Amino-Acid-Modified-Cashew Gum Flocculant: Synthesis, Characterization, and Application

Amphoteric poly( O -methacryloyl- l -serine)-grafted cashew gum (CG- g -P(SerMA)) flocculant was obtained with highly efficient in separation and sequential recovery of kaolin particles from aqueous suspension. The highest flocculation efficiency was achieved with a flocculant synthesized using an O...

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Published in:	Journal of polymers and the environment Vol. 27; no. 7; pp. 1465 - 1474
Main Authors:	Klein, Jalma Maria, de Lima, Vanessa Silva, Haack, Michele, da Feira, José Manoel Couto, de Camargo Forte, Maria Madalena
Format:	Journal Article
Language:	English
Published:	New York Springer US 01-07-2019 Springer Nature B.V
Subjects:	Amino acids Amino groups Anacardiaceae Chemistry Chemistry and Materials Science COPOLYMERS Efficiency Electrostatic properties ELECTROSTATICS Environmental Chemistry Environmental Engineering/Biotechnology Flocculants FLOCCULATION GUMS Impurities Industrial Chemistry/Chemical Engineering INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY KAOLIN L-Serine Materials Science Original Paper Polymer Sciences SERINE SUSPENSIONS SYNTHESIS WASTE WATER Wastewater Cashew gum Amino acid Graft copolymer Flocculation Amphoteric polymers
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Abstract	Amphoteric poly( O -methacryloyl- l -serine)-grafted cashew gum (CG- g -P(SerMA)) flocculant was obtained with highly efficient in separation and sequential recovery of kaolin particles from aqueous suspension. The highest flocculation efficiency was achieved with a flocculant synthesized using an O -methacryloyl- l -serine:cashew gum molar ratio of 3:1. The CG- g -P(SerMA) at a dosage of 3.0 mg L −1 resulted in a flocculation efficiency of more than 90% within 20 min for kaolin suspension. The efficiency, in standard experiments, the flocculant CG- g -P(SerMA) was superior to cashew gum and polyacrylamide-based commercial flocculants. The flocculation mechanism involves electrostatic interactions between the negatively charged surface of the kaolin and the protonated amino groups of the flocculant under acidic conditions. These results provide new opportunities and challenges for understanding and improving the removal of impurities present in water and wastewater.
AbstractList	Amphoteric poly(O-methacryloyl-L-serine)-grafted cashew gum (CG-g-P(SerMA)) flocculant was obtained with highly efficient in separation and sequential recovery of kaolin particles from aqueous suspension. The highest flocculation efficiency was achieved with a flocculant synthesized using an O-methacryloyl-L-serine:cashew gum molar ratio of 3:1. The CG-g-P(SerMA) at a dosage of 3.0 mg L{sup −1} resulted in a flocculation efficiency of more than 90% within 20 min for kaolin suspension. The efficiency, in standard experiments, the flocculant CG-g-P(SerMA) was superior to cashew gum and polyacrylamide-based commercial flocculants. The flocculation mechanism involves electrostatic interactions between the negatively charged surface of the kaolin and the protonated amino groups of the flocculant under acidic conditions. These results provide new opportunities and challenges for understanding and improving the removal of impurities present in water and wastewater. Amphoteric poly(O-methacryloyl-l-serine)-grafted cashew gum (CG-g-P(SerMA)) flocculant was obtained with highly efficient in separation and sequential recovery of kaolin particles from aqueous suspension. The highest flocculation efficiency was achieved with a flocculant synthesized using an O-methacryloyl-l-serine:cashew gum molar ratio of 3:1. The CG-g-P(SerMA) at a dosage of 3.0 mg L−1 resulted in a flocculation efficiency of more than 90% within 20 min for kaolin suspension. The efficiency, in standard experiments, the flocculant CG-g-P(SerMA) was superior to cashew gum and polyacrylamide-based commercial flocculants. The flocculation mechanism involves electrostatic interactions between the negatively charged surface of the kaolin and the protonated amino groups of the flocculant under acidic conditions. These results provide new opportunities and challenges for understanding and improving the removal of impurities present in water and wastewater. Amphoteric poly( O -methacryloyl- l -serine)-grafted cashew gum (CG- g -P(SerMA)) flocculant was obtained with highly efficient in separation and sequential recovery of kaolin particles from aqueous suspension. The highest flocculation efficiency was achieved with a flocculant synthesized using an O -methacryloyl- l -serine:cashew gum molar ratio of 3:1. The CG- g -P(SerMA) at a dosage of 3.0 mg L −1 resulted in a flocculation efficiency of more than 90% within 20 min for kaolin suspension. The efficiency, in standard experiments, the flocculant CG- g -P(SerMA) was superior to cashew gum and polyacrylamide-based commercial flocculants. The flocculation mechanism involves electrostatic interactions between the negatively charged surface of the kaolin and the protonated amino groups of the flocculant under acidic conditions. These results provide new opportunities and challenges for understanding and improving the removal of impurities present in water and wastewater.
Author	de Lima, Vanessa Silva da Feira, José Manoel Couto Klein, Jalma Maria Haack, Michele de Camargo Forte, Maria Madalena
Author_xml	– sequence: 1 givenname: Jalma Maria orcidid: 0000-0003-1417-9710 surname: Klein fullname: Klein, Jalma Maria email: jalma.klein@ufrgs.br organization: Laboratório de Materiais Poliméricos, Departamento de Materiais, Escola de Engenharia, Universidade Federal do Rio Grande do Sul (UFRGS) – sequence: 2 givenname: Vanessa Silva surname: de Lima fullname: de Lima, Vanessa Silva organization: Laboratório de Materiais Poliméricos, Departamento de Materiais, Escola de Engenharia, Universidade Federal do Rio Grande do Sul (UFRGS) – sequence: 3 givenname: Michele surname: Haack fullname: Haack, Michele organization: Laboratório de Materiais Poliméricos, Departamento de Materiais, Escola de Engenharia, Universidade Federal do Rio Grande do Sul (UFRGS) – sequence: 4 givenname: José Manoel Couto surname: da Feira fullname: da Feira, José Manoel Couto organization: Laboratório de Materiais Poliméricos, Departamento de Materiais, Escola de Engenharia, Universidade Federal do Rio Grande do Sul (UFRGS) – sequence: 5 givenname: Maria Madalena surname: de Camargo Forte fullname: de Camargo Forte, Maria Madalena organization: Laboratório de Materiais Poliméricos, Departamento de Materiais, Escola de Engenharia, Universidade Federal do Rio Grande do Sul (UFRGS)
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Keywords	Cashew gum Amino acid Graft copolymer Flocculation Amphoteric polymers
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Snippet	Amphoteric poly( O -methacryloyl- l -serine)-grafted cashew gum (CG- g -P(SerMA)) flocculant was obtained with highly efficient in separation and sequential... Amphoteric poly(O-methacryloyl-l-serine)-grafted cashew gum (CG-g-P(SerMA)) flocculant was obtained with highly efficient in separation and sequential recovery... Amphoteric poly(O-methacryloyl-L-serine)-grafted cashew gum (CG-g-P(SerMA)) flocculant was obtained with highly efficient in separation and sequential recovery...
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StartPage	1465
SubjectTerms	Amino acids Amino groups Anacardiaceae Chemistry Chemistry and Materials Science COPOLYMERS Efficiency Electrostatic properties ELECTROSTATICS Environmental Chemistry Environmental Engineering/Biotechnology Flocculants FLOCCULATION GUMS Impurities Industrial Chemistry/Chemical Engineering INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY KAOLIN L-Serine Materials Science Original Paper Polymer Sciences SERINE SUSPENSIONS SYNTHESIS WASTE WATER Wastewater
Title	Amino-Acid-Modified-Cashew Gum Flocculant: Synthesis, Characterization, and Application
URI	https://link.springer.com/article/10.1007/s10924-019-01440-z https://www.proquest.com/docview/2210304912 https://www.osti.gov/biblio/22977111
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