N‐methyl‐2‐hydroxyethylammonium oleate ionic liquid performance as corrosion inhibitor for mild steel in hydrochloric acid medium

• Published in: Materials and corrosion Vol. 71; no. 11; pp. 1885 - 1902
• Main Authors: Schmitzhaus, Tobias E., Ortega Vega, Maria R., Schroeder, Roberto, Muller, Iduvirges L., Mattedi, Silvana, Malfatti, Célia de Fraga
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 01-11-2020
• Subjects: acid inhibitors; Adsorption; chemisorption; Chlorides; Contact angle; Corrosion; corrosion inhibitor; Corrosion inhibitors; Corrosion mechanisms; Hydrochloric acid; Ionic liquids; Low carbon steels; mild steel; Performance evaluation; Raman spectroscopy; Weight loss measurement
• ISSN: 0947-5117; 1521-4176
• DOI: 10.1002/maco.202011709

The aim of the present study is to evaluate the performance of N‐methyl‐2‐hydroxyethylammonium oleate ([m‐2HEA][Ol]) as a corrosion inhibitor for mild steel in a 0.1‐mol/L hydrochloric acid solution and also investigate the role of chloride in the inhibition mechanism. This protic ionic liquid (PIL) has formerly shown a high efficiency as a corrosion inhibitor in a neutral chloride medium. Electrochemical and weight loss measurements, surface contact angle determination, scanning electron microscopy, and Raman spectroscopy were used to understand the factors that influence the response of the studied inhibitor. Results revealed that [m‐2HEA][Ol] behaves as a mixed‐type adsorption inhibitor, by blocking cathodic sites and by modifying the activation energy of the anodic reaction, and it can reach up to 94–97% of inhibition efficiency. PIL adsorption was enhanced by the excess of positive charge of the mild steel. The effect of inhibitor molecule has been discussed to propose a mechanism that explains the inhibitory action of the corrosion inhibitor, pointing out the role of chloride in the inhibition mechanism.
The performance of N‐methyl‐2‐hydroxyethylammonium oleate ([m‐2HEA][Ol]) as a corrosion inhibitor for mild steel in a 0.1‐mol/L hydrochloric acid solution and the role of chloride in the inhibition mechanism were investigated in this paper. Results revealed that [m‐2HEA][Ol] behaves as a mixed‐type adsorption inhibitor, by blocking cathodic sites and by modifying the activation energy of the anodic reaction, and it can reach up to 94–97% of inhibition efficiency.