Enlarged pore size in nanoparticulated bimodal porous silicas: Improving accessibility
Mass-transfer kinetics seems to be highly favored in siliceous materials constructed from the aggregation of mesoporous nanoparticles. Besides intra-particle mesopores, over the course of the aggregation process an inter-particle (textural) large pore system is generated. Diffusion constrains throug...
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| Published in: | Microporous and mesoporous materials Vol. 221; pp. 150 - 158 |
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| Main Authors: | , , , , , , |
| Format: | Journal Article |
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01-02-2016
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| Abstract | Mass-transfer kinetics seems to be highly favored in siliceous materials constructed from the aggregation of mesoporous nanoparticles. Besides intra-particle mesopores, over the course of the aggregation process an inter-particle (textural) large pore system is generated. Diffusion constrains through the resulting hierarchically structured pore systems mainly depend on the characteristics of the intra-particle mesopores. By using alkanes as swelling agents, we have been able to significantly increase the intra-particle mesopore size in previously well characterized UVM-7 materials. The Winsor-III-like behavior associated with the presence of alkanes in the hydro-alcoholic reaction media used in the surfactant-assisted preparative procedure allows explaining the existence of limits to the mesopore size expansion. A preliminary study on enzyme adsorption by these UVM-7-modified solids offers promising results about their capabilities as supports for processing a variety of biomolecules.
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•The intra-particle mesopores in nanoparticulated bimodal porous silicas have been enlarged up to ca. 56%.•We have established the limits for the mesopore expansion on the basis of classical principles of colloid chemistry.•The resulting open architecture leads to an enhanced accessibility for guest species. |
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| AbstractList | Mass-transfer kinetics seems to be highly favored in siliceous materials constructed from the aggregation of mesoporous nanoparticles. Besides intra-particle mesopores, over the course of the aggregation process an inter-particle (textural) large pore system is generated. Diffusion constrains through the resulting hierarchically structured pore systems mainly depend on the characteristics of the intra-particle mesopores. By using alkanes as swelling agents, we have been able to significantly increase the intra-particle mesopore size in previously well characterized UVM-7 materials. The Winsor-III-like behavior associated with the presence of alkanes in the hydro-alcoholic reaction media used in the surfactant-assisted preparative procedure allows explaining the existence of limits to the mesopore size expansion. A preliminary study on enzyme adsorption by these UVM-7-modified solids offers promising results about their capabilities as supports for processing a variety of biomolecules.
[Display omitted]
•The intra-particle mesopores in nanoparticulated bimodal porous silicas have been enlarged up to ca. 56%.•We have established the limits for the mesopore expansion on the basis of classical principles of colloid chemistry.•The resulting open architecture leads to an enhanced accessibility for guest species. |
| Author | Beltrán, Aurelio Guillem, Carmen Tortajada, Marta Mauri-Aucejo, Adela Beltrán, Daniel Moragues, Alaina Amorós, Pedro |
| Author_xml | – sequence: 1 givenname: Alaina orcidid: 0000-0003-4859-1180 surname: Moragues fullname: Moragues, Alaina organization: Institut de Ciència dels Materials (ICMUV), Universitat de València, P. O. Box 22085, 46071 Valencia, Spain – sequence: 2 givenname: Carmen surname: Guillem fullname: Guillem, Carmen organization: Institut de Ciència dels Materials (ICMUV), Universitat de València, P. O. Box 22085, 46071 Valencia, Spain – sequence: 3 givenname: Adela surname: Mauri-Aucejo fullname: Mauri-Aucejo, Adela organization: Departament de Química Analítica, Facultat de Química, Universitat de València, Dr Moliner 50, 46100 Burjassot, València, Spain – sequence: 4 givenname: Marta surname: Tortajada fullname: Tortajada, Marta organization: Biópolis S. L., C/ Catedrático Agustín Escardino 9, 46980 Paterna, Valencia, Spain – sequence: 5 givenname: Aurelio surname: Beltrán fullname: Beltrán, Aurelio organization: Institut de Ciència dels Materials (ICMUV), Universitat de València, P. O. Box 22085, 46071 Valencia, Spain – sequence: 6 givenname: Daniel surname: Beltrán fullname: Beltrán, Daniel organization: Institut de Ciència dels Materials (ICMUV), Universitat de València, P. O. Box 22085, 46071 Valencia, Spain – sequence: 7 givenname: Pedro surname: Amorós fullname: Amorós, Pedro email: pedro.amoros@uv.es organization: Institut de Ciència dels Materials (ICMUV), Universitat de València, P. O. Box 22085, 46071 Valencia, Spain |
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| CitedBy_id | crossref_primary_10_1002_nano_202300169 crossref_primary_10_1016_j_cis_2023_103070 crossref_primary_10_1016_j_jcis_2021_02_069 crossref_primary_10_1080_01496395_2017_1367810 crossref_primary_10_1016_j_scitotenv_2019_135071 crossref_primary_10_3390_molecules24193552 crossref_primary_10_1016_j_fuel_2020_118660 crossref_primary_10_3390_nano8100817 crossref_primary_10_1007_s43207_022_00267_0 |
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| Keywords | Silica nanoparticles Bimodal porosity Template synthesis Mesoporous materials Swelling agents |
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| Title | Enlarged pore size in nanoparticulated bimodal porous silicas: Improving accessibility |
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