Synthesis and electrochemical, electrical and gas sensing properties of novel mononuclear metal-free, Zn(II), Ni(II), Co(II), Cu(II), Lu(III) and double-decker Lu(III) phthalocyanines substituted with 2-(2H-1,2,3-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl) phenoxy

Novel metallophthalocyanines 4–8 (M=Zn, Ni, Co, Cu, Lu, respectively), metal free 9 and double decker Lu(III) phthalocyanine 10 with four peripheral 2-(2H-1,2,3-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenoxy groups were synthesized by cyclotetramerisation of the phthalonitrile. Their electro...

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Bibliographic Details
Published in:	Synthetic metals Vol. 161; no. 1-2; pp. 112 - 123
Main Authors:	Gümrükçü, Gülşah, Özgür, Mahmure Üstün, Altındal, Ahmet, Özkaya, Ali Rıza, Salih, Bekir, Bekaroğlu, Özer
Format:	Journal Article
Language:	English
Published:	Amsterdam Elsevier B.V 01-01-2011 Elsevier
Subjects:	Chemistry Conductivity Copper Direct current Double decker Electrochemistry Electrochemistry–spectroelectrochemistry Exact sciences and technology Gas sensing Gas sensors General and physical chemistry Heterocyclic compounds Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings Impedance spectroscopy Kinetics and mechanisms Lutetium double decker Nickel Noncondensed benzenic compounds Organic chemistry Phthalocyanine Preparations and properties Reactivity and mechanisms Synthesis Toluene Voltammetry Conductivity Phthalocyanine Gas sensing Synthesis Lutetium double decker Electrochemistry–spectroelectrochemistry Copper II Benzotriazole derivatives Fourier transformation Transition element complexes Chemical analysis Electrical conductivity Nickel II Nitrile Film Nitrogen heterocycle Electrochemistry-spectroelectrochemistry Lutetium III Temperature effect NMR spectrometry Matrix assisted laser desorption ionization Characterization Hydrogen 1 Cyclic voltammetry Cobalt II Reaction mechanism Redox system Chemical synthesis Spectroelectrochemistry Nucleophilic reaction Electrical properties Zinc II Toluene Measurement sensor Infrared spectrometry Time of flight method Metallophthalocyanine Electrochemistry Phenols Impedance Gas sensors Mass spectrometry Ultraviolet visible spectrometry
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