Structural and luminescence properties of Eu-doped ZnO nanorods fabricated by a microemulsion method
We have studied photoluminescence (PL) properties of Eu-doped ZnO (ZnO:Eu) nanorods fabricated by a microemulsion method. The ZnO:Eu nanorods have a hexagonal crystal structure and exhibit a sharp luminescence due to the intra- 4 f transitions of Eu 3 + ions. The excitation energy and temperature de...
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Published in: | Applied physics letters Vol. 86; no. 25; pp. 253106 - 253106-3 |
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Language: | English |
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American Institute of Physics
20-06-2005
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Abstract | We have studied photoluminescence (PL) properties of Eu-doped ZnO (ZnO:Eu) nanorods fabricated by a microemulsion method. The ZnO:Eu nanorods have a hexagonal crystal structure and exhibit a sharp luminescence due to the intra-
4
f
transitions of
Eu
3
+
ions. The excitation energy and temperature dependence of the PL intensity show that the
Eu
3
+
-related PL efficiency is determined by the energy relaxation process of excited
Eu
3
+
ions, rather than by the energy transfer process from ZnO nanorods to
Eu
3
+
ions. The energy transfer and luminescence processes in ZnO:Eu nanorods are discussed. |
---|---|
AbstractList | We have studied photoluminescence (PL) properties of Eu-doped ZnO (ZnO:Eu) nanorods fabricated by a microemulsion method. The ZnO:Eu nanorods have a hexagonal crystal structure and exhibit a sharp luminescence due to the intra-
4
f
transitions of
Eu
3
+
ions. The excitation energy and temperature dependence of the PL intensity show that the
Eu
3
+
-related PL efficiency is determined by the energy relaxation process of excited
Eu
3
+
ions, rather than by the energy transfer process from ZnO nanorods to
Eu
3
+
ions. The energy transfer and luminescence processes in ZnO:Eu nanorods are discussed. We have studied photoluminescence (PL) properties of Eu-doped ZnO (ZnO:Eu) nanorods fabricated by a microemulsion method. The ZnO:Eu nanorods have a hexagonal crystal structure and exhibit a sharp luminescence due to the intra-4f transitions of Eu3+ ions. The excitation energy and temperature dependence of the PL intensity show that the Eu3+-related PL efficiency is determined by the energy relaxation process of excited Eu3+ ions, rather than by the energy transfer process from ZnO nanorods to Eu3+ ions. The energy transfer and luminescence processes in ZnO:Eu nanorods are discussed. |
Author | Ishizumi, Atsushi Kanemitsu, Yoshihiko |
Author_xml | – sequence: 1 givenname: Atsushi surname: Ishizumi fullname: Ishizumi, Atsushi organization: Graduate School of Materials Science, Nara Institute of Science and Technology, Ikoma, Nara 630-0192, Japan – sequence: 2 givenname: Yoshihiko surname: Kanemitsu fullname: Kanemitsu, Yoshihiko email: kanemitu@scl.kyoto-u.ac.jp organization: International Research Center for Elements Science, Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan |
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