Cu₂ZnSnS₄ thin films and nanowires prepared by different single-step electrodeposition method in quaternary electrolyte

We investigated the effect of single-step electrodeposition methods for the fabrication of CZTS thin films as solar cell absorber layer. For deposition of CZTS thin films, a potentiostatic method and a pulsed potential electrodeposition method were examined. Near stoichiometric CZTS thin films were...

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Published in:	Materials letters Vol. 65; no. 15-16; pp. 2364 - 2367
Main Authors:	Jeon, Minsung, Shimizu, Tomohiro, Shingubara, Shoso
Format:	Journal Article
Language:	English
Published:	Elsevier B.V 01-08-2011
Subjects:	copper CZT Deposition Electrodeposition Electrolytes Nanocomposites Nanostructure Nanowires photovoltaic cells Thin films tin zinc
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Abstract	We investigated the effect of single-step electrodeposition methods for the fabrication of CZTS thin films as solar cell absorber layer. For deposition of CZTS thin films, a potentiostatic method and a pulsed potential electrodeposition method were examined. Near stoichiometric CZTS thin films were prepared by potentiostatic deposition method. On the other hands, the samples deposited by pulsed potential method showed wire-like CZTS nanostructures. The nanowires were composed of the Cu and S element mainly and included Zn and Sn microelements. From these results, we realized that the electrodeposition methods strongly affect the structural and compositional characteristics of as-deposited CZTS thin films.
AbstractList	We investigated the effect of single-step electrodeposition methods for the fabrication of CZTS thin films as solar cell absorber layer. For deposition of CZTS thin films, a potentiostatic method and a pulsed potential electrodeposition method were examined. Near stoichiometric CZTS thin films were prepared by potentiostatic deposition method. On the other hands, the samples deposited by pulsed potential method showed wire-like CZTS nanostructures. The nanowires were composed of the Cu and S element mainly and included Zn and Sn microelements. From these results, we realized that the electrodeposition methods strongly affect the structural and compositional characteristics of as-deposited CZTS thin films. We investigated the effect of single-step electrodeposition methods for the fabrication of CZTS thin films as solar cell absorber layer. For deposition of CZTS thin films, a potentiostatic method and a pulsed potential electrodeposition method were examined. Near stoichiometric CZTS thin films were prepared by potentiostatic deposition method. On the other hands, the samples deposited by pulsed potential method showed wire-like CZTS nanostructures. The nanowires were composed of the Cu and S element mainly and included Zn and Sn microelements. From these results, we realized that the electrodeposition methods strongly affect the structural and compositional characteristics of as-deposited CZTS thin films. Self-assembled CZTS nanowires by pulsed potential electrodeposition method in quaternary electrolyte.
Author	Jeon, Minsung Shingubara, Shoso Shimizu, Tomohiro
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SubjectTerms	copper CZT Deposition Electrodeposition Electrolytes Nanocomposites Nanostructure Nanowires photovoltaic cells Thin films tin zinc
Title	Cu₂ZnSnS₄ thin films and nanowires prepared by different single-step electrodeposition method in quaternary electrolyte
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