Multielectron C-H photoactivation with an Sb(v) oxo corrole
Pnictogen complexes are ideal for mediating multi-electron chemical reactions in two-electron steps. We report an Sb(v) bis-μ-oxo corrole that photochemically oxidises the C-H bonds of organic substrates. In the case of toluene, the substrate is oxidised to benzaldehyde, a rare example of a four-ele...
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| Published in: | Chemical communications (Cambridge, England) Vol. 56; no. 39; p. 5247 |
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| Main Authors: | , , , , , |
| Format: | Journal Article |
| Language: | English |
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England
14-05-2020
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| Abstract | Pnictogen complexes are ideal for mediating multi-electron chemical reactions in two-electron steps. We report an Sb(v) bis-μ-oxo corrole that photochemically oxidises the C-H bonds of organic substrates. In the case of toluene, the substrate is oxidised to benzaldehyde, a rare example of a four-electron photoreaction. |
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| AbstractList | Pnictogen complexes are ideal for mediating multi-electron chemical reactions in two-electron steps. We report an Sb(v) bis-μ-oxo corrole that photochemically oxidises the C-H bonds of organic substrates. In the case of toluene, the substrate is oxidised to benzaldehyde, a rare example of a four-electron photoreaction. |
| Author | Powers, David C Nocera, Daniel G Lemon, Christopher M Gonzalez, Miguel I Maher, Andrew G Mazzotti, Anthony R |
| Author_xml | – sequence: 1 givenname: Christopher M surname: Lemon fullname: Lemon, Christopher M email: dnocera@fas.harvard.edu organization: Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford St., Cambridge, MA 02138, USA. dnocera@fas.harvard.edu – sequence: 2 givenname: Andrew G surname: Maher fullname: Maher, Andrew G – sequence: 3 givenname: Anthony R surname: Mazzotti fullname: Mazzotti, Anthony R – sequence: 4 givenname: David C surname: Powers fullname: Powers, David C – sequence: 5 givenname: Miguel I surname: Gonzalez fullname: Gonzalez, Miguel I – sequence: 6 givenname: Daniel G surname: Nocera fullname: Nocera, Daniel G |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/32270146$$D View this record in MEDLINE/PubMed |
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| CitedBy_id | crossref_primary_10_1016_j_mcat_2021_112063 crossref_primary_10_1039_D4CC00675E crossref_primary_10_1021_acs_inorgchem_2c02285 crossref_primary_10_1021_acs_inorgchem_3c02778 crossref_primary_10_1021_jacs_4c01748 crossref_primary_10_1002_ejic_202300283 crossref_primary_10_1039_D1CC00105A crossref_primary_10_1021_jacsau_2c00255 crossref_primary_10_1002_aoc_7088 crossref_primary_10_1039_D3GC04884E crossref_primary_10_1002_ange_202306598 crossref_primary_10_1002_anie_202306598 crossref_primary_10_1515_pac_2020_0703 |
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| Snippet | Pnictogen complexes are ideal for mediating multi-electron chemical reactions in two-electron steps. We report an Sb(v) bis-μ-oxo corrole that photochemically... |
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| SubjectTerms | Antimony - chemistry Benzaldehydes - chemistry Electrons Models, Molecular Molecular Structure Oxidation-Reduction Photochemical Processes Porphyrins - chemistry |
| Title | Multielectron C-H photoactivation with an Sb(v) oxo corrole |
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