Absolute configuration of (6S,9S)-roseoside from Polygonum hydropiper

From Polygonum hydropiper L., a C13-norisoprenoid glucoside was isolated and its absolute configuration was established to be (6S,9S)-roseoside (1) by spectroscopic evidence and X-ray crystallographic analysis of its acetate derivative (2). In addition, the stereostructure of roseoside from Canthium...

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Published in:Planta medica Vol. 67; no. 5; p. 480
Main Authors: Murai, Y, Kashimura, S, Tamezawa, S, Hashimoto, T, Takaoka, S, Asakawa, Y, Kiguchi, K, Murai, F, Tagawa, M
Format: Journal Article
Language:English
Published: Germany 01-07-2001
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Abstract From Polygonum hydropiper L., a C13-norisoprenoid glucoside was isolated and its absolute configuration was established to be (6S,9S)-roseoside (1) by spectroscopic evidence and X-ray crystallographic analysis of its acetate derivative (2). In addition, the stereostructure of roseoside from Canthium subcordatum was revised to the (6S,9S) configuration.
AbstractList From Polygonum hydropiper L., a C13-norisoprenoid glucoside was isolated and its absolute configuration was established to be (6S,9S)-roseoside (1) by spectroscopic evidence and X-ray crystallographic analysis of its acetate derivative (2). In addition, the stereostructure of roseoside from Canthium subcordatum was revised to the (6S,9S) configuration.
Author Murai, Y
Kashimura, S
Tagawa, M
Hashimoto, T
Murai, F
Takaoka, S
Asakawa, Y
Tamezawa, S
Kiguchi, K
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  surname: Tagawa
  fullname: Tagawa, M
BackLink https://www.ncbi.nlm.nih.gov/pubmed/11488470$$D View this record in MEDLINE/PubMed
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Snippet From Polygonum hydropiper L., a C13-norisoprenoid glucoside was isolated and its absolute configuration was established to be (6S,9S)-roseoside (1) by...
SourceID pubmed
SourceType Index Database
StartPage 480
SubjectTerms Glucosides - chemistry
Magnetic Resonance Spectroscopy
Molecular Conformation
Molecular Structure
Molecular Weight
Norisoprenoids
Plant Extracts
Plants, Medicinal
Polygonaceae - chemistry
X-Rays
Title Absolute configuration of (6S,9S)-roseoside from Polygonum hydropiper
URI https://www.ncbi.nlm.nih.gov/pubmed/11488470
Volume 67
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