Atom Economical Photocatalytic Oxidation of Phenols and Site-Selective Epoxidation Toward Epoxyquinols

The discovery of a multiple-bond-forming process merging the singlet oxygen-mediated dearomatization of 3,4-disubstitued phenols and diastereo- and regioselective epoxidation is described. This one-pot strategy using a transition metal-free multicatalytic system comprised of rose bengal and cesium c...

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Bibliographic Details

Published in:	Journal of organic chemistry Vol. 86; no. 24; pp. 18192 - 18203
Main Authors:	Péault, Louis, Planchat, Aurélien, Nun, Pierrick, Le Grognec, Erwan, Coeffard, Vincent
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 17-12-2021
Subjects:	Catalysis Chemical Sciences Organic chemistry Oxidation-Reduction Phenols Rose Bengal Singlet Oxygen Transition Elements
Online Access:	Get full text
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