Kinetic and mechanistic study of methanol oxidation on a Pt(110) surface in alkaline media

The comparative study of methanol oxidation on a Pt(110) surface was carried out in bicarbonate, carbonate and sodium hydroxide solutions. It was shown that OH − electrosorption precedes the oxide layer formation in sodium hydroxide solution and is coupled by HCO 3 − and CO 3 2− electrosorption in t...

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Published in:	Electrochimica acta Vol. 44; no. 6; pp. 1135 - 1145
Main Authors:	TRIPKOVIC, A. V, POPOVIC, K. D, MOMCILOVIC, J. D, DRAZIC, D. M
Format:	Journal Article Conference Proceeding
Language:	English
Published:	Oxford Elsevier Ltd 01-01-1998 Elsevier
Subjects:	Alkaline solutions Chemistry Electrochemistry Exact sciences and technology General and physical chemistry Kinetics and mechanism of reactions Methanol oxidation OH − ion electrosorption Pt electrode Reaction mechanism Alkaline solutions Reaction mechanism OH − ion electrosorption Methanol oxidation Pt electrode Crystal orientation Basic solution Electrode poisoning Transition metal Experimental study Primary alcohol Hydrogencarbonates Electrodes Platinum Sodium Hydroxides Oxidation Carbonates Kinetics Electrochemical reaction Organic compounds Methanol
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Abstract	The comparative study of methanol oxidation on a Pt(110) surface was carried out in bicarbonate, carbonate and sodium hydroxide solutions. It was shown that OH − electrosorption precedes the oxide layer formation in sodium hydroxide solution and is coupled by HCO 3 − and CO 3 2− electrosorption in the corresponding media. Adsorbed bicarbonates suppressed the methanol oxidation. The surface activity was correlated to the OH ad species coverage. Coverage with `poisoning species' formed during methanol oxidation is time dependent. The dual path mechanism for methanol oxidation on the Pt(110) surface, as well as for the other low-index planes, was proposed based on the assumptions that HCO ad and OH ad are reactive intermediates and that formate is the reaction product in the main path, while CO 2 is a product of `poisoning species' oxidation in a parallel reaction path.
AbstractList	The comparative study of methanol oxidation on a Pt(110) surface was carried out in bicarbonate, carbonate and sodium hydroxide solutions. It was shown that OH super(-) electrosorption precedes the oxide layer formation in sodium hydroxide solution and is coupled by HCO super(-) sub(3) and CO super(2) sub(3) super(-) electrosorption in the corresponding media. Adsorbed bicarbonates suppressed the methanol oxidation. The surface activity was correlated to the OH sub(ad) species coverage. Coverage with 'poisoning species' formed during methanol oxidation is time dependent. The dual path mechanism for methanol oxidation on the Pt(110) surface, as well as for the other low-index planes, was proposed based on the assumptions that HCO sub(ad) and OH sub(ad) are reactive intermediates and that formate is the reaction product in the main path, while CO sub(2) is a product of 'poisoning species' oxidation in a parallel reaction path. The comparative study of methanol oxidation on a Pt(110) surface was carried out in bicarbonate, carbonate and sodium hydroxide solutions. It was shown that OH − electrosorption precedes the oxide layer formation in sodium hydroxide solution and is coupled by HCO 3 − and CO 3 2− electrosorption in the corresponding media. Adsorbed bicarbonates suppressed the methanol oxidation. The surface activity was correlated to the OH ad species coverage. Coverage with `poisoning species' formed during methanol oxidation is time dependent. The dual path mechanism for methanol oxidation on the Pt(110) surface, as well as for the other low-index planes, was proposed based on the assumptions that HCO ad and OH ad are reactive intermediates and that formate is the reaction product in the main path, while CO 2 is a product of `poisoning species' oxidation in a parallel reaction path.
Author	Momčilović, J.D. Dražić, D.M. Popović, K.Đ. Tripković, A.V.
Author_xml	– sequence: 1 givenname: A. V surname: TRIPKOVIC fullname: TRIPKOVIC, A. V organization: ICTM - Institute of Electrochemistry, University of Belgrade, P.O. Box 815, Belgrade, Yugoslavia – sequence: 2 givenname: K. D surname: POPOVIC fullname: POPOVIC, K. D organization: ICTM - Institute of Electrochemistry, University of Belgrade, P.O. Box 815, Belgrade, Yugoslavia – sequence: 3 givenname: J. D surname: MOMCILOVIC fullname: MOMCILOVIC, J. D organization: ICTM - Institute of Electrochemistry, University of Belgrade, P.O. Box 815, Belgrade, Yugoslavia – sequence: 4 givenname: D. M surname: DRAZIC fullname: DRAZIC, D. M organization: ICTM - Institute of Electrochemistry, University of Belgrade, P.O. Box 815, Belgrade, Yugoslavia
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Keywords	Alkaline solutions Reaction mechanism OH − ion electrosorption Methanol oxidation Pt electrode Crystal orientation Basic solution Electrode poisoning Transition metal Experimental study Primary alcohol Hydrogencarbonates Electrodes Platinum Sodium Hydroxides Oxidation Carbonates Kinetics Electrochemical reaction Organic compounds Methanol
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Snippet	The comparative study of methanol oxidation on a Pt(110) surface was carried out in bicarbonate, carbonate and sodium hydroxide solutions. It was shown that OH...
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SubjectTerms	Alkaline solutions Chemistry Electrochemistry Exact sciences and technology General and physical chemistry Kinetics and mechanism of reactions Methanol oxidation OH − ion electrosorption Pt electrode Reaction mechanism
Title	Kinetic and mechanistic study of methanol oxidation on a Pt(110) surface in alkaline media
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