Multielectron C-H photoactivation with an Sb(v) oxo corrole

Pnictogen complexes are ideal for mediating multi-electron chemical reactions in two-electron steps. We report an Sb(v) bis-μ-oxo corrole that photochemically oxidises the C-H bonds of organic substrates. In the case of toluene, the substrate is oxidised to benzaldehyde, a rare example of a four-ele...

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Bibliographic Details

Published in:	Chemical communications (Cambridge, England) Vol. 56; no. 39; p. 5247
Main Authors:	Lemon, Christopher M, Maher, Andrew G, Mazzotti, Anthony R, Powers, David C, Gonzalez, Miguel I, Nocera, Daniel G
Format:	Journal Article
Language:	English
Published:	England 14-05-2020
Subjects:	Antimony - chemistry Benzaldehydes - chemistry Electrons Models, Molecular Molecular Structure Oxidation-Reduction Photochemical Processes Porphyrins - chemistry
Online Access:	Get more information
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