Micellar Solutions of a Symmetrical Amphiphilic ABA Triblock Copolymer with a Temperature-Responsive Shell
We have studied the thermal behavior of an ABA triblock copolymer having short, deuterated polystyrene end-blocks and a longer poly(N-isopropyl acrylamide) middle block, the latter exhibiting a lower critical solution temperature. The collapse of the micelles was investigated using dynamic light sca...
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| Published in: | Macromolecular symposia. Vol. 291-292; no. 1; pp. 221 - 229 |
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| Main Authors: | , , , , , , , |
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Weinheim
Wiley-VCH Verlag
01-05-2010
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| Abstract | We have studied the thermal behavior of an ABA triblock copolymer having short, deuterated polystyrene end-blocks and a longer poly(N-isopropyl acrylamide) middle block, the latter exhibiting a lower critical solution temperature. The collapse of the micelles was investigated using dynamic light scattering. Small-angle neutron scattering with contrast matching allowed us to quantify the core-shell structure of the micelles as well as their correlations as a function of temperature. |
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| AbstractList | We have studied the thermal behavior of an ABA triblock copolymer having short, deuterated polystyrene end-blocks and a longer poly(N-isopropyl acrylamide) middle block, the latter exhibiting a lower critical solution temperature. The collapse of the micelles was investigated using dynamic light scattering. Small-angle neutron scattering with contrast matching allowed us to quantify the core-shell structure of the micelles as well as their correlations as a function of temperature. Abstract We have studied the thermal behavior of an ABA triblock copolymer having short, deuterated polystyrene end‐blocks and a longer poly(N‐isopropyl acrylamide) middle block, the latter exhibiting a lower critical solution temperature. The collapse of the micelles was investigated using dynamic light scattering. Small‐angle neutron scattering with contrast matching allowed us to quantify the core‐shell structure of the micelles as well as their correlations as a function of temperature. |
| Author | Wang, W Busch, P Müller-Buschbaum, P Koumba, A.M. Bivigou Kulkarni, A Laschewsky, A Jain, A Papadakis, C.M |
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| Snippet | We have studied the thermal behavior of an ABA triblock copolymer having short, deuterated polystyrene end-blocks and a longer poly(N-isopropyl acrylamide)... We have studied the thermal behavior of an ABA triblock copolymer having short, deuterated polystyrene end‐blocks and a longer poly(N‐isopropyl acrylamide)... Abstract We have studied the thermal behavior of an ABA triblock copolymer having short, deuterated polystyrene end‐blocks and a longer poly(N‐isopropyl... |
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| SubjectTerms | amphiphiles Block copolymers Collapse colloids Correlation dynamic light scattering Dynamic tests Micelles Neutron scattering Polystyrene resins Shells small-angle neutron scattering stimuli-sensitive polymers |
| Title | Micellar Solutions of a Symmetrical Amphiphilic ABA Triblock Copolymer with a Temperature-Responsive Shell |
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