The Remote Activation of Chemical Bonds via Metal Coordination

The Remote Activation of Chemical Bonds via Metal Coordination

The activation of chemical bonds to cleavage by mild metal nucleophiles can be achieved by precoordination of a transition metal fragment to a site remote from the bond in question. The following bonds have been activated in this manner by η6‐coordination to an internal arene ring: CC in biphenylen...

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Bibliographic Details
Published in:Advanced synthesis & catalysis Vol. 345; no. 9-10; pp. 1053 - 1060
Main Authors: Oh, Moonhyun, Yu, Kunquan, Li, Huazhi, Watson, Eric J., Carpenter, Gene B., Sweigart, Dwight A.
Format: Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag 01-09-2003
WILEY‐VCH Verlag
Subjects:
bond activation
heterocycles
homogeneous catalysis
hydrodesulfurization
manganese
metallocycles
Online Access:Get full text
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Summary:The activation of chemical bonds to cleavage by mild metal nucleophiles can be achieved by precoordination of a transition metal fragment to a site remote from the bond in question. The following bonds have been activated in this manner by η6‐coordination to an internal arene ring: CC in biphenylene, CS in benzothiophene and dibenzothiophene, CSe in benzoselenophene, CO in benzofuran, and NH in indole.
Bibliography:istex:FFDF0686FEABF9F4CE27DE910C4C46295DA0A603
ArticleID:ADSC200303080
ark:/67375/WNG-SWZ0B3WH-L
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.200303080