Particle size effect in carbon supported Pt–Co alloy electrocatalysts prepared by the borohydride method: XRD characterization

• Published in: Applied catalysis. A, General Vol. 357; no. 1; pp. 1 - 4
• Main Authors: Leontyev, I.N., Chernyshov, D. Yu, Guterman, V.E., Pakhomova, E.V., Guterman, A.V.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 31-03-2009; Elsevier
• Subjects: Grain size distribution; Oxygen reduction; Pt–Co alloy; Size effects; X-ray diffraction; Size effects; X-ray diffraction; Oxygen reduction; Pt–Co alloy; Grain size distribution
• ISSN: 0926-860X; 1873-3875
• DOI: 10.1016/j.apcata.2008.12.023

Pt
3Co/C electrocatalysts prepared by wet synthesis method from water–ethylene glycol solutions of Pt and Co precursors were investigated by X-ray diffraction in conjunction with electrochemical measurements. It was shown that varying the binary solvent composition is an effective means of control over the average nanoparticle size and the grain size distribution. It was found that unit cell parameter of the Pt
3Co/C electrocatalysts decreases nonlinearly with decreasing particle size. The activity of the prepared Pt
3Co/C catalysts for the oxygen reduction reaction (ORR) in H
2SO
4 solution enhances with decrease in the particle size, the unit cell parameter, and the dispersion of the grain size distribution. All samples studied show higher catalytic activities in comparison with the commercial Pt/C materials.
We report on combined X-ray diffraction and electrochemical investigation of Pt
3Co/C electrocatalysts prepared by wet synthesis method from water–ethylene glycol solutions. X-ray diffraction analysis showed that variation of the binary solvent composition is an effective way to control microstructural characteristics of the catalysts nanoparticles. Nonlinear change in the variation of the unit cell parameter with decreasing particle size has been found.