Oxygen reduction on gold electrode in Li2CO3 / K2CO3 (62 / 38mol %) molten electrolyte: experimental and simulation analysis
A kinetic model of oxygen reduction at an inert electrode in a carbonate melt has been proposed. Combined with the thermodynamic calculations of the chemical equilibria in the carbonate melts and with the diffusivity values taken from the literature, the model was used to simulate kinetics of oxygen...
Saved in:
| Published in: | Electrochimica acta Vol. 182; pp. 61 - 66 |
|---|---|
| Main Authors: | , , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
Elsevier Ltd
10-11-2015
|
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Abstract | A kinetic model of oxygen reduction at an inert electrode in a carbonate melt has been proposed. Combined with the thermodynamic calculations of the chemical equilibria in the carbonate melts and with the diffusivity values taken from the literature, the model was used to simulate kinetics of oxygen reduction reaction at a gold electrode in the Li2CO3 / K2CO3 (62 / 38mol %) molten electrolyte under 0.33 О2+0.67 СО2 atmosphere at 923K for the case of coulostatic pulse perturbation. The simulation has shown that the partial exchange current of the O2− reduction step makes the largest contribution to the overall exchange current, and neutralization of the oxide ion by CO2 controls the rate of the overall electrode process. The total exchange current per one-electron electrode reaction was estimated as 83mA/cm2. The simulation has demonstrated satisfactory agreement with the experiment. |
|---|---|
| AbstractList | A kinetic model of oxygen reduction at an inert electrode in a carbonate melt has been proposed. Combined with the thermodynamic calculations of the chemical equilibria in the carbonate melts and with the diffusivity values taken from the literature, the model was used to simulate kinetics of oxygen reduction reaction at a gold electrode in the Li2CO3 / K2CO3 (62 / 38mol %) molten electrolyte under 0.33 О2+0.67 СО2 atmosphere at 923K for the case of coulostatic pulse perturbation. The simulation has shown that the partial exchange current of the O2− reduction step makes the largest contribution to the overall exchange current, and neutralization of the oxide ion by CO2 controls the rate of the overall electrode process. The total exchange current per one-electron electrode reaction was estimated as 83mA/cm2. The simulation has demonstrated satisfactory agreement with the experiment. |
| Author | Batalov, N.N. Konopelko, M.A. Nekrasov, V.N. Limanovskaya, O.V. Lystsov, A.A. |
| Author_xml | – sequence: 1 givenname: V.N. surname: Nekrasov fullname: Nekrasov, V.N. – sequence: 2 givenname: A.A. surname: Lystsov fullname: Lystsov, A.A. – sequence: 3 givenname: O.V. surname: Limanovskaya fullname: Limanovskaya, O.V. – sequence: 4 givenname: N.N. surname: Batalov fullname: Batalov, N.N. – sequence: 5 givenname: M.A. surname: Konopelko fullname: Konopelko, M.A. email: m.konopelko@inbox.ru |
| BookMark | eNqFUE1LAzEUDFLBtvobzEXQw26TTXez8SbFLyz0oueQTV5LSpotyVa64I83_cCr8GDeYWbevBmhgW89IHRLSU4JrSbrHBzoTqXJC0LLnIicTNkFGtKas4zVpRigISGUZdOqrq7QKMY1IYRXnAzRz2Lfr8DjAGanO9t6nGbVOoOPrqE1gK3Hc1vMFgxP8McR76si7azetA7fPeAEXfI4K1zfwSOG_RaC3YDvlMPKGxztZufU8YTyyvXRxmt0uVQuws0Zx-jr5flz9pbNF6_vs6d5pllZdBmUmpvG1KCZ0IUADkJzKJdUN-lFMiW04YpA2YiqWgpORd2ALhpqEgUMZ2yM-MlXhzbGAEu5TdFU6CUl8lCiXMu_EuWhREmETCUm5dNJCSnet4Ugo7bgNRgbEl-a1v7r8QvjpoEg |
| CitedBy_id | crossref_primary_10_1016_j_ijhydene_2017_10_171 crossref_primary_10_1016_j_molliq_2022_118979 crossref_primary_10_1016_j_ijhydene_2020_05_112 crossref_primary_10_1016_j_ijhydene_2016_03_121 crossref_primary_10_1002_bbb_2648 crossref_primary_10_1016_j_ijhydene_2016_08_067 crossref_primary_10_1016_j_jpowsour_2017_04_046 crossref_primary_10_1016_j_jpowsour_2021_229949 crossref_primary_10_1149_1945_7111_acb853 |
| Cites_doi | 10.1149/1.2798662 10.1016/j.apenergy.2012.01.060 10.1016/j.ijggc.2012.05.002 10.1149/2.031309jes 10.1016/j.jpowsour.2010.03.016 10.1016/j.jpowsour.2007.07.065 10.1016/j.jpowsour.2013.09.024 10.1016/0022-0728(96)04514-7 10.1016/S0013-4686(99)00305-9 10.1016/j.jpowsour.2010.04.084 10.1016/j.ijhydene.2011.09.096 10.1016/j.ijhydene.2013.08.144 10.1016/0013-4686(94)00328-X 10.1016/S0013-4686(01)00522-9 10.1016/0013-4686(93)85109-C 10.1016/0368-1874(72)80161-8 10.1016/j.molliq.2007.09.006 10.1149/1.2095891 10.1149/1.2086891 10.1016/0022-0728(92)80395-K 10.1016/0022-0728(95)04190-7 10.1149/1.2086614 10.1016/j.ijhydene.2011.11.006 10.1016/j.ijhydene.2013.11.039 10.1149/1.1764567 10.1016/S0013-4686(98)00070-X 10.1149/1.2054895 10.1016/0022-0728(74)80007-0 10.1016/j.jpowsour.2005.07.023 10.1016/0022-0728(93)80296-T 10.1021/ic00157a015 10.1016/j.memsci.2009.08.034 |
| ContentType | Journal Article |
| Copyright | 2015 Elsevier Ltd |
| Copyright_xml | – notice: 2015 Elsevier Ltd |
| DBID | AAYXX CITATION |
| DOI | 10.1016/j.electacta.2015.09.043 |
| DatabaseName | CrossRef |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering Chemistry |
| EISSN | 1873-3859 |
| EndPage | 66 |
| ExternalDocumentID | 10_1016_j_electacta_2015_09_043 S0013468615304552 |
| GroupedDBID | --K --M -~X .~1 0R~ 1B1 1RT 1~. 1~5 4.4 457 4G. 5GY 5VS 7-5 71M 8P~ 9JN AABNK AACTN AAEDT AAEDW AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AARLI AAXUO ABFNM ABFRF ABJNI ABMAC ABNUV ABYKQ ACBEA ACDAQ ACGFO ACGFS ACIWK ACNCT ACRLP ADBBV ADECG ADEWK ADEZE ADIYS AEBSH AEFWE AEKER AENEX AFKWA AFTJW AFZHZ AGHFR AGUBO AGYEJ AHHHB AHPOS AIEXJ AIKHN AITUG AJBFU AJOXV AJSZI AKURH ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ AXJTR BKOJK BLXMC CS3 DU5 EBS EFJIC EFLBG EJD ENUVR EO8 EO9 EP2 EP3 F5P FDB FIRID FLBIZ FNPLU FYGXN G-Q GBLVA IHE J1W KOM M36 M41 MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 RIG RNS ROL RPZ SDF SDG SDP SES SPC SPCBC SSG SSK SSZ T5K TWZ UPT WH7 XPP YK3 ZMT ~02 ~G- 29G 41~ 53G AAQXK AAXKI AAYXX ABEFU ABTAH ABXDB ACNNM ADMUD AFJKZ AI. AIDUJ AJQLL AKRWK ASPBG AVWKF AZFZN CITATION FEDTE FGOYB HMU HVGLF HZ~ H~9 LPU R2- SC5 SCB SCH SEW T9H VH1 WUQ XOL ZY4 |
| ID | FETCH-LOGICAL-c352t-e5c7dbd8ec39c29e7e9c7e5f1cb1870401b7a0e5b966f97198bec2b1d5f1ed733 |
| ISSN | 0013-4686 |
| IngestDate | Thu Sep 26 18:21:00 EDT 2024 Fri Feb 23 02:21:55 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Language | English |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c352t-e5c7dbd8ec39c29e7e9c7e5f1cb1870401b7a0e5b966f97198bec2b1d5f1ed733 |
| PageCount | 6 |
| ParticipantIDs | crossref_primary_10_1016_j_electacta_2015_09_043 elsevier_sciencedirect_doi_10_1016_j_electacta_2015_09_043 |
| PublicationCentury | 2000 |
| PublicationDate | 2015-11-10 |
| PublicationDateYYYYMMDD | 2015-11-10 |
| PublicationDate_xml | – month: 11 year: 2015 text: 2015-11-10 day: 10 |
| PublicationDecade | 2010 |
| PublicationTitle | Electrochimica acta |
| PublicationYear | 2015 |
| Publisher | Elsevier Ltd |
| Publisher_xml | – name: Elsevier Ltd |
| References | Janowitz, Kah, Wendt (bib0100) 1999; 45 Dunks, Stelman (bib0075) 1983; 22 Yamada, Nishina, Uchida, Selman (bib0120) 1993; 38 Milewski, Bujalski, Wołowicz, Futyma, Kucowski, Bernat (bib0020) 2014; 39 Reeve, Tseung (bib0130) 1996; 403 Kim, Jung, Song, Song, Ahn, Lee, Lee, Kang (bib0005) 2014; 39 Yamada, Nishina, Uchida (bib0125) 1995; 40 Discepoli, Cinti, Desideri, Penchini, Proietti (bib0015) 2012; 9 Bychin, Chupakhin, Batalov (bib0085) 1996; 32 Nishina, Uchida, Selman (bib0110) 1994; 141 Kunz, Murphy (bib0175) 1988; 135 Bieniasz, Tomczyk (bib0155) 1993; 353 Nekrasov, Terentiev, Batalov, Barbin, Konopelko (bib0160) 2002; 1 Bodén, Di, Lagergren, Lindbergh, Wang (bib0045) 2007; 172 Appleby, Nicholson (bib0070) 1974; 53 Nishina, Ohuchi, Yamada, Uchida (bib0150) 1996; 408 Wang, Ma, Zhu (bib0050) 2012; 37 Frangini, Scaccia (bib0140) 2004; 151 Mitsushima, Okuno, Kamiya, Ota (bib0135) 2007; 3 Rui, Anderson, Lin, Li (bib0040) 2009; 345 Nekrasov, Terentiev, Barbin, Moiseyev (bib0165) 2001; 4 Elleuch, Sahraoui, Boussetta, Halouani, Li (bib0060) 2014; 248 Falcucci, Jannelli, Minutillo, Ubertini, Han, Yoon, Nam (bib0010) 2012; 97 Lu, Selman (bib0115) 1992; 333 Lu, Selman (bib0170) 1990; 137 Tomczyk, Mosialek (bib0105) 2001; 46 Adanuvor, White, Appleby (bib0145) 1990; 137 Morita, Kawase, Mugikura, Asano (bib0055) 2010; 195 Pointon, Lakeman, Irvine, Bradley, Jain (bib0030) 2006; 162 Peelen, van Driel, Hemmes, de Wit (bib0095) 1998; 43 Cassir, McPhail, Moreno (bib0035) 2012; 37 Scaccia, Frangini, Dellepiane (bib0090) 2008; 138 Jia, Tian, Liu, Xia, Yu, Wang, Zhao, Li (bib0025) 2010; 195 Appleby, Nicholson (bib0065) 1972; 38 Gong, Li, Zhang, Tharp, Qin, Huang (bib0080) 2013; 160 Cassir (10.1016/j.electacta.2015.09.043_bib0035) 2012; 37 Tomczyk (10.1016/j.electacta.2015.09.043_bib0105) 2001; 46 Yamada (10.1016/j.electacta.2015.09.043_bib0120) 1993; 38 Morita (10.1016/j.electacta.2015.09.043_bib0055) 2010; 195 Bychin (10.1016/j.electacta.2015.09.043_bib0085) 1996; 32 Rui (10.1016/j.electacta.2015.09.043_bib0040) 2009; 345 Discepoli (10.1016/j.electacta.2015.09.043_bib0015) 2012; 9 Appleby (10.1016/j.electacta.2015.09.043_bib0065) 1972; 38 Kim (10.1016/j.electacta.2015.09.043_bib0005) 2014; 39 Pointon (10.1016/j.electacta.2015.09.043_bib0030) 2006; 162 Nishina (10.1016/j.electacta.2015.09.043_bib0150) 1996; 408 Reeve (10.1016/j.electacta.2015.09.043_bib0130) 1996; 403 Frangini (10.1016/j.electacta.2015.09.043_bib0140) 2004; 151 Scaccia (10.1016/j.electacta.2015.09.043_bib0090) 2008; 138 Bodén (10.1016/j.electacta.2015.09.043_bib0045) 2007; 172 Peelen (10.1016/j.electacta.2015.09.043_bib0095) 1998; 43 Lu (10.1016/j.electacta.2015.09.043_bib0115) 1992; 333 Bieniasz (10.1016/j.electacta.2015.09.043_bib0155) 1993; 353 Jia (10.1016/j.electacta.2015.09.043_bib0025) 2010; 195 Milewski (10.1016/j.electacta.2015.09.043_bib0020) 2014; 39 Mitsushima (10.1016/j.electacta.2015.09.043_bib0135) 2007; 3 Nekrasov (10.1016/j.electacta.2015.09.043_bib0160) 2002; 1 Nishina (10.1016/j.electacta.2015.09.043_bib0110) 1994; 141 Lu (10.1016/j.electacta.2015.09.043_bib0170) 1990; 137 Wang (10.1016/j.electacta.2015.09.043_bib0050) 2012; 37 Elleuch (10.1016/j.electacta.2015.09.043_bib0060) 2014; 248 Dunks (10.1016/j.electacta.2015.09.043_bib0075) 1983; 22 Kunz (10.1016/j.electacta.2015.09.043_bib0175) 1988; 135 Nekrasov (10.1016/j.electacta.2015.09.043_bib0165) 2001; 4 Falcucci (10.1016/j.electacta.2015.09.043_bib0010) 2012; 97 Yamada (10.1016/j.electacta.2015.09.043_bib0125) 1995; 40 Gong (10.1016/j.electacta.2015.09.043_bib0080) 2013; 160 Adanuvor (10.1016/j.electacta.2015.09.043_bib0145) 1990; 137 Appleby (10.1016/j.electacta.2015.09.043_bib0070) 1974; 53 Janowitz (10.1016/j.electacta.2015.09.043_bib0100) 1999; 45 |
| References_xml | – volume: 38 start-page: 497 year: 1972 ident: bib0065 article-title: Oxygen reduction in carbonate melts: Significance of the peroxide and superoxide ions publication-title: J. Electroanal. Chem contributor: fullname: Nicholson – volume: 39 start-page: 1558 year: 2014 ident: bib0020 article-title: Experimental investigation of CO publication-title: Int. J. Hydrogen Energy contributor: fullname: Bernat – volume: 195 start-page: 5581 year: 2010 ident: bib0025 article-title: A direct carbon fuel cell with (molten carbonate)/(doped ceria) composite electrolyte publication-title: J. Power Sources contributor: fullname: Li – volume: 46 start-page: 3023 year: 2001 ident: bib0105 article-title: Investigation of the oxygen electrode reaction in basic molten carbonates using electrochemical impedance spectroscopy publication-title: Electrochim. Acta contributor: fullname: Mosialek – volume: 40 start-page: 1927 year: 1995 ident: bib0125 article-title: Kinetic study of oxygen reduction in molten Li publication-title: Electrochim. Acta contributor: fullname: Uchida – volume: 160 start-page: F958 year: 2013 ident: bib0080 article-title: Molten carbonates as an effective oxygen reduction catalyst for 550-650 publication-title: J. Electrochem. Soc. contributor: fullname: Huang – volume: 138 start-page: 107 year: 2008 ident: bib0090 article-title: Enhanced O publication-title: J. Mol. Liq. contributor: fullname: Dellepiane – volume: 141 start-page: 1191 year: 1994 ident: bib0110 article-title: Gas Electrode Reactions in Molten Carbonate Media. Part V. Electrochemical Analysis of the Oxygen Reduction Mechanism at a Fully Immersed Gold Electrode publication-title: J. Electrochem. Soc. contributor: fullname: Selman – volume: 333 start-page: 257 year: 1992 ident: bib0115 article-title: Electrode kinetics of oxygen reduction on gold in molten carbonate publication-title: J. Electroanal. Chem. contributor: fullname: Selman – volume: 1 start-page: 3 year: 2002 ident: bib0160 article-title: On the possibility to estimate oxide ion equilibrium in mixtures of alkali metal carbonates by methods of molecular thermodynamics publication-title: Elektrokhimicheskaya Energetika contributor: fullname: Konopelko – volume: 9 start-page: 372 year: 2012 ident: bib0015 article-title: Carbon capture with molten carbonate fuel cells: Experimental tests and fuel cell performance assessment publication-title: Int. J. Greenhouse Gas Control contributor: fullname: Proietti – volume: 135 start-page: 1124 year: 1988 end-page: 1131 ident: bib0175 article-title: The Effect of Oxidant Composition on the Performance of Molten Carbonate Fuel Cells publication-title: J. Electrochem. Soc. contributor: fullname: Murphy – volume: 248 start-page: 44 year: 2014 ident: bib0060 article-title: 2-D numerical modeling and experimental investigation of electrochemical mechanisms coupled with heat and mass transfer in a planar direct carbon fuel cell publication-title: J. Power Sources contributor: fullname: Li – volume: 97 start-page: 734 year: 2012 ident: bib0010 article-title: Integrated numerical and experimental study of a MCFC-plasma gasifier energy system publication-title: Applied Energy contributor: fullname: Nam – volume: 38 start-page: 2405 year: 1993 ident: bib0120 article-title: Kinetic study of oxygen reduction in molten Li2CO publication-title: Electrochim. Acta contributor: fullname: Selman – volume: 37 start-page: 19417 year: 2012 ident: bib0050 article-title: State of the art ceria-carbonate composites (3C) electrolyte for advanced low temperature ceramic fuel cells (LTCFCs) publication-title: Int. J. Hydrogen Energy contributor: fullname: Zhu – volume: 4 start-page: 67 year: 2001 ident: bib0165 article-title: Thermodynamic modeling of mixtures of alkali metal carbonates in equilibrium with reducing gas medium (Н publication-title: Rasplavy contributor: fullname: Moiseyev – volume: 408 start-page: 181 year: 1996 ident: bib0150 article-title: Water effect on oxygen reduction in molten (Li publication-title: J. Electroanal. Chem. contributor: fullname: Uchida – volume: 45 start-page: 1025 year: 1999 ident: bib0100 article-title: Molten carbonate fuel cell research: Part I. Comparing cathodic oxygen reduction in lithium/potassium and lithium/sodium carbonate melts publication-title: Electrochim. Acta contributor: fullname: Wendt – volume: 162 start-page: 750 year: 2006 ident: bib0030 article-title: The development of a carbon–air semi fuel cell publication-title: J. Power Sources contributor: fullname: Jain – volume: 172 start-page: 520 year: 2007 ident: bib0045 article-title: Conductivity of SDC and (Li/Na) publication-title: J. Power Sources contributor: fullname: Wang – volume: 353 start-page: 195 year: 1993 ident: bib0155 article-title: Kinetics of the oxygen electrode reaction in molten Li publication-title: J. Electroanal. Chem. contributor: fullname: Tomczyk – volume: 137 start-page: 1125 year: 1990 ident: bib0170 article-title: Influence of Chemical Equilibria on Oxygen Reduction Reaction in Molten Carbonate publication-title: J. Electrochem. Soc. contributor: fullname: Selman – volume: 345 start-page: 110 year: 2009 ident: bib0040 article-title: Modeling and analysis of carbon dioxide permeation through ceramic-carbonate dual-phase membranes publication-title: J. Membrane Science contributor: fullname: Li – volume: 3 start-page: 195 year: 2007 ident: bib0135 article-title: Dependence of Oxygen Reduction Reaction on Temperature in (Li/Na/La)CO publication-title: ECS Transactions contributor: fullname: Ota – volume: 39 start-page: 1826 year: 2014 ident: bib0005 article-title: Optimization of molten carbonate fuel cell (MCFC) and homogeneous charge compression ignition (HCCI) engine hybrid system for distributed power generation publication-title: Int. J. Hydrogen Energy contributor: fullname: Kang – volume: 195 start-page: 6988 year: 2010 ident: bib0055 article-title: Degradation mechanism of molten carbonate fuel cell based on long-term performance: Long-term operation by using bench-scale cell and post-test analysis of the cell publication-title: J. Power Sources contributor: fullname: Asano – volume: 403 start-page: 69 year: 1996 ident: bib0130 article-title: Factors affecting the dissolution and reduction of oxygen in molten carbonate electrolytes. Part 1: Effect of temperature and alkali carbonate mixture publication-title: J. Electroanal. Chem. contributor: fullname: Tseung – volume: 22 start-page: 2168 year: 1983 ident: bib0075 article-title: Electrochemical studies of molten sodium carbonate publication-title: Inorg. Chem. contributor: fullname: Stelman – volume: 43 start-page: 3313 year: 1998 ident: bib0095 article-title: Study of the (electro) chemical equilibria in molten carbonate under MCFC cathode gas conditions. Part II: non-equilibrium study of (electro) chemical reactions involved in oxygen reduction in molten carbonate publication-title: Electrochim. Acta contributor: fullname: de Wit – volume: 151 start-page: A1251 year: 2004 ident: bib0140 article-title: Sensitive Determination of Oxygen Solubility in Alkali Carbonate Melts publication-title: J. Electrochem. Soc. contributor: fullname: Scaccia – volume: 37 start-page: 19345 year: 2012 ident: bib0035 article-title: Strategies and new developments in the field of molten carbonates and high-temperature fuel cells in the carbon cycle publication-title: International Journal of Hydrogen Energy contributor: fullname: Moreno – volume: 32 start-page: 365 year: 1996 ident: bib0085 article-title: Effect of cationic composition on the mechanism of the oxygen cathodic reduction in carbonate melts publication-title: Russ. J. Electrochem. contributor: fullname: Batalov – volume: 137 start-page: 2095 year: 1990 ident: bib0145 article-title: A Computer Simulation of the Oxygen Reduction Reaction in Carbonate Melts publication-title: J. Electrochem. Soc. contributor: fullname: Appleby – volume: 53 start-page: 105 year: 1974 ident: bib0070 article-title: The reduction of oxygen in molten lithium carbonate publication-title: J. Electroanal. Chem contributor: fullname: Nicholson – volume: 3 start-page: 195 year: 2007 ident: 10.1016/j.electacta.2015.09.043_bib0135 article-title: Dependence of Oxygen Reduction Reaction on Temperature in (Li/Na/La)CO3 publication-title: ECS Transactions doi: 10.1149/1.2798662 contributor: fullname: Mitsushima – volume: 97 start-page: 734 year: 2012 ident: 10.1016/j.electacta.2015.09.043_bib0010 article-title: Integrated numerical and experimental study of a MCFC-plasma gasifier energy system publication-title: Applied Energy doi: 10.1016/j.apenergy.2012.01.060 contributor: fullname: Falcucci – volume: 9 start-page: 372 year: 2012 ident: 10.1016/j.electacta.2015.09.043_bib0015 article-title: Carbon capture with molten carbonate fuel cells: Experimental tests and fuel cell performance assessment publication-title: Int. J. Greenhouse Gas Control doi: 10.1016/j.ijggc.2012.05.002 contributor: fullname: Discepoli – volume: 160 start-page: F958 year: 2013 ident: 10.1016/j.electacta.2015.09.043_bib0080 article-title: Molten carbonates as an effective oxygen reduction catalyst for 550-650°C solid oxide fuel cells publication-title: J. Electrochem. Soc. doi: 10.1149/2.031309jes contributor: fullname: Gong – volume: 195 start-page: 5581 year: 2010 ident: 10.1016/j.electacta.2015.09.043_bib0025 article-title: A direct carbon fuel cell with (molten carbonate)/(doped ceria) composite electrolyte publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2010.03.016 contributor: fullname: Jia – volume: 32 start-page: 365 year: 1996 ident: 10.1016/j.electacta.2015.09.043_bib0085 article-title: Effect of cationic composition on the mechanism of the oxygen cathodic reduction in carbonate melts publication-title: Russ. J. Electrochem. contributor: fullname: Bychin – volume: 172 start-page: 520 year: 2007 ident: 10.1016/j.electacta.2015.09.043_bib0045 article-title: Conductivity of SDC and (Li/Na)2CO3 composite electrolytes in reducing and oxidising atmospheres publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2007.07.065 contributor: fullname: Bodén – volume: 248 start-page: 44 year: 2014 ident: 10.1016/j.electacta.2015.09.043_bib0060 article-title: 2-D numerical modeling and experimental investigation of electrochemical mechanisms coupled with heat and mass transfer in a planar direct carbon fuel cell publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2013.09.024 contributor: fullname: Elleuch – volume: 408 start-page: 181 year: 1996 ident: 10.1016/j.electacta.2015.09.043_bib0150 article-title: Water effect on oxygen reduction in molten (Li+K)CO3 eutectic publication-title: J. Electroanal. Chem. doi: 10.1016/0022-0728(96)04514-7 contributor: fullname: Nishina – volume: 45 start-page: 1025 year: 1999 ident: 10.1016/j.electacta.2015.09.043_bib0100 article-title: Molten carbonate fuel cell research: Part I. Comparing cathodic oxygen reduction in lithium/potassium and lithium/sodium carbonate melts publication-title: Electrochim. Acta doi: 10.1016/S0013-4686(99)00305-9 contributor: fullname: Janowitz – volume: 195 start-page: 6988 year: 2010 ident: 10.1016/j.electacta.2015.09.043_bib0055 article-title: Degradation mechanism of molten carbonate fuel cell based on long-term performance: Long-term operation by using bench-scale cell and post-test analysis of the cell publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2010.04.084 contributor: fullname: Morita – volume: 37 start-page: 19417 year: 2012 ident: 10.1016/j.electacta.2015.09.043_bib0050 article-title: State of the art ceria-carbonate composites (3C) electrolyte for advanced low temperature ceramic fuel cells (LTCFCs) publication-title: Int. J. Hydrogen Energy doi: 10.1016/j.ijhydene.2011.09.096 contributor: fullname: Wang – volume: 39 start-page: 1558 year: 2014 ident: 10.1016/j.electacta.2015.09.043_bib0020 article-title: Experimental investigation of CO2 separation from lignite flue gases by 100cm2 single Molten Carbonate Fuel Cell publication-title: Int. J. Hydrogen Energy doi: 10.1016/j.ijhydene.2013.08.144 contributor: fullname: Milewski – volume: 40 start-page: 1927 year: 1995 ident: 10.1016/j.electacta.2015.09.043_bib0125 article-title: Kinetic study of oxygen reduction in molten Li2CO3–Na2CO3 under pressurized conditions publication-title: Electrochim. Acta doi: 10.1016/0013-4686(94)00328-X contributor: fullname: Yamada – volume: 46 start-page: 3023 year: 2001 ident: 10.1016/j.electacta.2015.09.043_bib0105 article-title: Investigation of the oxygen electrode reaction in basic molten carbonates using electrochemical impedance spectroscopy publication-title: Electrochim. Acta doi: 10.1016/S0013-4686(01)00522-9 contributor: fullname: Tomczyk – volume: 38 start-page: 2405 year: 1993 ident: 10.1016/j.electacta.2015.09.043_bib0120 article-title: Kinetic study of oxygen reduction in molten Li2CO3–K2CO3 under pressurized conditions publication-title: Electrochim. Acta doi: 10.1016/0013-4686(93)85109-C contributor: fullname: Yamada – volume: 38 start-page: 497 year: 1972 ident: 10.1016/j.electacta.2015.09.043_bib0065 article-title: Oxygen reduction in carbonate melts: Significance of the peroxide and superoxide ions publication-title: J. Electroanal. Chem doi: 10.1016/0368-1874(72)80161-8 contributor: fullname: Appleby – volume: 138 start-page: 107 year: 2008 ident: 10.1016/j.electacta.2015.09.043_bib0090 article-title: Enhanced O2 solubility by RE2O3 (RE=La, Gd) additions in molten carbonate electrolytes for MCFC publication-title: J. Mol. Liq. doi: 10.1016/j.molliq.2007.09.006 contributor: fullname: Scaccia – volume: 135 start-page: 1124 year: 1988 ident: 10.1016/j.electacta.2015.09.043_bib0175 article-title: The Effect of Oxidant Composition on the Performance of Molten Carbonate Fuel Cells publication-title: J. Electrochem. Soc. doi: 10.1149/1.2095891 contributor: fullname: Kunz – volume: 137 start-page: 2095 year: 1990 ident: 10.1016/j.electacta.2015.09.043_bib0145 article-title: A Computer Simulation of the Oxygen Reduction Reaction in Carbonate Melts publication-title: J. Electrochem. Soc. doi: 10.1149/1.2086891 contributor: fullname: Adanuvor – volume: 4 start-page: 67 year: 2001 ident: 10.1016/j.electacta.2015.09.043_bib0165 article-title: Thermodynamic modeling of mixtures of alkali metal carbonates in equilibrium with reducing gas medium (Н2, СН4, СО, СО2, Н2О) publication-title: Rasplavy contributor: fullname: Nekrasov – volume: 333 start-page: 257 year: 1992 ident: 10.1016/j.electacta.2015.09.043_bib0115 article-title: Electrode kinetics of oxygen reduction on gold in molten carbonate publication-title: J. Electroanal. Chem. doi: 10.1016/0022-0728(92)80395-K contributor: fullname: Lu – volume: 403 start-page: 69 year: 1996 ident: 10.1016/j.electacta.2015.09.043_bib0130 article-title: Factors affecting the dissolution and reduction of oxygen in molten carbonate electrolytes. Part 1: Effect of temperature and alkali carbonate mixture publication-title: J. Electroanal. Chem. doi: 10.1016/0022-0728(95)04190-7 contributor: fullname: Reeve – volume: 1 start-page: 3 year: 2002 ident: 10.1016/j.electacta.2015.09.043_bib0160 article-title: On the possibility to estimate oxide ion equilibrium in mixtures of alkali metal carbonates by methods of molecular thermodynamics publication-title: Elektrokhimicheskaya Energetika contributor: fullname: Nekrasov – volume: 137 start-page: 1125 year: 1990 ident: 10.1016/j.electacta.2015.09.043_bib0170 article-title: Influence of Chemical Equilibria on Oxygen Reduction Reaction in Molten Carbonate publication-title: J. Electrochem. Soc. doi: 10.1149/1.2086614 contributor: fullname: Lu – volume: 37 start-page: 19345 year: 2012 ident: 10.1016/j.electacta.2015.09.043_bib0035 article-title: Strategies and new developments in the field of molten carbonates and high-temperature fuel cells in the carbon cycle publication-title: International Journal of Hydrogen Energy doi: 10.1016/j.ijhydene.2011.11.006 contributor: fullname: Cassir – volume: 39 start-page: 1826 year: 2014 ident: 10.1016/j.electacta.2015.09.043_bib0005 article-title: Optimization of molten carbonate fuel cell (MCFC) and homogeneous charge compression ignition (HCCI) engine hybrid system for distributed power generation publication-title: Int. J. Hydrogen Energy doi: 10.1016/j.ijhydene.2013.11.039 contributor: fullname: Kim – volume: 151 start-page: A1251 year: 2004 ident: 10.1016/j.electacta.2015.09.043_bib0140 article-title: Sensitive Determination of Oxygen Solubility in Alkali Carbonate Melts publication-title: J. Electrochem. Soc. doi: 10.1149/1.1764567 contributor: fullname: Frangini – volume: 43 start-page: 3313 year: 1998 ident: 10.1016/j.electacta.2015.09.043_bib0095 article-title: Study of the (electro) chemical equilibria in molten carbonate under MCFC cathode gas conditions. Part II: non-equilibrium study of (electro) chemical reactions involved in oxygen reduction in molten carbonate publication-title: Electrochim. Acta doi: 10.1016/S0013-4686(98)00070-X contributor: fullname: Peelen – volume: 141 start-page: 1191 year: 1994 ident: 10.1016/j.electacta.2015.09.043_bib0110 article-title: Gas Electrode Reactions in Molten Carbonate Media. Part V. Electrochemical Analysis of the Oxygen Reduction Mechanism at a Fully Immersed Gold Electrode publication-title: J. Electrochem. Soc. doi: 10.1149/1.2054895 contributor: fullname: Nishina – volume: 53 start-page: 105 year: 1974 ident: 10.1016/j.electacta.2015.09.043_bib0070 article-title: The reduction of oxygen in molten lithium carbonate publication-title: J. Electroanal. Chem doi: 10.1016/0022-0728(74)80007-0 contributor: fullname: Appleby – volume: 162 start-page: 750 year: 2006 ident: 10.1016/j.electacta.2015.09.043_bib0030 article-title: The development of a carbon–air semi fuel cell publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2005.07.023 contributor: fullname: Pointon – volume: 353 start-page: 195 year: 1993 ident: 10.1016/j.electacta.2015.09.043_bib0155 article-title: Kinetics of the oxygen electrode reaction in molten Li+Na carbonate eutectic: Part 6. Quantitative analysis of the linear scan voltammetric curves for the first reduction process at monocrystalline NiO electrodes publication-title: J. Electroanal. Chem. doi: 10.1016/0022-0728(93)80296-T contributor: fullname: Bieniasz – volume: 22 start-page: 2168 year: 1983 ident: 10.1016/j.electacta.2015.09.043_bib0075 article-title: Electrochemical studies of molten sodium carbonate publication-title: Inorg. Chem. doi: 10.1021/ic00157a015 contributor: fullname: Dunks – volume: 345 start-page: 110 year: 2009 ident: 10.1016/j.electacta.2015.09.043_bib0040 article-title: Modeling and analysis of carbon dioxide permeation through ceramic-carbonate dual-phase membranes publication-title: J. Membrane Science doi: 10.1016/j.memsci.2009.08.034 contributor: fullname: Rui |
| SSID | ssj0007670 |
| Score | 2.271035 |
| Snippet | A kinetic model of oxygen reduction at an inert electrode in a carbonate melt has been proposed. Combined with the thermodynamic calculations of the chemical... |
| SourceID | crossref elsevier |
| SourceType | Aggregation Database Publisher |
| StartPage | 61 |
| Title | Oxygen reduction on gold electrode in Li2CO3 / K2CO3 (62 / 38mol %) molten electrolyte: experimental and simulation analysis |
| URI | https://dx.doi.org/10.1016/j.electacta.2015.09.043 |
| Volume | 182 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV3db9MwELdK9wA8IBigjS_5ASRQ5ZDEcZ3srZSi8aH2YQPtLXIcB7q1CWq7ikr88Zw_krQwCRBCqiLHqd3I9-vd-XT-HUJPiyAWhQr7RFekIREVERFghwinRdyPM-ZLU0Xh-ISPz-LXo2jU6dSVNdu-_ypp6ANZ65OzfyHtZlLogDbIHK4gdbj-kdwn3zbwrLfQlKzWGyx7n6tZ3nMFb3LDEvJhGg4ntKc5y9-7Fmw6zD2N59UMWkwHDKC50nUA7NjZZmWOsu-UBTCR9-nclQGDW8tyshPyt8Pll6kmJ9D8HY0xGKuLhVhWa5Nv6429JkFos1y57oE3aLunc1FW6-WF2Bivd-J9ap69MpGotT0_5mZy8YyAEZNT1wbZ6oM2bVaTUdwBJVG_Zs22ujrmlNDYEYo3yjzcUseW590Zdlvd5ReTYaMX555ZSb0AOt-PGfJbSyD1Ex_3iX4X_SpgK8AfZmD_90LQclEX7Q3ejs7eNY4A73O_LqChB-ykF175c1c7R1sOz-ltdMvtVPDAQuwO6qhyH10f1gUC99HNLS7Lu-i7BR5ugIfho4GHG-DhaYkt8PBLbGCHn_dDaBvI4WcvsIUb3oLbEd4GGwaw4RZsuAbbPfTxzeh0eExcaQ8iweNfEcUkz7M8VpImMkwUV4nkihWBzECsYFiCjAtfsQx240XCgyQGXRNmQQ5fUTmn9D7qllWpDhBmTARCKF4oKaKkYJmELXwSwWxCxlTwQ-TXa5p-tQwuaZ3aeJ42Yki1GFI_SUEMh-ioXvvUOaLWwUwBNL8b_OBfBj9EN9r_xCPUXS0u1WN0bZlfPnHo-gG-8asK |
| link.rule.ids | 315,782,786,27934,27935 |
| linkProvider | Elsevier |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Oxygen+reduction+on+gold+electrode+in+Li2CO3+%2F+K2CO3+%2862+%2F+38mol+%25%29+molten+electrolyte%3A+experimental+and+simulation+analysis&rft.jtitle=Electrochimica+acta&rft.au=Nekrasov%2C+V.N.&rft.au=Lystsov%2C+A.A.&rft.au=Limanovskaya%2C+O.V.&rft.au=Batalov%2C+N.N.&rft.date=2015-11-10&rft.pub=Elsevier+Ltd&rft.issn=0013-4686&rft.eissn=1873-3859&rft.volume=182&rft.spage=61&rft.epage=66&rft_id=info:doi/10.1016%2Fj.electacta.2015.09.043&rft.externalDocID=S0013468615304552 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0013-4686&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0013-4686&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0013-4686&client=summon |