Critical behavior of hydrogen in Nb/Ta superlattices

An in situ X-ray scattering study showing the existence of the lattice-gas- lattice-liquid phase transition for H dissolved in Nb /Ta superlattices is presented, where it is found that critical fluctuations with wavelengths shorter than the superlattice periodicity are suppressed. Since fluctuations...

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Published in:Physical review letters Vol. 59; no. 11; pp. 1224 - 1227
Main Authors: MICELI, P. F, ZABEL, H
Format: Journal Article
Language:English
Published: Ridge, NY American Physical Society 14-09-1987
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Summary:An in situ X-ray scattering study showing the existence of the lattice-gas- lattice-liquid phase transition for H dissolved in Nb /Ta superlattices is presented, where it is found that critical fluctuations with wavelengths shorter than the superlattice periodicity are suppressed. Since fluctuations of only long wavelengths develop, phase separation into gas and liquid phases cannot occur. These results demonstrate that the coherent phase transition is sensitive to the microscopic properties of the H-H interaction. (Author)
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ISSN:0031-9007
1079-7114
DOI:10.1103/PhysRevLett.59.1224