Preparation and characterization of a new sawdust/MNP/PEI nanocomposite and its applications for removing Pb (II) ions from aqueous solution

• Published in: Water science and technology Vol. 78; no. 12; pp. 2469 - 2480
• Main Authors: Ghasemi, Avat, Sohrabi, Mahmoud Reza, Motiee, Fereshteh
• Format: Journal Article
• Language: English
• Published: England IWA Publishing 01-12-2018
• Subjects: Adsorbents; Adsorption; Analytical methods; Aqueous solutions; Arsenic removal; Chemistry; Crosslinking; Desalination; Efficiency; Electron microscopy; Emulsion polymerization; Fourier transforms; Heavy metals; Independent variables; Infrared spectroscopy; Ions; Isotherms; Kinetics; Lead; Lead - analysis; Lead - chemistry; Lead content; Magnetite; Magnetometers; Membrane separation; Metals; Nanocomposites; Nanocomposites - chemistry; Nanoparticles; Nitrates; pH effects; Polyethyleneimine; Polymers; Removal; Sawdust; Scanning electron microscopy; Scientific imaging; Solutions; Sorbents; Spectroscopy, Fourier Transform Infrared; Water Pollutants, Chemical - analysis; Water Pollutants, Chemical - chemistry; Water Purification - methods; Water treatment; X-ray diffraction
• ISSN: 0273-1223; 1996-9732
• DOI: 10.2166/wst.2018.521

A new sawdust/magnetite nanoparticles/polyethyleneimine (SD/MNP/PEI) nanocomposite was synthesized by grafting polyethyleneimine (PEI) to magnetic sawdust. Features of SD/MNP/PEI were characterized using Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD), vibrating sample magnetometer (VSM) and scanning electron microscopy (SEM). SD/MNP/PEI was used as an adsorbent for the removal of lead (Pb (II)) from aqueous solution. The effects of independent variables including pH of solution, adsorbent dose and contact time were performed and adsorption isotherms were obtained. Experimental results show that priority effective variables were pH and the amount of nanocomposite, and it was found that the sorption capacity increases with the increasing phase contact time. The adsorption process followed the Langmuir adsorption isotherm. Although SD and SD/MNP do not show a high affinity for the adsorption of Pb (II) in aqueous media, polyethyleneimine cross-linked on SD/MNP showed 40 and 66% increases, respectively, in the adsorption of Pb (II) compared to the SD and SD/MNP. It was found that SD/MNP/PEI removes more efficiently lead ions from aqueous solutions than the SD, SD/MNP. Desorption of the lead from the SD/MNP/PEI was conducted. It was proved that SD/MNP/PEI has excellent properties and can be used as a sorbent of multi-use.