Luminescence Lifetime Temperature Sensing Based on Sol-Gels and Poly(acrylonitrile)s Dyed with Ruthenium Metal-Ligand Complexes

Temperature‐sensitive materials based on the temperature probe ruthenium‐tris‐1,10‐phenathroline (Ru(phen)) are presented. As its luminescence, the intensity and decay time of which are both temperature sensitive, is quenched by oxygen, Ru(phen) needs to be encapsulated in materials with very low pe...

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Bibliographic Details
Published in:Advanced materials (Weinheim) Vol. 11; no. 15; pp. 1296 - 1299
Main Authors: Liebsch, G., Klimant, I., Wolfbeis, O. S.
Format: Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag GmbH 01-10-1999
WILEY‐VCH Verlag GmbH
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Summary:Temperature‐sensitive materials based on the temperature probe ruthenium‐tris‐1,10‐phenathroline (Ru(phen)) are presented. As its luminescence, the intensity and decay time of which are both temperature sensitive, is quenched by oxygen, Ru(phen) needs to be encapsulated in materials with very low permeability to molecular oxygen. Its incorporation into sol‐gels and poly(acrylonitrile)s (PANs) is investigated here and it is shown that the resulting materials can be deposited onto optical fibers for use as temperature optodes.
Bibliography:ark:/67375/WNG-DC7C9LMM-P
ArticleID:ADMA1296
istex:9BF8722B82D805CB441483A9EDE7828CDF0D0C61
ISSN:0935-9648
1521-4095
DOI:10.1002/(SICI)1521-4095(199910)11:15<1296::AID-ADMA1296>3.0.CO;2-B