Supramolecular association of acid-terminated polydimethylsiloxanes. IV. NMR investigation of hydrogen bonding interactions and apparent molecular weight in the bulk state
Carbon-13 spin-lattice relaxation time measurements were used to probe the existence of hydrogen bonding interactions in bulk for a diacid-terminated oligosiloxane at temperatures well above its glass transition and melting temperatures. The behavior of the corresponding monoacid-terminated oligosil...
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| Published in: | Polymer (Guilford) Vol. 44; no. 8; pp. 2295 - 2302 |
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01-04-2003
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| Abstract | Carbon-13 spin-lattice relaxation time measurements were used to probe the existence of hydrogen bonding interactions in bulk for a diacid-terminated oligosiloxane at temperatures well above its glass transition and melting temperatures. The behavior of the corresponding monoacid-terminated oligosiloxane, which can form dimers only, diester-terminated oligosiloxane, which cannot undergo any hydrogen bonding interactions, and two higher molecular weight covalent polymers, which serve as models for the supramolecular polymer, was also studied. The degree of association of the diacid-terminated oligosiloxane was estimated by investigating its transverse relaxation derived from
1H NMR and comparing the results thus obtained with data from a series of polydimethylsiloxane samples with different molecular weights. |
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| AbstractList | Carbon-13 spin-lattice relaxation time measurements were used to probe the existence of hydrogen bonding interactions in bulk for a diacid-terminated oligosiloxane at temperatures well above its glass transition and melting temperatures. The behavior of the corresponding monoacid-terminated oligosiloxane, which can form dimers only, diester-terminated oligosiloxane, which cannot undergo any hydrogen bonding interactions, and two higher molecular weight covalent polymers, which serve as models for the supramolecular polymer, was also studied. The degree of association of the diacid-terminated oligosiloxane was estimated by investigating its transverse relaxation derived from
1H NMR and comparing the results thus obtained with data from a series of polydimethylsiloxane samples with different molecular weights. |
| Author | Abed, S. Lauprêtre, F. Duweltz, D. Bouteiller, L. Boileau, S. |
| Author_xml | – sequence: 1 givenname: D. surname: Duweltz fullname: Duweltz, D. – sequence: 2 givenname: F. surname: Lauprêtre fullname: Lauprêtre, F. email: laupretre@glvt-cnrs.fr – sequence: 3 givenname: S. surname: Abed fullname: Abed, S. – sequence: 4 givenname: L. surname: Bouteiller fullname: Bouteiller, L. – sequence: 5 givenname: S. surname: Boileau fullname: Boileau, S. |
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| Cites_doi | 10.1021/ma000048x 10.1021/ma960141e 10.1021/ma00030a009 10.1007/s002890050154 10.1016/S0032-3861(01)00379-2 10.1103/PhysRev.80.580 10.1063/1.1681380 10.1016/0079-6565(93)80004-D 10.1021/ma981950w 10.1021/ma00185a028 10.1016/0032-3861(93)90536-J 10.1021/ma00034a003 10.1021/ma9715029 10.1021/ja974112a 10.1126/science.278.5343.1601 |
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| Keywords | Telechelic polydimethylsiloxane NMR Hydrogen bond Dimethylsiloxane polymer Molten state End group Telechelic polymer Molecular association Temperature effect Carboxyl group Experimental study Functional group |
| Language | English |
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| SubjectTerms | Applied sciences Chemical Sciences Exact sciences and technology Hydrogen bond Inorganic and organomineral polymers NMR Physicochemistry of polymers Properties and characterization Telechelic polydimethylsiloxane |
| Title | Supramolecular association of acid-terminated polydimethylsiloxanes. IV. NMR investigation of hydrogen bonding interactions and apparent molecular weight in the bulk state |
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