Synthesis of a New Macromonomer from 2-(Dimethylamino)ethyl Methacrylate Bearing 1-(Isopropenylphenyl)-1,1-dimethylmethyl Isocyanate Group

The telomerization of 2‐(dimethylamino)ethyl methacrylate (DMAEMA) with 2‐mercaptoethanol in acetonitrile shows that the telogen can react with the monomer by nucleophilic addition. It is to say that the tertiary amino group leads to nucleophilic addition rather than telomerization. The oligomers th...

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Bibliographic Details
Published in:	Macromolecular chemistry and physics Vol. 205; no. 5; pp. 645 - 655
Main Authors:	Boyer, Cyril, Boutevin, Gilles, Robin, Jean-Jacques, Boutevin, Bernard
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 01-03-2004 WILEY‐VCH Verlag Wiley
Subjects:	1-(isopropenylphenyl)-1 1-dimethyl methyl isocyanate 1‐(isopropenylphenyl)‐1,1‐dimethyl methyl isocyanate 2-(dimethylamino)ethyl methacrylate Applied sciences copolymerization Exact sciences and technology macromonomers Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts reactivity ratio Terpolymer Radical telomerization Organic isocyanate Methacrylate polymer Graft copolymer End group Solution copolymerization Experimental study Reactivity ratio Macromer Carbamoylation Chemical modification Mercaptoalcohol Amine polymer Preparation Styrene Hydroxyl group Methacrylate copolymer Radical copolymerization Amine copolymer Styrene(alpha-methyl) copolymer Styrene copolymer
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