Effect of water vapor pressure on the phase composition of lithium monoaluminates formed in the interaction of aluminum hydroxide and lithium carbonate

It is shown that the partial water vapor pressure affects the phase composition of lithium monoaluminates formed when aluminum hydroxide (gibbsite) and lithium carbonate are heated in air, in the atmosphere of helium, and in a dynamic vacuum. When the mixture is heated to 800°C in an air atmosphere...

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Published in:	Russian journal of applied chemistry Vol. 90; no. 8; pp. 1219 - 1224
Main Authors:	Isupov, V. P., Bulina, N. V., Borodulina, I. A.
Format:	Journal Article
Language:	English
Published:	Moscow Pleiades Publishing 01-08-2017 Springer Nature B.V
Subjects:	Aluminum Aluminum base alloys Aluminum hydroxide Bayer process Chemistry Chemistry and Materials Science Chemistry/Food Science Gibbsite Helium Humidity Industrial Chemistry/Chemical Engineering Inorganic Synthesis and Industrial Inorganic Chemistry Lithium Lithium carbonate Phase composition Pressure effects Vapor pressure Vapors Water pressure Water vapor
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Abstract	It is shown that the partial water vapor pressure affects the phase composition of lithium monoaluminates formed when aluminum hydroxide (gibbsite) and lithium carbonate are heated in air, in the atmosphere of helium, and in a dynamic vacuum. When the mixture is heated to 800°C in an air atmosphere with partial water pressure of 1300 Pa, a nearly single-phase lithium monoaluminate α-LiAlO 2 is formed. In the reaction in the atmosphere of helium, in which the partial water vapor pressure does not exceed 4 Pa, γ-LiAlO 2 is formed together with α-LiAlO 2 , with the content of the former exceeding that produced in the reaction in air. When the mixture is heated under dynamic vacuum conditions with partial water vapor pressure lower than 0.1 Pa, mostly γ-LiAlO 2 is formed.
AbstractList	It is shown that the partial water vapor pressure affects the phase composition of lithium monoaluminates formed when aluminum hydroxide (gibbsite) and lithium carbonate are heated in air, in the atmosphere of helium, and in a dynamic vacuum. When the mixture is heated to 800°C in an air atmosphere with partial water pressure of 1300 Pa, a nearly single-phase lithium monoaluminate α-LiAlO2 is formed. In the reaction in the atmosphere of helium, in which the partial water vapor pressure does not exceed 4 Pa, γ-LiAlO2 is formed together with α-LiAlO2, with the content of the former exceeding that produced in the reaction in air. When the mixture is heated under dynamic vacuum conditions with partial water vapor pressure lower than 0.1 Pa, mostly γ-LiAlO2 is formed. It is shown that the partial water vapor pressure affects the phase composition of lithium monoaluminates formed when aluminum hydroxide (gibbsite) and lithium carbonate are heated in air, in the atmosphere of helium, and in a dynamic vacuum. When the mixture is heated to 800°C in an air atmosphere with partial water pressure of 1300 Pa, a nearly single-phase lithium monoaluminate α-LiAlO 2 is formed. In the reaction in the atmosphere of helium, in which the partial water vapor pressure does not exceed 4 Pa, γ-LiAlO 2 is formed together with α-LiAlO 2 , with the content of the former exceeding that produced in the reaction in air. When the mixture is heated under dynamic vacuum conditions with partial water vapor pressure lower than 0.1 Pa, mostly γ-LiAlO 2 is formed.
Author	Isupov, V. P. Borodulina, I. A. Bulina, N. V.
Author_xml	– sequence: 1 givenname: V. P. surname: Isupov fullname: Isupov, V. P. email: isupov@solid.nsc.ru organization: Institute of Solid State Chemistry, and Mechanochemistry, Siberian Branch, Russian Academy of Sciences – sequence: 2 givenname: N. V. surname: Bulina fullname: Bulina, N. V. organization: Institute of Solid State Chemistry, and Mechanochemistry, Siberian Branch, Russian Academy of Sciences – sequence: 3 givenname: I. A. surname: Borodulina fullname: Borodulina, I. A. organization: Institute of Solid State Chemistry, and Mechanochemistry, Siberian Branch, Russian Academy of Sciences
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SubjectTerms	Aluminum Aluminum base alloys Aluminum hydroxide Bayer process Chemistry Chemistry and Materials Science Chemistry/Food Science Gibbsite Helium Humidity Industrial Chemistry/Chemical Engineering Inorganic Synthesis and Industrial Inorganic Chemistry Lithium Lithium carbonate Phase composition Pressure effects Vapor pressure Vapors Water pressure Water vapor
Title	Effect of water vapor pressure on the phase composition of lithium monoaluminates formed in the interaction of aluminum hydroxide and lithium carbonate
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