Miscibility studies of the blends of chitosan with some cellulose ethers

The polymeric films have been prepared based on blends of chitosan with two cellulose ethers—hydroxypropylmethylcellulose and methylcellulose by casting from acetic acid solutions. The films were transparent and brittle in a dry state but an immersion of the samples in deionized water for over 24 h...

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Published in:Carbohydrate polymers Vol. 63; no. 2; pp. 238 - 244
Main Authors: Yin, Jingbo, Luo, Kun, Chen, Xuesi, Khutoryanskiy, Vitaliy V.
Format: Journal Article
Language:English
Published: Oxford Elsevier Ltd 03-02-2006
Elsevier Science
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Abstract The polymeric films have been prepared based on blends of chitosan with two cellulose ethers—hydroxypropylmethylcellulose and methylcellulose by casting from acetic acid solutions. The films were transparent and brittle in a dry state but an immersion of the samples in deionized water for over 24 h leads to their disintegration or partial dissolution. The miscibility of the polymers in the blends has been assessed by infrared spectroscopy, wide-angle X-ray diffraction, scanning electron microscopy and thermal gravimetric analysis. It was shown that although weak hydrogen bonding exists between the polymer functional groups the blends are not fully miscible in a dry state.
AbstractList The polymeric films have been prepared based on blends of chitosan with two cellulose ethers-hydroxypropylmethylcellulose and methylcellulose by casting from acetic acid solutions. The films were transparent and brittle in a dry state but an immersion of the samples in deionized water for over 24 h leads to their disintegration or partial dissolution. The miscibility of the polymers in the blends has been assessed by infrared spectroscopy, wide-angle X-ray diffraction, scanning electron microscopy and thermal gravimetric analysis. It was shown that although weak hydrogen bonding exists between the polymer functional groups the blends are not fully miscible in a dry state.
The polymeric films have been prepared based on blends of chitosan with two cellulose ethers—hydroxypropylmethylcellulose and methylcellulose by casting from acetic acid solutions. The films were transparent and brittle in a dry state but an immersion of the samples in deionized water for over 24 h leads to their disintegration or partial dissolution. The miscibility of the polymers in the blends has been assessed by infrared spectroscopy, wide-angle X-ray diffraction, scanning electron microscopy and thermal gravimetric analysis. It was shown that although weak hydrogen bonding exists between the polymer functional groups the blends are not fully miscible in a dry state.
Author Yin, Jingbo
Chen, Xuesi
Luo, Kun
Khutoryanskiy, Vitaliy V.
Author_xml – sequence: 1
  givenname: Jingbo
  surname: Yin
  fullname: Yin, Jingbo
  email: jbyin@staff.shu.edu.cn
  organization: Department of Polymer Materials, Shanghai University, 20 Chengzhong Street, Jiading, Shanghai, 201800, China
– sequence: 2
  givenname: Kun
  surname: Luo
  fullname: Luo, Kun
  organization: Department of Polymer Materials, Shanghai University, 20 Chengzhong Street, Jiading, Shanghai, 201800, China
– sequence: 3
  givenname: Xuesi
  surname: Chen
  fullname: Chen, Xuesi
  organization: State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, China
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  givenname: Vitaliy V.
  surname: Khutoryanskiy
  fullname: Khutoryanskiy, Vitaliy V.
  email: v.khutoryanskiy@reading.ac.uk
  organization: School of Pharmacy, University of Reading, Whiteknights, P.O. Box 224, Reading RG6 6AD, UK
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Issue 2
Keywords Miscibility
Hydrophilic films
Blends
Chitosan
Cellulose ethers
Polymer blends
Cellulose(methyl)
Experimental study
Thermal stability
Morphology
Oside polymer
Thermodynamic properties
Cellulose ether
Hydrogen bond
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Snippet The polymeric films have been prepared based on blends of chitosan with two cellulose ethers—hydroxypropylmethylcellulose and methylcellulose by casting from...
The polymeric films have been prepared based on blends of chitosan with two cellulose ethers-hydroxypropylmethylcellulose and methylcellulose by casting from...
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SubjectTerms Applied sciences
Blends
cellulose
Cellulose and derivatives
Cellulose ethers
Chitosan
composite polymers
Exact sciences and technology
films (materials)
Hydrophilic films
Miscibility
Natural polymers
Physicochemistry of polymers
thermal analysis
ultrastructure
Title Miscibility studies of the blends of chitosan with some cellulose ethers
URI https://dx.doi.org/10.1016/j.carbpol.2005.08.041
Volume 63
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