Metal ion Stability constant Transition metal Complexes Aqueous solution Experimental study
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Abstract	The complex formation of poly(N-vinyl imidazole) (PVIm) with various metal ions was studied. UV-vis spectroscopy was employed to study the interaction of PVIm and metal ions in aqueous solution. Formation constants of PVIm-metal complexes were calculated by applying a "mole ratio" method. The stoichiometric ratios between polymer and metal ions were found to be4. The stability constants for the complexes of PVIm with bivalent transition metal ions were in agreement with the Irving-William series. The biggest formation constant was found for the PVIm-Cu^sup 2+^ complex system.[PUBLICATION ABSTRACT]
AbstractList	The complex formation of poly(N-vinyl imidazole) (PVIm) with various metal ions was studied. UV-vis spectroscopy was employed to study the interaction of PVIm and metal ions in aqueous solution. Formation constants of PVIm-metal complexes were calculated by applying a 'mole ratio' method. The stoichiometric ratios between polymer and metal ions were found to be4. The stability constants for the complexes of PVIm with bivalent transition metal ions were in agreement with the Irving-William series. The biggest formation constant was found for the PVIm-Cu complex system. The complex formation of poly(N-vinyl imidazole) (PVIm) with various metal ions was studied. UV-vis spectroscopy was employed to study the interaction of PVIm and metal ions in aqueous solution. Formation constants of PVIm-metal complexes were calculated by applying a "mole ratio" method. The stoichiometric ratios between polymer and metal ions were found to be4. The stability constants for the complexes of PVIm with bivalent transition metal ions were in agreement with the Irving-William series. The biggest formation constant was found for the PVIm-Cu^sup 2+^ complex system.[PUBLICATION ABSTRACT]
Author	PEKEL, N GÜVEN, O
Author_xml	– sequence: 1 givenname: N surname: PEKEL fullname: PEKEL, N organization: Department of Chemistry, Hacettepe University, 06532 Beytepe, Ankara, Turkey – sequence: 2 givenname: O surname: GÜVEN fullname: GÜVEN, O organization: Department of Chemistry, Hacettepe University, 06532 Beytepe, Ankara, Turkey
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SubjectTerms	Applied sciences Aqueous solutions Complex formation Complex systems Constants Exact sciences and technology Imidazole Ions Mathematical analysis Metal ions Metals Organic polymers Physicochemistry of polymers Properties and characterization Solution and gel properties Transition metals
Title	Investigation of complex formation between poly(N-vinyl imidazole) and various metal ions using the molar ratio method
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