Determination of Copper in Different Ethanolic Matrices Using a Chloropropyl Silica Gel Modified with a Nanostructured Cubic Octa(3-aminopropyl)octasilsesquioxane
The chloropropyl silica gel was modified with octa(3-aminopropyl)octasilsesquioxane and characterized by Fourier transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR), spectroscopies, and surface and area porosity. The specific sorption capacity of metallic ions (Cu2+ and Ni2+) in...
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| Published in: | Journal of chemistry Vol. 2013; no. 1 |
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| Abstract | The chloropropyl silica gel was modified with octa(3-aminopropyl)octasilsesquioxane and characterized by Fourier transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR), spectroscopies, and surface and area porosity. The specific sorption capacity of metallic ions (Cu2+ and Ni2+) increases in the following solvent order: water < ethanol 42% < ethanol < ketone. The high values of the constant (K) in the order of 103 L mol−1 suggested the high adsorbent capacity of the modified silica (SGAPC) for Cu2+ and Ni2+. SGAPC was applied to a separation column and shows recoveries of around 100% of copper in samples of sugar cane spirit, vodka, ginger brandy, and ethanol fuel. |
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| AbstractList | The chloropropyl silica gel was modified with octa(3-aminopropyl)octasilsesquioxane and characterized by Fourier transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR), spectroscopies, and surface and area porosity. The specific sorption capacity of metallic ions (Cu2+ and Ni2+) increases in the following solvent order: water < ethanol 42% < ethanol < ketone. The high values of the constant (K) in the order of 103 L mol−1 suggested the high adsorbent capacity of the modified silica (SGAPC) for Cu2+ and Ni2+. SGAPC was applied to a separation column and shows recoveries of around 100% of copper in samples of sugar cane spirit, vodka, ginger brandy, and ethanol fuel. The chloropropyl silica gel was modified with octa(3‐aminopropyl)octasilsesquioxane and characterized by Fourier transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR), spectroscopies, and surface and area porosity. The specific sorption capacity of metallic ions (Cu 2+ and Ni 2+ ) increases in the following solvent order: water < ethanol 42% < ethanol < ketone. The high values of the constant (K) in the order of 10 3 L mol −1 suggested the high adsorbent capacity of the modified silica (SGAPC) for Cu 2+ and Ni 2+ . SGAPC was applied to a separation column and shows recoveries of around 100% of copper in samples of sugar cane spirit, vodka, ginger brandy, and ethanol fuel. |
| Author | Do Carmo, Devaney Ribeiro Filho, Newton Luiz Dias a Silveira, Tayla Fernanda De Oliveira Bicalho, Urquisa Lataro Paim, Leonardo |
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| Cites_doi | 10.1016/j.materresbull.2008.02.017 10.1201/b12439 10.1016/S0927-7757(98)00569-X 10.1351/pac200880071593 10.1016/j.jcis.2004.02.016 10.1021/ic00351a002 10.1002/(SICI)1521-3765(20000103)6:1<25::AID-CHEM25>3.0.CO;2-Y 10.1016/S0003-2670(01)84117-9 10.1080/15583720802656237 10.1016/j.carbpol.2009.12.005 10.1016/B978-008045405-4.00380-3 10.1016/j.polymer.2010.03.028 10.1007/s10853-005-0839-9 10.1016/j.talanta.2003.10.028 10.1016/S0022-328X(96)06821-0 10.1039/a802670j 10.1016/j.apsusc.2006.07.080 10.1021/ja01145a126 10.1039/b909234j 10.1590/S0103-50531997000400015 10.1016/j.foodchem.2005.12.050 10.1021/ac00168a027 10.1007/3-540-11345-2_12 10.1002/anie.199412851 10.1590/S0100-40422000000400012 10.1016/j.aca.2006.03.049 10.1021/ja00084a065 10.1021/cr00037a012 10.1016/j.polymer.2010.06.033 10.1016/j.materresbull.2010.05.005 10.1007/s00216-006-0847-x 10.1016/j.jcis.2007.07.034 10.1590/S1516-14392004000300020 10.1016/S0039-9140(98)00127-1 |
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| References | Iler R. K. The Chemistry of Sílica 1979 New York, NY, USA John Willey and Sons Tóth J. Encyclopedia of surface and colloid science Adsorption Isotherms 2002 2nd Budapest, Hungary 212 224 (12) 2010; 80 (13) 2010; 51 Marmier N. Encyclopedia of Surface and Colloid Science 2002 New York, NY, USA Taylor & Francis Group (1) 1995; 95 (31) 1998; 144 (9) 1994; 33 (34) 1997; 8 (26) 2005; 40 BRASIL Decreto no 2314 of the 4 of september of 1997. Diário Oficial da União 171 (5 of sept., 1997) 19556 (21) 1998 (22) 2004; 7 (28) 1988; 60 Britto P. F. Sorption of Cu(II) íons on the surface of sílica gel modified with 4-amino-2-2-mercaptopyrimidine and mercaptopyrimidine [Dissertation] 2005 Ilha Solteira, Brazil Faculdade de Engenharia de Ilha Solteira; Universidade Estadual Paulista (11) 2010; 51 (14) 2008; 43 Andreotti I. E. Sílica gel funcionalizada com piperazina—propriedades de adsorção de íons metálicos em meio etanólico [Tese de mestrado] 1989 Campinas, Brazil Instituto de Química (7) 2000; 6 (39) 2006; 386 (40) 1998; 47 (41) 2006; 567 (24) 1981; 129 (3) 2009; 49 (23) 2007; 253 (2) 2009; 19 (20) 1999 (27) 1997; 542 (10) 1990; 29 (6) 2008; 80 (29) 2004; 62 (8) 1994; 116 (30) 1951; 73 (17) 2006; 101 (35) 2000; 23 (19) 2010; 45 (5) 1997; 5 (15) 2004; 275 (38) 2007; 316 Riedel G. F. Jorgensen S. E. Fath B. Copper Encyclopedia of Ecology 2008 Oxford, UK Elsevier 778 783 (4) 1982; 102 Marmier N. (e_1_2_6_32_2) 2002 Iler R. K. (e_1_2_6_25_2) 1979 e_1_2_6_31_2 e_1_2_6_30_2 Feher F. J. (e_1_2_6_20_2) 1999 Provatas A. (e_1_2_6_5_2) 1997; 5 e_1_2_6_18_2 e_1_2_6_19_2 e_1_2_6_12_2 e_1_2_6_35_2 e_1_2_6_13_2 e_1_2_6_34_2 e_1_2_6_10_2 e_1_2_6_11_2 e_1_2_6_16_2 e_1_2_6_39_2 e_1_2_6_17_2 e_1_2_6_38_2 e_1_2_6_14_2 e_1_2_6_37_2 e_1_2_6_15_2 e_1_2_6_36_2 e_1_2_6_41_2 e_1_2_6_40_2 Tóth J. (e_1_2_6_33_2) 2002 e_1_2_6_8_2 e_1_2_6_7_2 e_1_2_6_9_2 e_1_2_6_29_2 e_1_2_6_4_2 e_1_2_6_3_2 e_1_2_6_6_2 e_1_2_6_24_2 e_1_2_6_23_2 e_1_2_6_2_2 e_1_2_6_22_2 e_1_2_6_1_2 e_1_2_6_21_2 e_1_2_6_28_2 e_1_2_6_27_2 e_1_2_6_26_2 |
| References_xml | – volume: 101 start-page: 33 issue: 1 year: 2006 end-page: 36 ident: 17 article-title: Simple and efficient elimination of copper(II) in sugar-cane spirits publication-title: – volume: 8 start-page: 415 issue: 4 year: 1997 end-page: 419 ident: 34 article-title: Structure of cobalt (II) perchlorate adsorbed on silica gel surface chemically modified with benzimidazole molecule publication-title: – start-page: 1279 issue: 12 year: 1998 end-page: 1280 ident: 21 article-title: Practical methods for synthesizing four incompletely condensed silsesquioxanes from a single R Si O framework publication-title: – volume: 80 start-page: 481 issue: 2 year: 2010 end-page: 485 ident: 12 article-title: Modification of cellulose with reactive polyhedral oligomeric silsesquioxane and nano-crosslinking effect on color properties of dyed cellulose materials publication-title: – start-page: 1491 issue: 9 year: 1999 end-page: 1498 ident: 20 article-title: Syntheses of highly functionalized cube-octameric polyhedral oligosilsesquioxanes (R Si O ) publication-title: – volume: 95 start-page: 1409 issue: 5 year: 1995 end-page: 1430 ident: 1 article-title: Silsesquioxanes publication-title: – volume: 62 start-page: 1005 issue: 5 year: 2004 end-page: 1028 ident: 29 article-title: Chemical modification of silica surface by immobilization of functional groups for extractive concentration of metal ions publication-title: – volume: 33 start-page: 1285 issue: 12 year: 1994 end-page: 1286 ident: 9 article-title: Molecular siloxane complexes of rare earth metals—model systems for silicate-supported catalysts? publication-title: – volume: 316 start-page: 250 issue: 2 year: 2007 end-page: 259 ident: 38 article-title: Nanoparticles of octakis[3-(3-amino-1,2,4-triazole)propyl]octasilsesquioxane as ligands for Cu(II), Ni(II), Cd(II), Zn(II), and Fe(III) in aqueous solution publication-title: – volume: 23 start-page: 496 issue: 4 year: 2000 end-page: 503 ident: 35 article-title: The use of organofuntionalized silica gel as sequestrating agent for metals publication-title: – volume: 129 start-page: 29 year: 1981 end-page: 47 ident: 24 article-title: Synthetic aspects of the characterization of some silica-bound complexing agents publication-title: – volume: 542 start-page: 141 issue: 2 year: 1997 end-page: 183 ident: 27 article-title: Silicate cages: precursors to new materials publication-title: – volume: 144 start-page: 219 issue: 1–3 year: 1998 end-page: 227 ident: 31 article-title: Adsorption of copper(II) and cobalt(II) complexes on a silica gel surface chemically modified with 3-amino-1,2,4-triazole publication-title: – volume: 49 start-page: 25 issue: 1 year: 2009 end-page: 63 ident: 3 article-title: POSS polymers: physical properties and biomaterials applications publication-title: – volume: 253 start-page: 3683 issue: 7 year: 2007 end-page: 3689 ident: 23 article-title: Preparation, characterization and application of a nanostructured composite: octakis(cyanopropyldimethylsiloxy)octasilsesquioxane publication-title: – volume: 47 start-page: 745 issue: 3 year: 1998 end-page: 752 ident: 40 article-title: Iodimetric determination of 2-mercaptopyrimidines publication-title: – volume: 5 start-page: 327 year: 1997 end-page: 332 ident: 5 article-title: Silsesquioxanes: synthesis and applications publication-title: – volume: 567 start-page: 286 issue: 2 year: 2006 end-page: 292 ident: 41 article-title: Stopped-flow determination of 2-mercaptopyrimidines as inductors of the iodine-azide reaction publication-title: – volume: 386 start-page: 2153 issue: 7-8 year: 2006 end-page: 2160 ident: 39 article-title: New analytical procedure based on a cellulose bag and ionic exchanger with p-aminobenzoic acid groups for differentiation of labile and inert metal species in aquatic systems publication-title: – volume: 7 start-page: 499 year: 2004 end-page: 504 ident: 22 article-title: Synthesis and preliminary characterization of octakis(chloropropyldimethylsiloxy)octasilsesquioxane publication-title: – volume: 6 start-page: 25 issue: 1 year: 2000 end-page: 32 ident: 7 article-title: Advances in homogeneous and heterogeneous catalysis with metal-containing silsesquioxanes publication-title: – volume: 51 start-page: 2133 issue: 10 year: 2010 end-page: 2139 ident: 13 article-title: Synthesis of tadpole-shaped POSS-containing hybrid polymers via ‘click chemistry’ publication-title: – volume: 51 start-page: 3948 issue: 17 year: 2010 end-page: 3955 ident: 11 article-title: Synthesis and characterization of polyhedral oligomeric silsesquioxane (POSS) with multifunctional benzoxazine groups through click chemistry publication-title: – volume: 275 start-page: 251 issue: 1 year: 2004 end-page: 256 ident: 15 article-title: Al O -coated 3-N-propylpyridinium chloride silsesquioxane polymer film: preparation and electrochemical property study of adsorbed cobalt tetrasulfophthalocyanine publication-title: – volume: 102 start-page: 199 year: 1982 end-page: 236 ident: 4 article-title: Polyhedral oligosilsesquioxanes and their homo derivatives publication-title: – volume: 19 start-page: 9103 issue: 48 year: 2009 end-page: 9120 ident: 2 article-title: Cubic silsesquioxanes for use in solution processable organic light emitting diodes (OLED) publication-title: – volume: 40 start-page: 4721 issue: 18 year: 2005 end-page: 4726 ident: 26 article-title: Review synthesis and characterization of cage octa(cyclohexylsilsesquioxane) publication-title: – volume: 73 start-page: 373 issue: 1 year: 1951 end-page: 380 ident: 30 article-title: The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms publication-title: – volume: 80 start-page: 1593 issue: 7 year: 2008 end-page: 1611 ident: 6 article-title: Synthesis and applications of functionalized silsesquioxane polymers attached to organic and inorganic matrices publication-title: – volume: 116 start-page: 2145 issue: 5 year: 1994 end-page: 2146 ident: 8 article-title: Synthesis of a molybdenum-containing silsesquioxane which rapidly catalyzes the metathesis of olefins publication-title: – volume: 45 start-page: 1263 issue: 9 year: 2010 end-page: 1270 ident: 19 article-title: A novel nanostructured composite formed by interaction of copper octa(3-aminopropyl)octasilsesquioxane with azide ligands: preparation, characterization and a voltammetric application publication-title: – volume: 60 start-page: 1776 issue: 17 year: 1988 end-page: 1786 ident: 28 article-title: Structural characterization of (3-aminopropyl)triethoxysilane-modified silicas by silicon-29 and carbon-13 nuclear magnetic resonance publication-title: – volume: 43 start-page: 3286 issue: 12 year: 2008 end-page: 3296 ident: 14 article-title: Adsorption and electropolymerization of toluidine blue on the nanostructured octakis(hydridodimethylsiloxy)octasilsesquioxane surface publication-title: – volume: 29 start-page: 5138 issue: 26 year: 1990 end-page: 5139 ident: 10 article-title: A triosmium cluster-siloxane cage complex. Synthesis and structure of HOs (CO) [( -O)Si O (C H ) ] publication-title: – ident: e_1_2_6_16_2 – volume-title: Encyclopedia of Surface and Colloid Science year: 2002 ident: e_1_2_6_32_2 contributor: fullname: Marmier N. – ident: e_1_2_6_14_2 doi: 10.1016/j.materresbull.2008.02.017 – start-page: 212 volume-title: Adsorption Isotherms year: 2002 ident: e_1_2_6_33_2 doi: 10.1201/b12439 contributor: fullname: Tóth J. – volume-title: The Chemistry of Sílica year: 1979 ident: e_1_2_6_25_2 contributor: fullname: Iler R. K. – ident: e_1_2_6_31_2 doi: 10.1016/S0927-7757(98)00569-X – volume: 5 start-page: 327 year: 1997 ident: e_1_2_6_5_2 article-title: Silsesquioxanes: synthesis and applications publication-title: Trends in Polymer Science contributor: fullname: Provatas A. – ident: e_1_2_6_6_2 doi: 10.1351/pac200880071593 – ident: e_1_2_6_15_2 doi: 10.1016/j.jcis.2004.02.016 – ident: e_1_2_6_10_2 doi: 10.1021/ic00351a002 – ident: e_1_2_6_7_2 doi: 10.1002/(SICI)1521-3765(20000103)6:1<25::AID-CHEM25>3.0.CO;2-Y – ident: e_1_2_6_24_2 doi: 10.1016/S0003-2670(01)84117-9 – ident: e_1_2_6_3_2 doi: 10.1080/15583720802656237 – ident: e_1_2_6_12_2 doi: 10.1016/j.carbpol.2009.12.005 – ident: e_1_2_6_18_2 doi: 10.1016/B978-008045405-4.00380-3 – ident: e_1_2_6_13_2 doi: 10.1016/j.polymer.2010.03.028 – start-page: 1491 year: 1999 ident: e_1_2_6_20_2 article-title: Syntheses of highly functionalized cube-octameric polyhedral oligosilsesquioxanes (R8Si8O12) publication-title: Journal of the Chemical Society contributor: fullname: Feher F. J. – ident: e_1_2_6_26_2 doi: 10.1007/s10853-005-0839-9 – ident: e_1_2_6_29_2 doi: 10.1016/j.talanta.2003.10.028 – ident: e_1_2_6_27_2 doi: 10.1016/S0022-328X(96)06821-0 – ident: e_1_2_6_21_2 doi: 10.1039/a802670j – ident: e_1_2_6_23_2 doi: 10.1016/j.apsusc.2006.07.080 – ident: e_1_2_6_30_2 doi: 10.1021/ja01145a126 – ident: e_1_2_6_2_2 doi: 10.1039/b909234j – ident: e_1_2_6_34_2 doi: 10.1590/S0103-50531997000400015 – ident: e_1_2_6_17_2 doi: 10.1016/j.foodchem.2005.12.050 – ident: e_1_2_6_28_2 doi: 10.1021/ac00168a027 – ident: e_1_2_6_4_2 doi: 10.1007/3-540-11345-2_12 – ident: e_1_2_6_9_2 doi: 10.1002/anie.199412851 – ident: e_1_2_6_37_2 – ident: e_1_2_6_35_2 doi: 10.1590/S0100-40422000000400012 – ident: e_1_2_6_41_2 doi: 10.1016/j.aca.2006.03.049 – ident: e_1_2_6_8_2 doi: 10.1021/ja00084a065 – ident: e_1_2_6_1_2 doi: 10.1021/cr00037a012 – ident: e_1_2_6_11_2 doi: 10.1016/j.polymer.2010.06.033 – ident: e_1_2_6_19_2 doi: 10.1016/j.materresbull.2010.05.005 – ident: e_1_2_6_39_2 doi: 10.1007/s00216-006-0847-x – ident: e_1_2_6_36_2 – ident: e_1_2_6_38_2 doi: 10.1016/j.jcis.2007.07.034 – ident: e_1_2_6_22_2 doi: 10.1590/S1516-14392004000300020 – ident: e_1_2_6_40_2 doi: 10.1016/S0039-9140(98)00127-1 |
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| Snippet | The chloropropyl silica gel was modified with octa(3-aminopropyl)octasilsesquioxane and characterized by Fourier transform infrared (FTIR) spectroscopy,... The chloropropyl silica gel was modified with octa(3‐aminopropyl)octasilsesquioxane and characterized by Fourier transform infrared (FTIR) spectroscopy,... |
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| Title | Determination of Copper in Different Ethanolic Matrices Using a Chloropropyl Silica Gel Modified with a Nanostructured Cubic Octa(3-aminopropyl)octasilsesquioxane |
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