Sulfonamides photoassisted oxidation treatments catalyzed by ilmenite

• Published in: Chemosphere (Oxford) Vol. 180; pp. 523 - 530
• Main Authors: García-Muñoz, P., Pliego, G., Zazo, J.A., Bahamonde, A., Casas, J.A.
• Format: Journal Article
• Language: English
• Published: England Elsevier Ltd 01-08-2017
• Subjects: Advanced oxidation processes; Catalysis; CWPO-Photoassisted; Hydrogen Peroxide - chemistry; Hydroxyl radical; Iron - chemistry; Models, Chemical; Oxidation-Reduction; Peroxides - chemistry; Photocatalysis; Photochemical Processes; Radical organic condensation; Raw ilmenite; Sulfanilamides; Sulfonamides - chemistry; Titanium - chemistry; Waste Disposal, Fluid; Raw ilmenite; Advanced oxidation processes; CWPO-Photoassisted; Photocatalysis; Hydroxyl radical; Radical organic condensation
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2017.04.047

This work assesses the feasibility of several advanced oxidation processes (CWPO Catalytic Wet Peroxide Oxidation), Photocatalysis and their combination (CWPO-Photoassisted process) for sulfonamide antibiotic degradation. Raw ilmenite was used as catalyst in both processes, because of the presence of iron and titanium in its structure.
Despite both treatments allowed reaching a total starting antibiotic depletion working at pH0 = 3 and T0 = 30 °C within 30 min reaction time, significant differences were observed in terms of mineralization. Thus, whereas photocatalytic process just reduced 35% of initial TOC after 120 min, a 85% of mineralization was reached in the presence of H2O2 (CWPO-Photoassisted process) which was related to the oxidation pathway. Only a 35% of mineralization was reached in case of CWPO. In this sense, the degradation route under CWPO-Photoassisted process displayed a mechanism based on the hydroxylation that led to lower molecular weight intermediates. On the contrary, under photocatalysis conditions, the appearance of higher molecular weight intermediates due to organic radical recombination indicates the prevailing of a condensation mechanism.
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•Two AOPs with ilmenite as catalyst were employed for sulfonamides degradation.•Total conversion of sulfonamides were reached within 30 min reaction time.•Huge differences in TOC conversion were observed for each process.•In CWPO-Photoassisted process prevailed an hydroxylation mechanism.•In photocatalysis prevailed a condensation mechanism.