Processing of surface-treated boron carbide-reinforced aluminum matrix composites by liquid–metal stir-casting technique

• Published in: Journal of composite materials Vol. 45; no. 23; pp. 2371 - 2378
• Main Authors: Mahesh, V.P., Nair, Praseeda S., Rajan, T.P.D., Pai, B.C., Hubli, R.C.
• Format: Journal Article
• Language: English
• Published: London, England SAGE Publications 01-11-2011; Sage Publications
• Subjects: Aluminum base alloys; Aluminum matrix composites; Applied sciences; Cross-disciplinary physics: materials science; rheology; Dispersions; Energy; Energy. Thermal use of fuels; Exact sciences and technology; Fission nuclear power plants; Foundry engineering; Heating; Installations for energy generation and conversion: thermal and electrical energy; Interface reactions; Materials science; Materials synthesis; materials processing; Metal matrix composites; Metals. Metallurgy; Other casting methods. Solidification; Particulate composites; Physics; Preheating; Production techniques; metal matrix composite; aluminum; stir casting; interfacial reaction; boron carbide; Fibre reinforced metal; Metal matrix composite; Solid solid interface; Reaction product; Stirring; Dispersion reinforced material; Aluminium alloy; Fabrication property relation; Boron carbide; Casting; Powder technology; Sintering; Radiation shielding; Neutron irradiation; Oxidation; Preheating
• ISSN: 0021-9983; 1530-793X
• DOI: 10.1177/0021998311401086

Boron carbide is one of the potential neutron-shielding materials and its use can be maximized for structural shielding application by dispersing it into metal matrixes such as aluminum. Dispersion of B4C and its interfacial stability is a major issue during its processing. This investigation is on the synthesis of B4C-reinforced 6061 aluminum matrix composite by liquid–metal stir-casting technique under optimized conditions after solving the issues related to the processing, and evaluation of the structural, mechanical, and interfacial characteristics. During processing of composites, pretreatment of B4C particles is necessary to improve its dispersion. However, higher preheating temperatures above 300°C lead to particle agglomeration in the matrix due to the formation of B2O3 phase during preheating. B2O3 is formed due to the surface oxidation of B4C particles above 300°C and this glassy phase leads to particle sintering and lump formation. Incorporation of particles preheated at 250°C has shown uniform distribution of particles in the composite. Interfacial characterization of the composite and the extracted B4C particles from the matrix has shown the presence of interfacial reaction products such as AlB2, Al3BC, AlB12, and AlB10.