Highly active metal–acid bifunctional catalyst system for hydrogenolysis of glycerol under mild reaction conditions

Highly active metal–acid bifunctional catalyst system for hydrogenolysis of glycerol under mild reaction conditions

Combination of active carbon supported Ru catalyst with a cation exchange resin (Amberlyst 15) exhibited much higher activity in glycerol hydrogenolysis under mild reaction conditions such as 393 K and 4 MPa H 2, than other metal–acid bifunctional catalyst systems using various zeolites, sulfated zi...

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Bibliographic Details
Published in:Catalysis communications Vol. 6; no. 10; pp. 645 - 649
Main Authors: Kusunoki, Yohei, Miyazawa, Tomohisa, Kunimori, Kimio, Tomishige, Keiichi
Format: Journal Article
Language:English
Published: Elsevier B.V 01-10-2005
Subjects:
Acid
Glycerol
Hydrogenolysis
Ion exchange resin
Metal
Propylene glycol
Glycerol
Propylene glycol
Acid
Metal
Hydrogenolysis
Ion exchange resin
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Summary:Combination of active carbon supported Ru catalyst with a cation exchange resin (Amberlyst 15) exhibited much higher activity in glycerol hydrogenolysis under mild reaction conditions such as 393 K and 4 MPa H 2, than other metal–acid bifunctional catalyst systems using various zeolites, sulfated zirconia, H 2WO 4, and liquid H 2SO 4.
ISSN:1566-7367
1873-3905
DOI:10.1016/j.catcom.2005.06.006