Synthesis and characterization of 1,3,5-tris((1/2H-tetrazol-5-yl)methyl)-1,3,5-triazinane-2,4,6-trione

• Published in: Chemical papers Vol. 71; no. 5; pp. 949 - 952
• Main Authors: Bayat, Yadollah, Hajighasemali, Fatemeh
• Format: Journal Article
• Language: English
• Published: Cham Springer International Publishing 01-05-2017
• Subjects: Biochemistry; Biotechnology; Chemistry; Chemistry and Materials Science; Chemistry/Food Science; Industrial Chemistry/Chemical Engineering; Materials Science; Medicinal Chemistry; Original Paper; Isocyanuric acid; Mass spectroscopy; DSC/TGA; Tetrazole; Alkylation
• ISSN: 2585-7290; 1336-9075
• DOI: 10.1007/s11696-016-0018-2

2,2′,2″-(2,4,6-Trioxo-1,3,5-triazinane-1,3,5-triyl) triacetonitrile
(
or tris-(cyanomethyl)-isocyanurate) and 1,3,5-tris((1/2
H
-tetrazol-5-yl)methyl)-1,3,5-triazinane-2,4,6-trione (or tris-(5-tetrazolylmethyl)-isocyanurate) were synthesized with new methods. High yields, simple methodology, and cheapness are advantages of the methods. Furthermore, 1,3,5-tris((1/2
H
-tetrazol-5-yl)methyl)-1,3,5-triazinane-2,4,6-trione was synthesized in the less hazardous condition. The compounds were characterized by elemental analysis, IR,
1
HNMR,
13
CNMR and mass spectroscopic analysis. In addition, DSC/TGA measurements were carried out to determine the thermal behavior of the final product.