Photocatalytic activity of single and mixed nanosheet-like Bi2WO6 and TiO2 for Rhodamine B degradation under sunlike and visible illumination

• Published in: Applied catalysis. A, General Vol. 423-424; pp. 34 - 41
• Main Authors: Murcia-López, S., Hidalgo, M.C., Navío, J.A.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 07-05-2012; Elsevier
• Subjects: Bi2WO6; Catalysis; Chemistry; Colloidal state and disperse state; Degradation; Exact sciences and technology; General and physical chemistry; Illumination; Nanocomposites; Nanomaterials; Nanostructure; Photocatalysis; Photochemistry; Physical and chemical studies. Granulometry. Electrokinetic phenomena; Physical chemistry of induced reactions (with radiations, particles and ultrasonics); Rhodamine B; Sunlike illumination; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; TiO2; Titanium dioxide; Sunlike illumination; Rhodamine B; Bi2WO6; Photocatalysis; TiO2; Rhodamine; Binary compound; Incorporation; Nanoparticle; In situ; Transition element compounds; Bi; Precursor; Powder; Degradation; Heterogeneous catalysis; Hydrothermal treatment; Mineralization; wO; TiO; Titanium oxide; Catalyst
• ISSN: 0926-860X; 1873-3875
• DOI: 10.1016/j.apcata.2012.02.016

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► Bi2WO6–TiO2 systems were obtained by mixing single Bi2WO6 nanosheets and TiO2-P25. ► Rhodamine B photodegradation was studied under different illumination conditions. ► The mixtures showed a synergy compared to Bi2WO6 and P25 photocatalysts. ► It was observed the influence of the preparation method on the obtained material.
The photocatalytic activity, under sunlike illumination, for Rhodamine B (RhB) degradation using Bi2WO6–TiO2 samples, is reported. Two different kinds of Bi2WO6–TiO2 samples were studied, obtained by distinct methods: first, a mechanical mixing, by adding to synthesized nanosheet-like Bi2WO6 powder the corresponding amount of TiO2 nanoparticles (P25) in order to obtain physical mixtures of both catalysts with different percentages of TiO2 (5, 10 and 50wt%); second, a single Bi2WO6–TiO2 heterostructure was prepared by adding commercial TiO2-P25 to the Bi2WO6 precursors (50wt%) prior to the hydrothermal treatment, thus obtaining a sample with “in situ” TiO2 incorporation. Comparisons between the photocatalytic behaviour of these samples and those exhibited by the single materials Bi2WO6 and TiO2 (P25) were carried out, in order to establish the effect not only of the TiO2 addition but also of the way in which TiO2 (P25) is incorporated. The role of each single photocatalyst in the mixtures in the RhB degradation and mineralization under sunlike and just visible illumination was also studied.