Development of a novel phosphorus recovery system using incinerated sewage sludge ash (ISSA) and phosphorus-selective adsorbent

[Display omitted] •Phosphorus recovery from incinerated sewage sludge ash was investigated.•Zirconium-based adsorbent can efficiently purify phosphorus from the acid leachate.•More than 70% of phosphorus in ISSA was recovered with high purity.•Risk of trace elements (As, Cr, Cd, Pb) during phosphoru...

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Published in:Waste management (Elmsford) Vol. 120; pp. 41 - 49
Main Authors: Yu, Xiaolong, Nakamura, Yousuke, Otsuka, Masanari, Omori, Daisuke, Haruta, Shinsuke
Format: Journal Article
Language:English
Published: United States Elsevier Ltd 01-02-2021
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Abstract [Display omitted] •Phosphorus recovery from incinerated sewage sludge ash was investigated.•Zirconium-based adsorbent can efficiently purify phosphorus from the acid leachate.•More than 70% of phosphorus in ISSA was recovered with high purity.•Risk of trace elements (As, Cr, Cd, Pb) during phosphorus recovery process was low.•Several strategies were proposed to reduce the costs in the full-scale application. Phosphorus is an essential nutrient but faces foreseeable resource depletion. The incinerated sewage sludge ash (ISSA) is a promising source for recovering phosphorus. In this study, we proposed a new system for recovering phosphorus from ISSA. This innovative system uses phosphorus-selective adsorbent to purify phosphorus from the ISSA acid leachate. Laboratory scale batch and column tests were performed to demonstrate the feasibility of the system. Note that >70% of phosphorus in ISSA can be recovered as a high-purity recovery product. The product showed a structure similar to hydroxyapatite (Ca5(PO4)3OH). The total amount of Ca, P, and O in the product was above 90 wt%. The content of trace elements (As, Cd, Cr, and Pb) in the product was below the fertilizer limits, suggesting that the health and environmental risks of using fertilizer in agriculture are negligible. The expected costs of the system were estimated. The reusability of the adsorbent can reduce the operational costs to a satisfactory level. This study provides a practical alternative for recovering phosphorus from ISSA.
AbstractList Phosphorus is an essential nutrient but faces foreseeable resource depletion. The incinerated sewage sludge ash (ISSA) is a promising source for recovering phosphorus. In this study, we proposed a new system for recovering phosphorus from ISSA. This innovative system uses phosphorus-selective adsorbent to purify phosphorus from the ISSA acid leachate. Laboratory scale batch and column tests were performed to demonstrate the feasibility of the system. Note that >70% of phosphorus in ISSA can be recovered as a high-purity recovery product. The product showed a structure similar to hydroxyapatite (Ca (PO ) OH). The total amount of Ca, P, and O in the product was above 90 wt%. The content of trace elements (As, Cd, Cr, and Pb) in the product was below the fertilizer limits, suggesting that the health and environmental risks of using fertilizer in agriculture are negligible. The expected costs of the system were estimated. The reusability of the adsorbent can reduce the operational costs to a satisfactory level. This study provides a practical alternative for recovering phosphorus from ISSA.
[Display omitted] •Phosphorus recovery from incinerated sewage sludge ash was investigated.•Zirconium-based adsorbent can efficiently purify phosphorus from the acid leachate.•More than 70% of phosphorus in ISSA was recovered with high purity.•Risk of trace elements (As, Cr, Cd, Pb) during phosphorus recovery process was low.•Several strategies were proposed to reduce the costs in the full-scale application. Phosphorus is an essential nutrient but faces foreseeable resource depletion. The incinerated sewage sludge ash (ISSA) is a promising source for recovering phosphorus. In this study, we proposed a new system for recovering phosphorus from ISSA. This innovative system uses phosphorus-selective adsorbent to purify phosphorus from the ISSA acid leachate. Laboratory scale batch and column tests were performed to demonstrate the feasibility of the system. Note that >70% of phosphorus in ISSA can be recovered as a high-purity recovery product. The product showed a structure similar to hydroxyapatite (Ca5(PO4)3OH). The total amount of Ca, P, and O in the product was above 90 wt%. The content of trace elements (As, Cd, Cr, and Pb) in the product was below the fertilizer limits, suggesting that the health and environmental risks of using fertilizer in agriculture are negligible. The expected costs of the system were estimated. The reusability of the adsorbent can reduce the operational costs to a satisfactory level. This study provides a practical alternative for recovering phosphorus from ISSA.
Author Omori, Daisuke
Nakamura, Yousuke
Yu, Xiaolong
Otsuka, Masanari
Haruta, Shinsuke
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  givenname: Daisuke
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  fullname: Haruta, Shinsuke
  email: haruta@agr.ehime-u.ac.jp
  organization: Graduate School of Agriculture, Ehime University, Tarumi 3-5-7, Matsuyama, Ehime 790-8566, Japan
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Keywords Sewage sludge ash
Trace elements
Phosphorus recovery
Adsorbent
Fertilizer
Language English
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Snippet [Display omitted] •Phosphorus recovery from incinerated sewage sludge ash was investigated.•Zirconium-based adsorbent can efficiently purify phosphorus from...
Phosphorus is an essential nutrient but faces foreseeable resource depletion. The incinerated sewage sludge ash (ISSA) is a promising source for recovering...
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SubjectTerms Adsorbent
Fertilizer
Fertilizers
Incineration
Phosphorus
Phosphorus recovery
Sewage
Sewage sludge ash
Trace Elements
Title Development of a novel phosphorus recovery system using incinerated sewage sludge ash (ISSA) and phosphorus-selective adsorbent
URI https://dx.doi.org/10.1016/j.wasman.2020.11.017
https://www.ncbi.nlm.nih.gov/pubmed/33285373
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