Synthesis and growth mechanism of bamboo like N-doped CNT/Graphene nanostructure incorporated with hybrid metal nanoparticles for overall water splitting

• Published in: Carbon (New York) Vol. 170; pp. 452 - 463
• Main Authors: Ashok, Anchu, Kumar, Anand, Ponraj, Janarthanan, Mansour, Said A.
• Format: Journal Article
• Language: English
• Published: New York Elsevier Ltd 01-12-2020; Elsevier BV
• Subjects: Bamboo; Carbon; Charge transfer; Chemical properties; Chemical synthesis; Cobalt oxides; Crystal defects; Current density; Electrocatalysis; Encapsulation; Graphene; Hydrogen evolution reaction (HER); Intermetallic compounds; Lattice vacancies; Melamine; Multi wall carbon nanotubes; Nanocomposites; Nanoparticles; Nanotubes; Overall water splitting; Oxygen evolution reaction (OER); Pyrolysis; Semiconductor doping; Sulfur; Surface area; Water splitting; Hydrogen evolution reaction (HER); Oxygen evolution reaction (OER); Overall water splitting
• ISSN: 0008-6223; 1873-3891
• DOI: 10.1016/j.carbon.2020.08.047

Herein, we report a melamine and metal-salt based pyrolysis technique for synthesizing metal encapsulated N-doped carbon nanotube (CNTs) in form of bamboo-like CNTs and multi walled CNTs (MWCNT). Sulfur doping during synthesis greatly influenced the physio-chemical properties of the material formed. X-ray diffraction (XRD) analysis confirms NiCo alloy (NiCo@CNT) formation that transformed into a hybrid NiCo/Co3Ni6S8/Co3O4 nanocomposite (NiCoS@CNT) in presence of sulfur. A detailed study was conducted on the mechanism of the formation of metal-encapsulated N-doped CNT structures from the polymerization of melamine. The unique NiCoS@CNT structure renders high specific surface area (232.2 m2/g), large pore volume (0.92 cm2/g), and high lattice defect with abundant oxygen vacancies resulting in excellent performance for OER and HER in alkaline medium. The hybrid catalyst requires over-potentials of 198 mV and 295 mV to deliver a current-density of 10 mAcm−2, respectively for HER and OER. A cell voltage of only 1.53 V was required to deliver a long-term stable current-density of 10 mAcm−2 for water splitting when NiCoS@CNT was used as both anode and cathode. Superior performance of NiCoS@CNT could be ascribed to high surface area, abundant active sites, fast charge-transfer rate, high pyridinic-N content and the presence of highly conductive CNT architecture.
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