Polymerization of olefins with bulky substituents. 1. Homo- and copolymerization of 3-(1-adamantyl)propene
The use of bulky substituents like adamantane has been shown in the past to influence the glass transition temperatures of polymers significantly. In this paper the synthesis and homopolymerization of the monomer 3-(1-adamantyl) propene is described, as well as the copolymerization of this monomer w...
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| Published in: | Polymer (Guilford) Vol. 45; no. 3; pp. 799 - 804 |
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| Abstract | The use of bulky substituents like adamantane has been shown in the past to influence the glass transition temperatures of polymers significantly. In this paper the synthesis and homopolymerization of the monomer 3-(1-adamantyl) propene is described, as well as the copolymerization of this monomer with ethene, propene, 1-pentene, 4-methyl-1-pentene, 1-hexene and 1-octene. The resultant copolymers proved to be largely insoluble in organic solvents. It was also demonstrated that the presence of the bulky methyladamantyl side group influenced the glass transition temperatures of the copolymers in comparison with the corresponding homopolymers. |
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| AbstractList | The use of bulky substituents like adamantane has been shown in the past to influence the glass transition temperatures of polymers significantly. In this paper the synthesis and homopolymerization of the monomer 3-(1-adamantyl) propene is described, as well as the copolymerization of this monomer with ethene, propene, 1-pentene, 4-methyl-1-pentene, 1-hexene and 1-octene. The resultant copolymers proved to be largely insoluble in organic solvents. It was also demonstrated that the presence of the bulky methyladamantyl side group influenced the glass transition temperatures of the copolymers in comparison with the corresponding homopolymers. |
| Author | Mathias, Lon J Coetzee, Liezel van Reenen, Albert J |
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| Cites_doi | 10.1021/ma00019a005 10.1021/ja00072a010 10.1021/cm00025a002 10.1021/ma00085a052 10.1002/(SICI)1099-0518(19961130)34:16<3345::AID-POLA11>3.0.CO;2-G 10.1021/ma00120a020 10.1021/jo01306a004 10.1021/ma00069a054 10.1002/(SICI)1099-0518(19960115)34:1<117::AID-POLA12>3.0.CO;2-O 10.1021/ma00014a008 10.1016/S0040-4039(00)60898-5 10.1007/BF00296008 10.1016/0032-3861(95)97880-O |
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| Keywords | Polymer chemistry Polymer synthesis Insoluble compound Olefin copolymer Preparation Complex catalyst polymerization Experimental study Complex catalyst copolymerization Propylene derivative polymer Adamantane derivative polymer Propylene derivative copolymer |
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| SubjectTerms | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymer chemistry Polymer synthesis Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts |
| Title | Polymerization of olefins with bulky substituents. 1. Homo- and copolymerization of 3-(1-adamantyl)propene |
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