Reversible intercalation of ammonia molecules into a layered double hydroxide structure without exchanging nitrate counter-ions

A zinc/aluminum LDH was precipitated with recycled ammonia from a chemical vapor deposition reaction. The LDH presented a crystalline phase with basal distance of 8.9 Å, typical for nitrate-containing LDHs, and another phase with a basal distance of 13.9 Å. Thermal treatment at 150 °C eliminated the...

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Bibliographic Details
Published in:	Journal of solid state chemistry Vol. 183; no. 10; pp. 2324 - 2328
Main Authors:	Carbajal Arizaga, Gregorio Guadalupe, Wypych, Fernando, Castillón Barraza, Felipe, Contreras Lopez, Oscar Edel
Format:	Journal Article
Language:	English
Published:	Amsterdam Elsevier Inc 01-10-2010 Elsevier
Subjects:	ACETONE ALUMINIUM COMPOUNDS AMMONIA CHARGED PARTICLES CHEMICAL COATING CHEMICAL VAPOR DEPOSITION Chemical vapor deposition (including plasma-enhanced cvd, mocvd, etc.) CLATHRATES Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science; rheology Crystal structure DEPOSITION Electron density of states and band structure of crystalline solids Electron states Exact sciences and technology Exchanging EXPANSION Fullerenes and related materials; intercalation compounds HEAT TREATMENTS HEATING HYDRIDES HYDROGEN COMPOUNDS Hydroxide HYDROXIDES INFRARED SPECTRA Intercalation IONS KETONES Lattice dynamics Layered MATERIALS SCIENCE Methods of deposition of films and coatings; film growth and epitaxy NITRATES NITROGEN COMPOUNDS NITROGEN HYDRIDES ORGANIC COMPOUNDS OXYGEN COMPOUNDS PH VALUE Phase diagrams and microstructures developed by solidification and solid-solid phase transformations Phonons and vibrations in crystal lattices Physics Precipitation Recycled SPECTRA STIRRING SURFACE COATING TEMPERATURE RANGE TEMPERATURE RANGE 0400-1000 K Zinc ZINC COMPOUNDS Layered Ammonia Hydroxide Intercalation Crystalline phase Fourier transform spectroscopy pH value Hydroxides Phase composition Stirring Aluminium Nitrates Intercalation compounds Heat treatments Zinc CVD Precipitation Lamellar structure Anhydrous compound Calcium nitride Vibrational modes Fourier-transformed infrared spectrometry Double layers Acetone
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