Surprising Differences of Alkane C‐H Activation Catalyzed by Ruthenium Nanoparticles: Complex Surface‐Substrate Recognition?

The activation of C−H bonds of alkanes remains a major challenge for chemistry. In a series of deuteration experiments with D2 in contact with bis‐(diphenylphosphino) butane (dppb) stabilized ruthenium nanoparticles (liquid substrates, 60 °C, 6 bar D2) we have observed a surprisingly large reactivit...

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Bibliographic Details
Published in:	ChemCatChem Vol. 10; no. 19; pp. 4243 - 4247
Main Authors:	Rothermel, Niels, Bouzouita, Donia, Röther, Tobias, de Rosal, Iker, Tricard, Simon, Poteau, Romuald, Gutmann, Torsten, Chaudret, Bruno, Limbach, Hans‐Heinrich, Buntkowsky, Gerd
Format:	Journal Article
Language:	English
Published:	Weinheim Wiley Subscription Services, Inc 09-10-2018 Wiley
Subjects:	Activation Alkane C−H activation Alkanes Catalysis Chemical Sciences Cyclohexane Density functional calculations Deuteration Deuterium isotopic labeling Enthalpy Nanoparticles or physical chemistry Organic chemistry Ruthenium Substrates Theoretical and
Online Access:	Get full text
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