Equations of State for n-Hexadecane and n-Docosane
Equations of state for n -hexadecane (C 16 H 34 ) and n -docosane (C 22 H 46 ) have been developed as functions of the Helmholtz energy with independent variables of temperature and density. The equations were developed based on experimental values of density, speed of sound, isobaric heat capacity,...
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| Published in: | International journal of thermophysics Vol. 43; no. 10 |
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| Main Authors: | , |
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| Language: | English |
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| Abstract | Equations of state for
n
-hexadecane (C
16
H
34
) and
n
-docosane (C
22
H
46
) have been developed as functions of the Helmholtz energy with independent variables of temperature and density. The equations were developed based on experimental values of density, speed of sound, isobaric heat capacity, and vapor pressure. With these equations, all thermodynamic properties of
n
-hexadecane and
n
-docosane can be calculated. For
n
-hexadecane, the uncertainty in vapor pressure is 0.5 %. The uncertainty of the saturated liquid density is 0.05 % from the triple point up to 400 K, and 0.2 % at higher temperatures. The uncertainty in densities is within 0.5 %. The speed of sound and isobaric heat capacity can be calculated within 0.25 %. The uncertainties of the properties calculated with the equation for
n
-docosane are 5 % for vapor pressure, 0.1 % for saturated liquid density, 1 % for density, 0.5 % and 1 % for speed of sound at atmospheric pressure and higher pressures, respectively, and within 3 % for heat capacity. |
|---|---|
| AbstractList | Equations of state for
n
-hexadecane (C
16
H
34
) and
n
-docosane (C
22
H
46
) have been developed as functions of the Helmholtz energy with independent variables of temperature and density. The equations were developed based on experimental values of density, speed of sound, isobaric heat capacity, and vapor pressure. With these equations, all thermodynamic properties of
n
-hexadecane and
n
-docosane can be calculated. For
n
-hexadecane, the uncertainty in vapor pressure is 0.5 %. The uncertainty of the saturated liquid density is 0.05 % from the triple point up to 400 K, and 0.2 % at higher temperatures. The uncertainty in densities is within 0.5 %. The speed of sound and isobaric heat capacity can be calculated within 0.25 %. The uncertainties of the properties calculated with the equation for
n
-docosane are 5 % for vapor pressure, 0.1 % for saturated liquid density, 1 % for density, 0.5 % and 1 % for speed of sound at atmospheric pressure and higher pressures, respectively, and within 3 % for heat capacity. Equations of state for n-hexadecane (C16H34) and n-docosane (C22H46) have been developed as functions of the Helmholtz energy with independent variables of temperature and density. The equations were developed based on experimental values of density, speed of sound, isobaric heat capacity, and vapor pressure. With these equations, all thermodynamic properties of n-hexadecane and n-docosane can be calculated. For n-hexadecane, the uncertainty in vapor pressure is 0.5 %. The uncertainty of the saturated liquid density is 0.05 % from the triple point up to 400 K, and 0.2 % at higher temperatures. The uncertainty in densities is within 0.5 %. The speed of sound and isobaric heat capacity can be calculated within 0.25 %. The uncertainties of the properties calculated with the equation for n-docosane are 5 % for vapor pressure, 0.1 % for saturated liquid density, 1 % for density, 0.5 % and 1 % for speed of sound at atmospheric pressure and higher pressures, respectively, and within 3 % for heat capacity. |
| ArticleNumber | 146 |
| Author | Lemmon, Eric W. Romeo, Raffaella |
| Author_xml | – sequence: 1 givenname: Raffaella orcidid: 0000-0002-3012-8094 surname: Romeo fullname: Romeo, Raffaella email: r.romeo@inrim.it organization: Istituto Nazionale di Ricerca Metrologica – sequence: 2 givenname: Eric W. surname: Lemmon fullname: Lemmon, Eric W. organization: Applied Chemicals and Materials Division, National Institute of Standards and Technology |
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| CitedBy_id | crossref_primary_10_1063_5_0191228 crossref_primary_10_1007_s10765_023_03289_w crossref_primary_10_1021_acs_iecr_2c04238 crossref_primary_10_1007_s10765_022_03143_5 crossref_primary_10_1007_s10765_023_03266_3 crossref_primary_10_1007_s10765_022_03153_3 crossref_primary_10_1007_s10765_024_03360_0 |
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| Keywords | Helmholtz energy Equations of state Thermodynamic properties hexadecane docosane |
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| Snippet | Equations of state for
n
-hexadecane (C
16
H
34
) and
n
-docosane (C
22
H
46
) have been developed as functions of the Helmholtz energy with independent... Equations of state for n-hexadecane (C16H34) and n-docosane (C22H46) have been developed as functions of the Helmholtz energy with independent variables of... |
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| SubjectTerms | Classical Mechanics Condensed Matter Physics Density Equations of state Geophysics Hexadecane Independent variables Industrial Chemistry/Chemical Engineering Mathematical analysis Physical Chemistry Physics Physics and Astronomy Sound Specific heat Thermodynamic properties Thermodynamics Uncertainty Vapor pressure |
| Title | Equations of State for n-Hexadecane and n-Docosane |
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