Transformations in the Mn-O-Si system using concentrated solar energy
•Solar energy has a great potential in high temperature process as the production of ferroalloys.•We proposed the silicothermic reduction of the oxide of manganese (IV) using concentrated solar energy.•Silicon-manganese mixtures and silicomanganese were obtained by silicothermic reduction of the oxi...
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| Published in: | Solar energy Vol. 184; pp. 148 - 152 |
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| Abstract | •Solar energy has a great potential in high temperature process as the production of ferroalloys.•We proposed the silicothermic reduction of the oxide of manganese (IV) using concentrated solar energy.•Silicon-manganese mixtures and silicomanganese were obtained by silicothermic reduction of the oxide of manganese (IV).
Energy consumption and carbon dioxide emissions are a problem in the metallurgical industries. The synthesis of manganese and silicomanganese using concentrated solar energy is proposed in this paper. Mixtures of oxide of manganese (IV) and silicon (50 wt% and 75 wt%) were treated in a 1.5 kW solar furnace located in Odeillo. Results demonstrated that mixtures of manganese and silicon, but also silicomanganese, are obtained after treatment even in the less favorable situation: without iron, which reduces the liquidus temperature, and without slag-forming reagents. |
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| AbstractList | •Solar energy has a great potential in high temperature process as the production of ferroalloys.•We proposed the silicothermic reduction of the oxide of manganese (IV) using concentrated solar energy.•Silicon-manganese mixtures and silicomanganese were obtained by silicothermic reduction of the oxide of manganese (IV).
Energy consumption and carbon dioxide emissions are a problem in the metallurgical industries. The synthesis of manganese and silicomanganese using concentrated solar energy is proposed in this paper. Mixtures of oxide of manganese (IV) and silicon (50 wt% and 75 wt%) were treated in a 1.5 kW solar furnace located in Odeillo. Results demonstrated that mixtures of manganese and silicon, but also silicomanganese, are obtained after treatment even in the less favorable situation: without iron, which reduces the liquidus temperature, and without slag-forming reagents. Energy consumption and carbon dioxide emissions are a problem in the metallurgical industries. The synthesis of manganese and silicomanganese using concentrated solar energy is proposed in this paper. Mixtures of oxide of manganese (IV) and silicon (50 wt% and 75 wt%) were treated in a 1.5 kW solar furnace located in Odeillo. Results demonstrated that mixtures of manganese and silicon, but also silicomanganese, are obtained after treatment even in the less favorable situation: without iron, which reduces the liquidus temperature, and without slag-forming reagents. |
| Author | Ruiz-Bustinza, I. Piñuela-Noval, J. Fernández-González, D. González-Gasca, C. Prazuch, J. Verdeja, L.F. |
| Author_xml | – sequence: 1 givenname: D. surname: Fernández-González fullname: Fernández-González, D. email: fernandezgdaniel@uniovi.es organization: Department of Materials Science and Metallurgical Engineering, School of Mines, Energy and Materials, University of Oviedo, Oviedo, Asturias, Spain – sequence: 2 givenname: J. surname: Prazuch fullname: Prazuch, J. organization: Department of Physical Chemistry and Modelling, Faculty of Materials Science and Ceramics, AGH University of Science and Technology, Krakow, Poland – sequence: 3 givenname: I. surname: Ruiz-Bustinza fullname: Ruiz-Bustinza, I. organization: Department of Geological and Mining Engineering, Polytechnic University of Madrid, Madrid, Spain – sequence: 4 givenname: C. surname: González-Gasca fullname: González-Gasca, C. organization: European University of Madrid-Laureate International Universities, Villaviciosa de Odón, Madrid, Spain – sequence: 5 givenname: J. surname: Piñuela-Noval fullname: Piñuela-Noval, J. organization: Department of Materials Science and Metallurgical Engineering, School of Mines, Energy and Materials, University of Oviedo, Oviedo, Asturias, Spain – sequence: 6 givenname: L.F. surname: Verdeja fullname: Verdeja, L.F. organization: Department of Materials Science and Metallurgical Engineering, School of Mines, Energy and Materials, University of Oviedo, Oviedo, Asturias, Spain |
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| Cites_doi | 10.1007/s11663-017-0967-z 10.1016/j.solener.2019.02.026 10.1007/s11663-018-1175-1 10.1016/j.solener.2018.05.065 10.3390/met8110873 10.1016/j.jclepro.2012.08.010 10.1002/srin.201300377 10.1002/srin.201200145 10.1016/j.hydromet.2007.08.010 10.1016/S0196-8904(99)00025-4 10.3390/met8030162 10.1016/j.solener.2019.01.055 10.1016/j.solener.2018.07.012 |
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| Keywords | Concentrated solar energy Ferroalloys Environment Silicomanganese Manganese |
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| References | Fernández-González, Prazuch, Ruiz-Bustinza, González-Gasca, Piñuela- Noval, Verdeja (b0025) 2019; 180 Holappa (b0040) 2013 Olsen, Tangstad, Lindstad (b0065) 2007 Tangstad (b0080) 2013 Fernández-González, Prazuch, Ruiz-Bustinza, González-Gasca, Piñuela- Noval, Verdeja (b0030) 2019; 181 Fernández-González, Sancho-Gorostiaga, Piñuela-Noval, Verdeja González (b0020) 2018; 8 Zhang, Cheng (b0085) 2007; 89 Sakamoto, Tonooka, Yanagisawa (b0075) 1999; 40 Jamieson, Coley (b0050) 2017; 48 Ndlovu, Simate, Matinde (b0060) 2017 Ruiz-Bustinza, Cañadas, Rodríguez, Mochón, Verdeja, García-Carcedo, Vázquez (b0070) 2013; 84 Mochón, Ruiz-Bustinza, Vázquez, Fernández, Ayala, Barbés, Verdeja (b0055) 2014; 85 Fernández-González, Prazuch, Ruiz-Bustinza, González-Gasca, Piñuela- Noval, Verdeja (b0010) 2018; 171 Fernández-González, Ruiz-Bustinza, González-Gasca, Piñuela-Noval, Mochón-Castaños, Sancho-Gorostiaga, Verdeja (b0005) 2018; 180 Haque, Norgate (b0035) 2013; 39 Heo, Park (b0045) 2018; 49 Fernández-González, Prazuch, Ruiz-Bustinza, González-Gasca, Piñuela-Noval, Verdeja (b0015) 2018; 8 Fernández-González (10.1016/j.solener.2019.04.004_b0015) 2018; 8 Olsen (10.1016/j.solener.2019.04.004_b0065) 2007 Ruiz-Bustinza (10.1016/j.solener.2019.04.004_b0070) 2013; 84 Holappa (10.1016/j.solener.2019.04.004_b0040) 2013 Heo (10.1016/j.solener.2019.04.004_b0045) 2018; 49 Tangstad (10.1016/j.solener.2019.04.004_b0080) 2013 Zhang (10.1016/j.solener.2019.04.004_b0085) 2007; 89 Fernández-González (10.1016/j.solener.2019.04.004_b0010) 2018; 171 Mochón (10.1016/j.solener.2019.04.004_b0055) 2014; 85 Fernández-González (10.1016/j.solener.2019.04.004_b0005) 2018; 180 Fernández-González (10.1016/j.solener.2019.04.004_b0020) 2018; 8 Fernández-González (10.1016/j.solener.2019.04.004_b0030) 2019; 181 Ndlovu (10.1016/j.solener.2019.04.004_b0060) 2017 Fernández-González (10.1016/j.solener.2019.04.004_b0025) 2019; 180 Sakamoto (10.1016/j.solener.2019.04.004_b0075) 1999; 40 Haque (10.1016/j.solener.2019.04.004_b0035) 2013; 39 Jamieson (10.1016/j.solener.2019.04.004_b0050) 2017; 48 |
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| Snippet | •Solar energy has a great potential in high temperature process as the production of ferroalloys.•We proposed the silicothermic reduction of the oxide of... Energy consumption and carbon dioxide emissions are a problem in the metallurgical industries. The synthesis of manganese and silicomanganese using... |
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| SubjectTerms | Carbon dioxide Carbon dioxide emissions Concentrated solar energy Energy consumption Environment Ferroalloys Iron Liquidus Manganese Metallurgy Reagents Silicomanganese Silicon Slag Solar energy Solar furnaces |
| Title | Transformations in the Mn-O-Si system using concentrated solar energy |
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