Rheological and Structural Investigation of Layered Silicate Nanocomposites Based on Polyamide or Polyethylene: Influence of Processing Conditions and Volume Fraction Effects

Organoclay polymer nanocomposites offer improved material properties at very low filler loadings making them of immediate interest for industrial applications. In this study two matrices are used : a polar polymer, PA12, and a non polar polymer, LLDPE. Many articles focused on the importance of the...

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Published in:	Macromolecular symposia. Vol. 221; no. 1; pp. 75 - 84
Main Authors:	Médéric, Pascal, Razafinimaro, Tolotrahasina, Aubry, Thierry, Moan, Michel, Klopffer, Marie-Hélène
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 01-01-2005 WILEY‐VCH Verlag
Subjects:	Clay (material) layered silicates Matrices Nanocomposites polyamide Polyamide resins polyethylene Polyethylenes processing conditions Rheological properties rheology Silicates Volume fraction
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Abstract	Organoclay polymer nanocomposites offer improved material properties at very low filler loadings making them of immediate interest for industrial applications. In this study two matrices are used : a polar polymer, PA12, and a non polar polymer, LLDPE. Many articles focused on the importance of the chemistry used to modify the surface of the clay. Numerous papers studied the influence of the compatibilizing agent necessary to obtain intercalated structure, when the matrix is non polar. This paper demonstrates the importance of the way the clay was melt processed into the thermoplastic matrix. Layered silicate nanocomposites based on PA12 or LLDPE were characterized by X‐ray diffraction, transmission electron microscopy and rheological tests. The influence of volume fraction on rheological and structural properties is also investigated.
AbstractList	Organoclay polymer nanocomposites offer improved material properties at very low filler loadings making them of immediate interest for industrial applications. In this study two matrices are used : a polar polymer, PA12, and a non polar polymer, LLDPE. Many articles focused on the importance of the chemistry used to modify the surface of the clay. Numerous papers studied the influence of the compatibilizing agent necessary to obtain intercalated structure, when the matrix is non polar. This paper demonstrates the importance of the way the clay was melt processed into the thermoplastic matrix. Layered silicate nanocomposites based on PA12 or LLDPE were characterized by X-ray diffraction, transmission electron microscopy and rheological tests. The influence of volume fraction on rheological and structural properties is also investigated.
Author	Moan, Michel Médéric, Pascal Razafinimaro, Tolotrahasina Aubry, Thierry Klopffer, Marie-Hélène
Author_xml	– sequence: 1 givenname: Pascal surname: Médéric fullname: Médéric, Pascal email: pascal.mederic@univ-brest.fr organization: Laboratoire de Rhéologie, Université de Bretagne Occidentale, 6, avenue Victor Le Gorgeu, C.S. 93837, 29238 Brest cedex 3, France, Fax: 33 2 98 01 79 30 – sequence: 2 givenname: Tolotrahasina surname: Razafinimaro fullname: Razafinimaro, Tolotrahasina organization: Laboratoire de Rhéologie, Université de Bretagne Occidentale, 6, avenue Victor Le Gorgeu, C.S. 93837, 29238 Brest cedex 3, France, Fax: 33 2 98 01 79 30 – sequence: 3 givenname: Thierry surname: Aubry fullname: Aubry, Thierry organization: Laboratoire de Rhéologie, Université de Bretagne Occidentale, 6, avenue Victor Le Gorgeu, C.S. 93837, 29238 Brest cedex 3, France, Fax: 33 2 98 01 79 30 – sequence: 4 givenname: Michel surname: Moan fullname: Moan, Michel organization: Laboratoire de Rhéologie, Université de Bretagne Occidentale, 6, avenue Victor Le Gorgeu, C.S. 93837, 29238 Brest cedex 3, France, Fax: 33 2 98 01 79 30 – sequence: 5 givenname: Marie-Hélène surname: Klopffer fullname: Klopffer, Marie-Hélène organization: Institut Français du Pétrole, B.P. 311, 1-4 avenue Bois-Préau, 92506 Rueil-Malmaison, France
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SubjectTerms	Clay (material) layered silicates Matrices Nanocomposites polyamide Polyamide resins polyethylene Polyethylenes processing conditions Rheological properties rheology Silicates Volume fraction
Title	Rheological and Structural Investigation of Layered Silicate Nanocomposites Based on Polyamide or Polyethylene: Influence of Processing Conditions and Volume Fraction Effects
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