Slow pyrolysis of waste polyethylene terephthalate yielding paraldehyde, ethylene glycol, benzoic acid and clean fuel
•The low-temperature slow pyrolysis of PET waste was studied.•This waste could be completely pyrolyzed at 25 °C min−1 to final temperature 400 °C.•An intensive thermal activation at a heating rate of 40 °C min−1 to 200 °C is needed.•Main components of obtained oil were paraldehyde, ethylene glycol,...
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| Published in: | Polymer degradation and stability Vol. 198; p. 109900 |
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| Main Authors: | , , |
| Format: | Journal Article |
| Language: | English |
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01-04-2022
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| Abstract | •The low-temperature slow pyrolysis of PET waste was studied.•This waste could be completely pyrolyzed at 25 °C min−1 to final temperature 400 °C.•An intensive thermal activation at a heating rate of 40 °C min−1 to 200 °C is needed.•Main components of obtained oil were paraldehyde, ethylene glycol, benzoic acid and benzoates.•All obtained products are well applicable in practice.
The low-temperature slow pyrolysis of PET waste was studied. After intensive thermal activation, the waste PET could be completely pyrolyzed at 25 °C min−1 to the final temperature of 400 °C. The main components of the resulting oil were paraldehyde (54.7 wt.%) and ethylene glycol (23.7 wt.%); further, benzoic acid and benzoates were obtained. Such products represent valuable intermediates for industrial use or other applications. In addition, the pyrolysis produced a solid carbonaceous residue, particularly usable as a low-ash and low-sulfur smokeless fuel (HHV 31.3, LHV 30.4 MJ kg−1). Thus, the low-temperature pyrolysis of PET waste yields products that are easy to put to use with no demands on the purity of the feedstock.
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| AbstractList | The low-temperature slow pyrolysis of PET waste was studied. After intensive thermal activation, the waste PET could be completely pyrolyzed at 25 °C min−1 to the final temperature of 400 °C. The main components of the resulting oil were paraldehyde (54.7 wt.%) and ethylene glycol (23.7 wt.%); further, benzoic acid and benzoates were obtained. Such products represent valuable intermediates for industrial use or other applications. In addition, the pyrolysis produced a solid carbonaceous residue, particularly usable as a low-ash and low-sulfur smokeless fuel (HHV 31.3, LHV 30.4 MJ kg−1). Thus, the low-temperature pyrolysis of PET waste yields products that are easy to put to use with no demands on the purity of the feedstock. •The low-temperature slow pyrolysis of PET waste was studied.•This waste could be completely pyrolyzed at 25 °C min−1 to final temperature 400 °C.•An intensive thermal activation at a heating rate of 40 °C min−1 to 200 °C is needed.•Main components of obtained oil were paraldehyde, ethylene glycol, benzoic acid and benzoates.•All obtained products are well applicable in practice. The low-temperature slow pyrolysis of PET waste was studied. After intensive thermal activation, the waste PET could be completely pyrolyzed at 25 °C min−1 to the final temperature of 400 °C. The main components of the resulting oil were paraldehyde (54.7 wt.%) and ethylene glycol (23.7 wt.%); further, benzoic acid and benzoates were obtained. Such products represent valuable intermediates for industrial use or other applications. In addition, the pyrolysis produced a solid carbonaceous residue, particularly usable as a low-ash and low-sulfur smokeless fuel (HHV 31.3, LHV 30.4 MJ kg−1). Thus, the low-temperature pyrolysis of PET waste yields products that are easy to put to use with no demands on the purity of the feedstock. [Display omitted] |
| ArticleNumber | 109900 |
| Author | Bičáková, Olga Straka, Pavel Šupová, Monika |
| Author_xml | – sequence: 1 givenname: Pavel surname: Straka fullname: Straka, Pavel email: straka@irsm.cas.cz – sequence: 2 givenname: Olga surname: Bičáková fullname: Bičáková, Olga – sequence: 3 givenname: Monika surname: Šupová fullname: Šupová, Monika |
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| Keywords | Benzoic acid Waste PET Pyrolysis Ethylene glycol Paraldehyde Clean fuel |
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| Snippet | •The low-temperature slow pyrolysis of PET waste was studied.•This waste could be completely pyrolyzed at 25 °C min−1 to final temperature 400 °C.•An intensive... The low-temperature slow pyrolysis of PET waste was studied. After intensive thermal activation, the waste PET could be completely pyrolyzed at 25 °C min−1 to... |
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| SubjectTerms | Antifreeze solutions Benzoates Benzoic acid Clean fuel Clean fuels Ethylene glycol Industrial applications Low temperature Low temperature physics Paraldehyde Polyethylene terephthalate Pyrolysis Raw materials Waste PET |
| Title | Slow pyrolysis of waste polyethylene terephthalate yielding paraldehyde, ethylene glycol, benzoic acid and clean fuel |
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