Preparation of hollow glass microspheres from sol–gel derived glass for application in hydrogen gas storage

• Published in: Journal of non-crystalline solids Vol. 352; no. 6; pp. 626 - 631
• Main Authors: Schmitt, M.L., Shelby, J.E., Hall, M.M.
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Amsterdam Elsevier B.V 15-05-2006; Elsevier
• Subjects: Aerogel and solution chemistry; Alternative fuels. Production and utilization; Applied sciences; Cross-disciplinary physics: materials science; rheology; Energy; Exact sciences and technology; Fuels; Glasses; Glasses (including metallic glasses); Hydrogen; Hydrogen in glass; Materials science; Physics; Processing; Sol–gel; Specific materials; Hydrogen in glass; 06.60.Ei; Glasses; Sol–gel; 61.43.Fs; Aerogel and solution chemistry; Processing; Differential scanning calorimetry; Hydrogen storage; Thermogravimetry; Heat treatments; Borosilicate glass; Aerogels; Microspheres; Hollow shape; Preparation; Spherical particle; Xerogel; 61.43.Fs: 06.60.Ei; Sol-gel process; Hydrogen in glass; Glasses; Processing; Sol-gel; Aerogel and solution chemistry
• ISSN: 0022-3093; 1873-4812
• DOI: 10.1016/j.jnoncrysol.2005.11.057

Hollow glass microspheres are produced from a sol–gel derived sodium borosilicate glass with a composition suitable for photo-enhanced hydrogen diffusion for application in hydrogen storage. The heat treated xerogel is suspended and doped with iron sulfate or iron chloride to introduce the transition metal and blowing agent and is spray dried. The spray dried granules are then flame sprayed in an oxy-propane flame to produce glass microspheres.
N-Hexadecyltrimethylammonium chloride is added to selected suspensions prior to spray drying to produce hollow spray dried particles, which shows promise for improved HGMS. Current spray drying parameters are given, although adjustments are still being made to improve results. Agglomeration of the spray dried granules causes reduced flowability of the granules and decreases the efficiency and quality of the HGMS production. Although microspheres can readily be made of correct composition, many contain numerous small bubbles rather than a single, hollow cavity.