Far ultraviolet reflectance variation of MgF2-protected aluminum films under controlled exposure to the main components of the atmosphere

• Published in: Thin solid films Vol. 497; no. 1-2; pp. 249 - 253
• Main Authors: Fernández-Perea, M., Aznárez, J.A., Calvo-Angós, J., Larruquert, J.I., Méndez, J.A.
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 21-02-2006; Elsevier Science
• Subjects: Aluminum; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Evaporation; Exact sciences and technology; Fluorides; Optical coatings; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation; Other nonmetallic inorganics; Other nonmetals; Physics; Visible and ultraviolet spectra; Evaporation; Fluorides; Aluminum; Optical coatings; Inorganic compounds; Physical radiation effects; Controlled atmospheres; Binary compounds; Aluminium; Magnesium fluorides; Experimental study; Transmittance; Coated material; Thin films; Degradation; Reflectivity; Ultraviolet radiation
• ISSN: 0040-6090; 1879-2731
• DOI: 10.1016/j.tsf.2005.10.074

Far ultraviolet (FUV) reflectance measurements on in situ deposited MgF2-overcoated aluminum films and on the same films after exposure to controlled doses of air show that a reflectance degradation up to 10% takes place due to exposure. We applied increasing doses of molecular nitrogen, molecular oxygen and water vapor in order to identify the components of the atmosphere which are responsible for the variation mentioned above. Results show that doses larger than 104 L of both molecular oxygen and water vapor produce a reflectance decrease. On the other hand molecular nitrogen doses up to 106 L do not modify reflectance at all. Additional FUV transmittance measurements on MgF2 films deposited onto crystalline MgF2 substrates also showed a degradation behavior under similar gas exposures.