Ionic and polaronic hopping in glass
In this paper we present conductivity spectra of the ion conducting glasses B 2O 3 · 0.56Li 2O · 0.45LiBr and Ag 2S · GeS 2 and of the polaron conducting glass 0.2P 2O 5 · 0.8 (0.89V 2O 5 · 0.11V 2O 4), covering a frequency range of more than 13 decades. At frequencies below the onset of the vibrati...
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| Published in: | Solid state ionics Vol. 86; pp. 481 - 486 |
|---|---|
| Main Authors: | , , , , , , , , |
| Format: | Journal Article Conference Proceeding |
| Language: | English |
| Published: |
Amsterdam
Elsevier B.V
1996
Elsevier Science |
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| Abstract | In this paper we present conductivity spectra of the ion conducting glasses B
2O
3 · 0.56Li
2O · 0.45LiBr and Ag
2S · GeS
2 and of the polaron conducting glass 0.2P
2O
5 · 0.8 (0.89V
2O
5 · 0.11V
2O
4), covering a frequency range of more than 13 decades. At frequencies below the onset of the vibrational motion the spectra of both ion conducting glasses clearly differ from those of the polaronic glass. The dispersive conductivity of 0.2P
2O
5 · 0.8 (0.89V
2O
5 · 0.11V
2O
4) follows a simple power-law behavior, the exponent being smaller than one. In contrast, the conductivities of both ion conducting glasses show the existence of two power-law exponents; one is the Jonscher exponent, the other is larger than unity. The data are interpreted in terms of the ‘unified site relaxation model’. |
|---|---|
| AbstractList | In this paper we present conductivity spectra of the ion conducting glasses B
2O
3 · 0.56Li
2O · 0.45LiBr and Ag
2S · GeS
2 and of the polaron conducting glass 0.2P
2O
5 · 0.8 (0.89V
2O
5 · 0.11V
2O
4), covering a frequency range of more than 13 decades. At frequencies below the onset of the vibrational motion the spectra of both ion conducting glasses clearly differ from those of the polaronic glass. The dispersive conductivity of 0.2P
2O
5 · 0.8 (0.89V
2O
5 · 0.11V
2O
4) follows a simple power-law behavior, the exponent being smaller than one. In contrast, the conductivities of both ion conducting glasses show the existence of two power-law exponents; one is the Jonscher exponent, the other is larger than unity. The data are interpreted in terms of the ‘unified site relaxation model’. In this paper we present conductivity spectra of the ion conducting glasses B sub(2)O sub(3) multiplied by 0.56Li sub(2)O multiplied by 0.45LiBr and Ag sub(2)S multiplied by GeS sub(2) and of the polaron conducting glass 0.2P sub(2)O sub(5) multiplied by 0.8 (0.89V sub(2)O sub(5) multiplied by 0.11 V sub(2)O sub(4)), covering a frequency range of more than 13 decades. At frequencies below the onset of the vibrational motion the spectra of both ion conducting glasses clearly differ from those of the polaronic glass. The dispersive conductivity of 0.2P sub(2)O sub(5) multiplied by 0.8 (0.89V sub(2)O sub(5) multiplied by 0.11 V sub(2)O sub(4)) follows a simple power-law behavior, the exponent being smaller than one. In contrast, the conductivities of both ion conducting glasses show the existence of two power-law exponents; one is the Jonscher exponent, the other is larger than unity. The data are interpreted in terms of the lambda-bar unified site relaxation model lambda-bar . |
| Author | Pradel, A. Taillades, G. Ribes, M. Ingram, M.D. Funke, K. Roling, B. Saatkamp, T. Cramer, C. Wilmer, D. |
| Author_xml | – sequence: 1 givenname: C. surname: Cramer fullname: Cramer, C. organization: Institut für Physikalische Chemie, Schloβplatz 4/7, 48/49 Münster, Germany – sequence: 2 givenname: K. surname: Funke fullname: Funke, K. organization: Institut für Physikalische Chemie, Schloβplatz 4/7, 48/49 Münster, Germany – sequence: 3 givenname: B. surname: Roling fullname: Roling, B. organization: Institut für Physikalische Chemie, Schloβplatz 4/7, 48/49 Münster, Germany – sequence: 4 givenname: T. surname: Saatkamp fullname: Saatkamp, T. organization: Institut für Physikalische Chemie, Schloβplatz 4/7, 48/49 Münster, Germany – sequence: 5 givenname: D. surname: Wilmer fullname: Wilmer, D. organization: Institut für Physikalische Chemie, Schloβplatz 4/7, 48/49 Münster, Germany – sequence: 6 givenname: M.D. surname: Ingram fullname: Ingram, M.D. organization: Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB9 2UE, Scotland, UK – sequence: 7 givenname: A. surname: Pradel fullname: Pradel, A. organization: Laboratoire de Physicochimie des Matériaux Solides, URA D0407 CNRS CC3, Université de Montpellier II, 34095 Montpellier cédex 5, France – sequence: 8 givenname: M. surname: Ribes fullname: Ribes, M. organization: Laboratoire de Physicochimie des Matériaux Solides, URA D0407 CNRS CC3, Université de Montpellier II, 34095 Montpellier cédex 5, France – sequence: 9 givenname: G. surname: Taillades fullname: Taillades, G. organization: Laboratoire de Physicochimie des Matériaux Solides, URA D0407 CNRS CC3, Université de Montpellier II, 34095 Montpellier cédex 5, France |
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| Keywords | Ionic hopping Polaronic hopping Ion conducting glasses Coulomb potential Frequency dependence Inorganic compounds Ionic conductivity Glass Hopping conductivity Experimental study Chalcogenide glasses Borate glasses Relaxation Sulfides Vanadates Models Power law Polarons |
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| References | M.D. Ingram, K. Funke, A. Bunde, this issue. Funke (BIB3) 1993; 22 Ngai, Strom (BIB7) 1988; B38 Cramer, Funke, Saatkamp, Wilmer, Ingram (BIB8) 1995; 50a Funke, Kloidt, Wilmer, Carlile (BIB6) 1992; 53–56 Linsley, Owen, Hayatee (BIB10) 1970; 4 Durand, Taillades, Pradel, Ribes, Badot, Belhadj-Tahar (BIB9) 1994; 172–174 Bunde, Ingram, Maass (BIB4) 1994; 172–174 Hoppe, Kloidt, Funke (BIB5) 1991; 95 Funke (BIB2) 1991; 210 |
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| Snippet | In this paper we present conductivity spectra of the ion conducting glasses B
2O
3 · 0.56Li
2O · 0.45LiBr and Ag
2S · GeS
2 and of the polaron conducting glass... In this paper we present conductivity spectra of the ion conducting glasses B sub(2)O sub(3) multiplied by 0.56Li sub(2)O multiplied by 0.45LiBr and Ag sub(2)S... |
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| SubjectTerms | Condensed matter: structure, mechanical and thermal properties Diffusion in solids Exact sciences and technology Ion conducting glasses Ionic hopping Physics Polaronic hopping Self-diffusion and ionic conduction in nonmetals Transport properties of condensed matter (nonelectronic) |
| Title | Ionic and polaronic hopping in glass |
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