Studies of poly(lactic acid) based calcium carbonate nanocomposites

The effect of nano-calcium carbonate on chain linked poly(lactic acid) was investigated. In order to improve inorganic nanofillers/polymer compatibility CaCO3 nanoparticle surface was treated by stearic acid. The nanocomposites were prepared by means of solution blending and further studied by using...

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Published in:Composites. Part B, Engineering Vol. 56; pp. 184 - 188
Main Authors: Kumar, Vimal, Dev, Anshu, Gupta, A.P.
Format: Journal Article
Language:English
Published: Kidlington Elsevier Ltd 01-01-2014
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Abstract The effect of nano-calcium carbonate on chain linked poly(lactic acid) was investigated. In order to improve inorganic nanofillers/polymer compatibility CaCO3 nanoparticle surface was treated by stearic acid. The nanocomposites were prepared by means of solution blending and further studied by using dynamic mechanical analysis, fourier transform infrared spectroscopy, scanning electron microscopy and thermogravimetric analysis. Morphological analysis performed on nanocomposites fractured surfaces has revealed that the CaCO3 modification induces homogeneous and fine dispersion of nanoparticles into polymer as well as strong interfacial adhesion between the two phases. An increase in the Tg and storage modulus of the resulting nanocomposites was observed with the increase of calcium carbonate ratio. Thermogravimetric results showed a lower degradation temperature with the increase of calciium carbonate ration in the polymer matrix.
AbstractList The effect of nano-calcium carbonate on chain linked poly(lactic acid) was investigated. In order to improve inorganic nanofillers/polymer compatibility CaCO3 nanoparticle surface was treated by stearic acid. The nanocomposites were prepared by means of solution blending and further studied by using dynamic mechanical analysis, fourier transform infrared spectroscopy, scanning electron microscopy and thermogravimetric analysis. Morphological analysis performed on nanocomposites fractured surfaces has revealed that the CaCO3 modification induces homogeneous and fine dispersion of nanoparticles into polymer as well as strong interfacial adhesion between the two phases. An increase in the Tg and storage modulus of the resulting nanocomposites was observed with the increase of calcium carbonate ratio. Thermogravimetric results showed a lower degradation temperature with the increase of calciium carbonate ration in the polymer matrix.
Author Gupta, A.P.
Kumar, Vimal
Dev, Anshu
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Keywords D. Thermal analysis
A. Polymer–matrix composites (PMCs)
A. Particle-reinforcement
D. Electron microscopy
Storage modulus
Dispersion degree
A. Polymer―matrix composites (PMCs)
Dispersion reinforced material
Experimental study
Composite material
Thermal stability
Surface treatment
Thermal properties
Lactic acid polymer
Morphology
Aliphatic polymer
Calcium carbonate
Concentration effect
Nanocomposite
Stearic acid
Rheological properties
Language English
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Snippet The effect of nano-calcium carbonate on chain linked poly(lactic acid) was investigated. In order to improve inorganic nanofillers/polymer compatibility CaCO3...
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SubjectTerms A. Particle-reinforcement
A. Polymer–matrix composites (PMCs)
Applied sciences
Composites
D. Electron microscopy
D. Thermal analysis
Exact sciences and technology
Forms of application and semi-finished materials
Polymer industry, paints, wood
Technology of polymers
Title Studies of poly(lactic acid) based calcium carbonate nanocomposites
URI https://dx.doi.org/10.1016/j.compositesb.2013.08.021
Volume 56
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