Correlation for estimation of the chemical availability (exergy) from ultimate analysis of pyrolytic oils obtained from fast pyrolysis of biomass
The purpose of this study is to evaluate the chemical exergy (E CH ) of liquid products obtained from fast pyrolysis of biomass. I have calculated the chemical exergy values from a formula in literature and have developed a formula for estimating the chemical exergy of biomass from the higher heatin...
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| Published in: | Energy sources. Part A, Recovery, utilization, and environmental effects Vol. 38; no. 9; pp. 1286 - 1292 |
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| Format: | Journal Article |
| Language: | English |
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02-05-2016
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| Abstract | The purpose of this study is to evaluate the chemical exergy (E
CH
) of liquid products obtained from fast pyrolysis of biomass. I have calculated the chemical exergy values from a formula in literature and have developed a formula for estimating the chemical exergy of biomass from the higher heating value and their ultimate analysis values. The mean differences between these values range from -0.391% to 0.460%. The formula developed for estimating the chemical exergy of biomass from the higher heating value and their ultimate analyses had a correlation coefficient (R
2
= 0.9999), and the prediction of this formula is good. The goal is to identify desirable attributes that may serve as the basis for decision-making for future biofuel options. Studies on the pyrolytic oils showed that the oils obtained from chestnut cupulae and maple fruit can be used as a renewable fuel and chemical feedstock. |
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| AbstractList | The purpose of this study is to evaluate the chemical exergy (E super(CH)) of liquid products obtained from fast pyrolysis of biomass. I have calculated the chemical exergy values from a formula in literature and have developed a formula for estimating the chemical exergy of biomass from the higher heating value and their ultimate analysis values. The mean differences between these values range from -0.391% to 0.460%. The formula developed for estimating the chemical exergy of biomass from the higher heating value and their ultimate analyses had a correlation coefficient (R super(2) = 0.9999), and the prediction of this formula is good. The goal is to identify desirable attributes that may serve as the basis for decision-making for future biofuel options. Studies on the pyrolytic oils showed that the oils obtained from chestnut cupulae and maple fruit can be used as a renewable fuel and chemical feedstock. The purpose of this study is to evaluate the chemical exergy (E CH ) of liquid products obtained from fast pyrolysis of biomass. I have calculated the chemical exergy values from a formula in literature and have developed a formula for estimating the chemical exergy of biomass from the higher heating value and their ultimate analysis values. The mean differences between these values range from -0.391% to 0.460%. The formula developed for estimating the chemical exergy of biomass from the higher heating value and their ultimate analyses had a correlation coefficient (R 2 = 0.9999), and the prediction of this formula is good. The goal is to identify desirable attributes that may serve as the basis for decision-making for future biofuel options. Studies on the pyrolytic oils showed that the oils obtained from chestnut cupulae and maple fruit can be used as a renewable fuel and chemical feedstock. |
| Author | Bilgen, Selçuk |
| Author_xml | – sequence: 1 givenname: Selçuk surname: Bilgen fullname: Bilgen, Selçuk email: selcuk61bilgen@yahoo.com organization: Department of Chemistry, Karadeniz Technical University |
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| CitedBy_id | crossref_primary_10_1007_s10163_020_01114_2 crossref_primary_10_1080_15567036_2016_1212292 crossref_primary_10_1080_15567249_2017_1316797 crossref_primary_10_1016_j_matpr_2021_12_455 crossref_primary_10_1002_ep_13426 |
| Cites_doi | 10.1016/j.renene.2012.06.030 10.1016/j.apenergy.2008.02.001 10.3866/PKU.WHXB20090806 10.1002/9781119990840 10.1016/j.rser.2012.05.026 10.1002/ep.10612 10.1016/j.enconman.2007.04.005 10.1080/15567030701548778 10.1080/15567036.2010.549908 10.1016/j.fuproc.2012.05.002 10.1016/j.energy.2012.03.001 10.1080/15567030701258311 10.1016/S0360-5442(01)00094-9 10.1016/j.jaap.2013.02.007 |
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| References | Bilgen S. (CIT0005) 2009; 25 CIT0010 CIT0020 CIT0011 Garg A. (CIT0012) 2006 Basu P. (CIT0002) 2010 Szargut J. (CIT0019) 2005 Kar T. (CIT0014) 2012 Bahadır A. (CIT0001) 2013 CIT0013 CIT0016 CIT0004 CIT0015 Bejan A. (CIT0003) 1996 CIT0007 CIT0018 CIT0006 CIT0017 CIT0009 CIT0008 |
| References_xml | – ident: CIT0016 doi: 10.1016/j.renene.2012.06.030 – ident: CIT0008 doi: 10.1016/j.apenergy.2008.02.001 – volume-title: Pyrolysis of Chestnut Cupulae and Its Liquid Products Characterization year: 2012 ident: CIT0014 contributor: fullname: Kar T. – volume-title: Exergy Method: Technical and Ecological Applications year: 2005 ident: CIT0019 contributor: fullname: Szargut J. – volume: 25 start-page: 1645 year: 2009 ident: CIT0005 publication-title: Acta Phys. – Chim. Sin. doi: 10.3866/PKU.WHXB20090806 contributor: fullname: Bilgen S. – ident: CIT0010 doi: 10.1002/9781119990840 – volume-title: 2006 IPCC Guidelines for National Greenhouse Gas Inventories year: 2006 ident: CIT0012 contributor: fullname: Garg A. – volume-title: Production of Liquid Products from Maple (Platanoides) Fruit via Fast Pyrolysis year: 2013 ident: CIT0001 contributor: fullname: Bahadır A. – ident: CIT0015 doi: 10.1016/j.rser.2012.05.026 – volume-title: Thermal Design and Optimization year: 1996 ident: CIT0003 contributor: fullname: Bejan A. – ident: CIT0017 doi: 10.1002/ep.10612 – ident: CIT0013 doi: 10.1016/j.enconman.2007.04.005 – ident: CIT0006 doi: 10.1080/15567030701548778 – ident: CIT0009 doi: 10.1080/15567036.2010.549908 – ident: CIT0018 doi: 10.1016/j.fuproc.2012.05.002 – ident: CIT0004 doi: 10.1016/j.energy.2012.03.001 – ident: CIT0007 doi: 10.1080/15567030701258311 – ident: CIT0011 doi: 10.1016/S0360-5442(01)00094-9 – volume-title: Biomass Gasification and Pyrolysis year: 2010 ident: CIT0002 contributor: fullname: Basu P. – ident: CIT0020 doi: 10.1016/j.jaap.2013.02.007 |
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| Snippet | The purpose of this study is to evaluate the chemical exergy (E
CH
) of liquid products obtained from fast pyrolysis of biomass. I have calculated the chemical... The purpose of this study is to evaluate the chemical exergy (E super(CH)) of liquid products obtained from fast pyrolysis of biomass. I have calculated the... |
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| SubjectTerms | bio-oil Biomass Calorific value chemical exergy correlation Estimating Exergy fast pyrolysis Formulas (mathematics) Fuels Liquids Pyrolysis |
| Title | Correlation for estimation of the chemical availability (exergy) from ultimate analysis of pyrolytic oils obtained from fast pyrolysis of biomass |
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