Solid-liquid equilibria in the ThO2 –ZrO2 system: An experimental study
In this work, solid-liquid equilibria of the pseudo-binary system ThO2-ZrO2 are investigated. A series of different molar ratios (80:20, 60:40, 40:60, and 20:80 ThO2:ZrO2) of ThO2 and ZrO2 were synthesised at JRC-Karlsruhe using an external sol-gel method. The XRD data of samples sintered at 1650 °C...
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| Published in: | Journal of nuclear materials Vol. 521; pp. 99 - 108 |
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| Main Authors: | , , , , , , |
| Format: | Journal Article |
| Language: | English |
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01-08-2019
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| Abstract | In this work, solid-liquid equilibria of the pseudo-binary system ThO2-ZrO2 are investigated. A series of different molar ratios (80:20, 60:40, 40:60, and 20:80 ThO2:ZrO2) of ThO2 and ZrO2 were synthesised at JRC-Karlsruhe using an external sol-gel method. The XRD data of samples sintered at 1650 °C show two-phase behaviour throughout the range of compositions with small solubility (<5%) of ZrO2 in ThO2 and limited solubility of ThO2 in ZrO2. These results were supported with Raman spectroscopy and SEM measurements to have a better understanding of the distribution of the components within each other. Solid/liquid equilibria in the ThO2-ZrO2 system are investigated here for the first time by laser heating coupled with fast optical thermometry under a controlled atmosphere. A minimum solidus point exists in this system for intermediate compositions (close to Th0.4Zr0.6O2) at approximately 2750 K. These results contribute to assessing the thermal stability of the fuel-cladding system in a ThO2-fuel based reactor. Moreover, when compared with other similar mixed oxide systems, the present data confirm the essential role played by oxygen chemistry in the definition of the studied phase boundaries. |
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| AbstractList | In this work, solid-liquid equilibria of the pseudo-binary system ThO2-ZrO2 are investigated. A series of different molar ratios (80:20, 60:40, 40:60, and 20:80 ThO2:ZrO2) of ThO2 and ZrO2 were synthesised at JRC-Karlsruhe using an external sol-gel method. The XRD data of samples sintered at 1650 °C show two-phase behaviour throughout the range of compositions with small solubility (<5%) of ZrO2 in ThO2 and limited solubility of ThO2 in ZrO2. These results were supported with Raman spectroscopy and SEM measurements to have a better understanding of the distribution of the components within each other. Solid/liquid equilibria in the ThO2-ZrO2 system are investigated here for the first time by laser heating coupled with fast optical thermometry under a controlled atmosphere. A minimum solidus point exists in this system for intermediate compositions (close to Th0.4Zr0.6O2) at approximately 2750 K. These results contribute to assessing the thermal stability of the fuel-cladding system in a ThO2-fuel based reactor. Moreover, when compared with other similar mixed oxide systems, the present data confirm the essential role played by oxygen chemistry in the definition of the studied phase boundaries. |
| Author | Vigier, Jean-François Seibert, Alice Mastromarino, Sara Ciccioli, Andrea Manara, Dario Hashem, Emtethal Naji, Mohamed |
| Author_xml | – sequence: 1 givenname: Emtethal surname: Hashem fullname: Hashem, Emtethal organization: European Commission, Joint Research Centre (JRC), Directorate of Nuclear Safety and Security, P.O. Box 2340, D-76125, Karlsruhe, Germany – sequence: 2 givenname: Alice surname: Seibert fullname: Seibert, Alice organization: European Commission, Joint Research Centre (JRC), Directorate of Nuclear Safety and Security, P.O. Box 2340, D-76125, Karlsruhe, Germany – sequence: 3 givenname: Jean-François surname: Vigier fullname: Vigier, Jean-François organization: European Commission, Joint Research Centre (JRC), Directorate of Nuclear Safety and Security, P.O. Box 2340, D-76125, Karlsruhe, Germany – sequence: 4 givenname: Mohamed surname: Naji fullname: Naji, Mohamed organization: European Commission, Joint Research Centre (JRC), Directorate of Nuclear Safety and Security, P.O. Box 2340, D-76125, Karlsruhe, Germany – sequence: 5 givenname: Sara surname: Mastromarino fullname: Mastromarino, Sara organization: European Commission, Joint Research Centre (JRC), Directorate of Nuclear Safety and Security, P.O. Box 2340, D-76125, Karlsruhe, Germany – sequence: 6 givenname: Andrea surname: Ciccioli fullname: Ciccioli, Andrea organization: Università "La Sapienza", Department of Chemistry, Piazzale Aldo Moro 5, 00185, Rome, Italy – sequence: 7 givenname: Dario surname: Manara fullname: Manara, Dario email: dario.manara@ec.europa.eu organization: European Commission, Joint Research Centre (JRC), Directorate of Nuclear Safety and Security, P.O. Box 2340, D-76125, Karlsruhe, Germany |
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| Keywords | Melting Thorium oxide Zirconium oxide Mixed oxides Thorium nuclear fuel |
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| SubjectTerms | Cladding Composition Equilibrium Laser beam heating Melting Mixed oxides Nuclear fuels Organic chemistry Raman spectroscopy Sol-gel processes Solidus Solubility Stability analysis Thermal stability Thorium nuclear fuel Thorium oxide Thorium oxides Zirconium dioxide Zirconium oxide |
| Title | Solid-liquid equilibria in the ThO2 –ZrO2 system: An experimental study |
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