Vanadium nitride supercapacitors: Effect of Processing Parameters on electrochemical charge storage behavior
Nanoparticulate transition metal nitride based supercapacitor electrodes have recently gained considerable attention as high capacity energy storage materials. In particular, vanadium nitride has been shown to be an excellent pseudocapacitor on account of surface reactions occurring at an oxide exo-...
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Published in: | Electrochimica acta Vol. 207; pp. 37 - 47 |
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20-07-2016
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Abstract | Nanoparticulate transition metal nitride based supercapacitor electrodes have recently gained considerable attention as high capacity energy storage materials. In particular, vanadium nitride has been shown to be an excellent pseudocapacitor on account of surface reactions occurring at an oxide exo-shell. However, there is limited understanding into the exact nature of charge storage behavior and its dependence on synthesis and processing route. In the present work, we explore the effect of materials processing and electrode properties on capacitive charge storage in vanadium nitride based supercapacitor electrodes. Dependence of capacitance on particle properties and electrode properties are evaluated and reported here-in. |
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AbstractList | Nanoparticulate transition metal nitride based supercapacitor electrodes have recently gained considerable attention as high capacity energy storage materials. In particular, vanadium nitride has been shown to be an excellent pseudocapacitor on account of surface reactions occurring at an oxide exo-shell. However, there is limited understanding into the exact nature of charge storage behavior and its dependence on synthesis and processing route. In the present work, we explore the effect of materials processing and electrode properties on capacitive charge storage in vanadium nitride based supercapacitor electrodes. Dependence of capacitance on particle properties and electrode properties are evaluated and reported here-in. |
Author | Kadakia, Karan Okoli, Christopher Patel, Prasad Kumta, Prashant N. Hanumantha, Prashanth Jampani Datta, Moni Kanchan |
Author_xml | – sequence: 1 givenname: Prashanth Jampani surname: Hanumantha fullname: Hanumantha, Prashanth Jampani organization: Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, PA 15261, USA – sequence: 2 givenname: Moni Kanchan surname: Datta fullname: Datta, Moni Kanchan organization: Department of Bioengineering, University of Pittsburgh, Pittsburgh, PA 15261, USA – sequence: 3 givenname: Karan surname: Kadakia fullname: Kadakia, Karan organization: Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, PA 15261, USA – sequence: 4 givenname: Christopher surname: Okoli fullname: Okoli, Christopher organization: Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, PA 15261, USA – sequence: 5 givenname: Prasad surname: Patel fullname: Patel, Prasad organization: Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, PA 15261, USA – sequence: 6 givenname: Prashant N. surname: Kumta fullname: Kumta, Prashant N. email: pkumta@gmail.com organization: Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, PA 15261, USA |
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