Conversion of Oxygenates to Aromatic Hydrocarbons on a Commercial Zeolite Catalyst: Comparison of Ethanol and Dimethyl Ether

Conversion of oxygenates to aromatic hydrocarbons in the syngas medium in the presence of a commercial zeolite-containing catalyst was studied. The influence of pressure on aromatization of dimethyl ether and ethanol was examined. At 400°C, an increase in the pressure from 0.1 to 3.0–10.0 MPa leads...

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Published in:	Russian journal of applied chemistry Vol. 92; no. 7; pp. 918 - 923
Main Authors:	Golubev, K. B., Bedenko, S. P., Budnyak, A. D., Ilolov, A. M., Tret’yakov, V. F., Talyshinskii, R. M., Maksimov, A. L., Khadzhiev, S. N.
Format:	Journal Article
Language:	English
Published:	Moscow Pleiades Publishing 01-07-2019 Springer Nature B.V
Subjects:	Aromatic compounds Aromatic hydrocarbons Catalysis Catalysts Chemistry Chemistry and Materials Science Chemistry/Food Science Conversion Dimethyl ether Ethanol Hydrocarbons Industrial Chemistry/Chemical Engineering Isomers Selectivity Substrates Synthesis Synthesis gas Zeolites oxygenates zeolite catalyst selectivity dimethyl ether aromatic hydrocarbons pressure ethanol
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Abstract	Conversion of oxygenates to aromatic hydrocarbons in the syngas medium in the presence of a commercial zeolite-containing catalyst was studied. The influence of pressure on aromatization of dimethyl ether and ethanol was examined. At 400°C, an increase in the pressure from 0.1 to 3.0–10.0 MPa leads to a sharp increase in the yield of aromatic compounds. Dimethyl ether and ethanol, which are isomers belonging to different classes of compounds, were compared as substrates in conversion to aromatic hydrocarbons. At elevated pressure, dimethyl ether compared to ethanol exhibits higher selectivity in formation of the desired synthesis products, allowing synthesis of liquid hydrocarbons with increased content of arenes.
AbstractList	Conversion of oxygenates to aromatic hydrocarbons in the syngas medium in the presence of a commercial zeolite-containing catalyst was studied. The influence of pressure on aromatization of dimethyl ether and ethanol was examined. At 400°C, an increase in the pressure from 0.1 to 3.0–10.0 MPa leads to a sharp increase in the yield of aromatic compounds. Dimethyl ether and ethanol, which are isomers belonging to different classes of compounds, were compared as substrates in conversion to aromatic hydrocarbons. At elevated pressure, dimethyl ether compared to ethanol exhibits higher selectivity in formation of the desired synthesis products, allowing synthesis of liquid hydrocarbons with increased content of arenes.
Author	Budnyak, A. D. Maksimov, A. L. Khadzhiev, S. N. Golubev, K. B. Ilolov, A. M. Tret’yakov, V. F. Talyshinskii, R. M. Bedenko, S. P.
Author_xml	– sequence: 1 givenname: K. B. surname: Golubev fullname: Golubev, K. B. email: konstantin.golubev@ips.ac.ru organization: Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences – sequence: 2 givenname: S. P. surname: Bedenko fullname: Bedenko, S. P. organization: Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences – sequence: 3 givenname: A. D. surname: Budnyak fullname: Budnyak, A. D. organization: Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences – sequence: 4 givenname: A. M. surname: Ilolov fullname: Ilolov, A. M. organization: Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences – sequence: 5 givenname: V. F. surname: Tret’yakov fullname: Tret’yakov, V. F. organization: Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences – sequence: 6 givenname: R. M. surname: Talyshinskii fullname: Talyshinskii, R. M. organization: Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences – sequence: 7 givenname: A. L. surname: Maksimov fullname: Maksimov, A. L. organization: Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences – sequence: 8 givenname: S. N. surname: Khadzhiev fullname: Khadzhiev, S. N. organization: Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
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SubjectTerms	Aromatic compounds Aromatic hydrocarbons Catalysis Catalysts Chemistry Chemistry and Materials Science Chemistry/Food Science Conversion Dimethyl ether Ethanol Hydrocarbons Industrial Chemistry/Chemical Engineering Isomers Selectivity Substrates Synthesis Synthesis gas Zeolites
Title	Conversion of Oxygenates to Aromatic Hydrocarbons on a Commercial Zeolite Catalyst: Comparison of Ethanol and Dimethyl Ether
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