Stereoselective syntheses of siphonarienal and siphonarienone

Stereoselective syntheses of siphonarienal and siphonarienone

[Display omitted] The asymmetric total synthesis of marine polypropionate natural products siphonarienal and siphonarienone has been achieved from a common precursor 3. The key transformations of this synthesis are the diastereoselective oxidative kinetic resolution, Wittig olefination, Grignard rea...

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Published in:Tetrahedron: asymmetry Vol. 26; no. 17; pp. 885 - 890
Main Authors: Ghanty, Supriya, Suresh Kumar, Chinta Krinda, Reddy, B.V. Subba
Format: Journal Article
Language:English
Published: Elsevier Ltd 15-09-2015
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Abstract [Display omitted] The asymmetric total synthesis of marine polypropionate natural products siphonarienal and siphonarienone has been achieved from a common precursor 3. The key transformations of this synthesis are the diastereoselective oxidative kinetic resolution, Wittig olefination, Grignard reaction, and Evans asymmetric alkylation for the installation of a third stereogenic center of the target molecules from commercially available starting materials.
AbstractList [Display omitted] The asymmetric total synthesis of marine polypropionate natural products siphonarienal and siphonarienone has been achieved from a common precursor 3. The key transformations of this synthesis are the diastereoselective oxidative kinetic resolution, Wittig olefination, Grignard reaction, and Evans asymmetric alkylation for the installation of a third stereogenic center of the target molecules from commercially available starting materials.
Author Ghanty, Supriya
Reddy, B.V. Subba
Suresh Kumar, Chinta Krinda
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Snippet [Display omitted] The asymmetric total synthesis of marine polypropionate natural products siphonarienal and siphonarienone has been achieved from a common...
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Title Stereoselective syntheses of siphonarienal and siphonarienone
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