Vanadium nitride supercapacitors: Effect of Processing Parameters on electrochemical charge storage behavior

Nanoparticulate transition metal nitride based supercapacitor electrodes have recently gained considerable attention as high capacity energy storage materials. In particular, vanadium nitride has been shown to be an excellent pseudocapacitor on account of surface reactions occurring at an oxide exo-...

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Published in:Electrochimica acta Vol. 207; pp. 37 - 47
Main Authors: Hanumantha, Prashanth Jampani, Datta, Moni Kanchan, Kadakia, Karan, Okoli, Christopher, Patel, Prasad, Kumta, Prashant N.
Format: Journal Article
Language:English
Published: Elsevier Ltd 20-07-2016
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Abstract Nanoparticulate transition metal nitride based supercapacitor electrodes have recently gained considerable attention as high capacity energy storage materials. In particular, vanadium nitride has been shown to be an excellent pseudocapacitor on account of surface reactions occurring at an oxide exo-shell. However, there is limited understanding into the exact nature of charge storage behavior and its dependence on synthesis and processing route. In the present work, we explore the effect of materials processing and electrode properties on capacitive charge storage in vanadium nitride based supercapacitor electrodes. Dependence of capacitance on particle properties and electrode properties are evaluated and reported here-in.
AbstractList Nanoparticulate transition metal nitride based supercapacitor electrodes have recently gained considerable attention as high capacity energy storage materials. In particular, vanadium nitride has been shown to be an excellent pseudocapacitor on account of surface reactions occurring at an oxide exo-shell. However, there is limited understanding into the exact nature of charge storage behavior and its dependence on synthesis and processing route. In the present work, we explore the effect of materials processing and electrode properties on capacitive charge storage in vanadium nitride based supercapacitor electrodes. Dependence of capacitance on particle properties and electrode properties are evaluated and reported here-in.
Author Kadakia, Karan
Okoli, Christopher
Patel, Prasad
Kumta, Prashant N.
Hanumantha, Prashanth Jampani
Datta, Moni Kanchan
Author_xml – sequence: 1
  givenname: Prashanth Jampani
  surname: Hanumantha
  fullname: Hanumantha, Prashanth Jampani
  organization: Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, PA 15261, USA
– sequence: 2
  givenname: Moni Kanchan
  surname: Datta
  fullname: Datta, Moni Kanchan
  organization: Department of Bioengineering, University of Pittsburgh, Pittsburgh, PA 15261, USA
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  givenname: Karan
  surname: Kadakia
  fullname: Kadakia, Karan
  organization: Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, PA 15261, USA
– sequence: 4
  givenname: Christopher
  surname: Okoli
  fullname: Okoli, Christopher
  organization: Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, PA 15261, USA
– sequence: 5
  givenname: Prasad
  surname: Patel
  fullname: Patel, Prasad
  organization: Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, PA 15261, USA
– sequence: 6
  givenname: Prashant N.
  surname: Kumta
  fullname: Kumta, Prashant N.
  email: pkumta@gmail.com
  organization: Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, PA 15261, USA
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Snippet Nanoparticulate transition metal nitride based supercapacitor electrodes have recently gained considerable attention as high capacity energy storage materials....
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SubjectTerms Charge
Electrodes
Materials processing
Nitrides
Oxides
Supercapacitor
Supercapacitors
Surface reactions
Transition metals
Vanadium
Vanadium nitride
Title Vanadium nitride supercapacitors: Effect of Processing Parameters on electrochemical charge storage behavior
URI https://dx.doi.org/10.1016/j.electacta.2016.04.058
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