Facile obtaining of Iridium(0), Platinum(0) and Platinum(0)-Iridium(0) alloy nanoparticles and the catalytic reduction of 4-nitrophenol
The obtaining of Pt(0), Ir(0), and Pt(0)-Ir(0) nanoparticles (NPs) is accomplished using readily available metallic precursors through their reduction with NaBH4 in solid state. Byproducts are removed by water/acetone washes and the influence of a final heat treatment step whether using air or nitro...
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Published in: | Materials chemistry and physics Vol. 201; pp. 289 - 296 |
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Abstract | The obtaining of Pt(0), Ir(0), and Pt(0)-Ir(0) nanoparticles (NPs) is accomplished using readily available metallic precursors through their reduction with NaBH4 in solid state. Byproducts are removed by water/acetone washes and the influence of a final heat treatment step whether using air or nitrogen is compared with untreated samples. Characterization by PXRD shows NPs with diameters >10 nm and satisfactory results for unheated samples. Further analysis by XPS, TEM, and catalytic reduction of 4-nitrophenol provides evidence to confirm the presence of zero-valent NPs and the formation of an alloy in the Pt(0)-Ir(0).
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•Pt(0), Ir(0), and Pt(0)-Ir(0) alloy NPs are readily obtained in a solventless and aerobic process at room temperature.•XRD and TEM analysis demonstrate nanometric size particles with crystalline structure.•XPS studies show energy shifts attributable to the formation of a Pt(0)-Ir(0) alloy.•Specific reactivity on 4-nitrophenol reduction allows determining characteristic features for the synthesized NPs. |
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AbstractList | The obtaining of Pt(0), Ir(0), and Pt(0)-Ir(0) nanoparticles (NPs) is accomplished using readily available metallic precursors through their reduction with NaBH4 in solid state. Byproducts are removed by water/acetone washes and the influence of a final heat treatment step whether using air or nitrogen is compared with untreated samples. Characterization by PXRD shows NPs with diameters >10 nm and satisfactory results for unheated samples. Further analysis by XPS, TEM, and catalytic reduction of 4-nitrophenol provides evidence to confirm the presence of zero-valent NPs and the formation of an alloy in the Pt(0)-Ir(0). The obtaining of Pt(0), Ir(0), and Pt(0)-Ir(0) nanoparticles (NPs) is accomplished using readily available metallic precursors through their reduction with NaBH4 in solid state. Byproducts are removed by water/acetone washes and the influence of a final heat treatment step whether using air or nitrogen is compared with untreated samples. Characterization by PXRD shows NPs with diameters >10 nm and satisfactory results for unheated samples. Further analysis by XPS, TEM, and catalytic reduction of 4-nitrophenol provides evidence to confirm the presence of zero-valent NPs and the formation of an alloy in the Pt(0)-Ir(0). [Display omitted] •Pt(0), Ir(0), and Pt(0)-Ir(0) alloy NPs are readily obtained in a solventless and aerobic process at room temperature.•XRD and TEM analysis demonstrate nanometric size particles with crystalline structure.•XPS studies show energy shifts attributable to the formation of a Pt(0)-Ir(0) alloy.•Specific reactivity on 4-nitrophenol reduction allows determining characteristic features for the synthesized NPs. |
Author | Herrera-Gomez, Alberto Fernandez-Osorio, Ana-Leticia Gomez-Sosa, Gustavo Redón, Rocío Ramírez-Crescencio, Fermín Bravo-Sanchez, Mariela |
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Snippet | The obtaining of Pt(0), Ir(0), and Pt(0)-Ir(0) nanoparticles (NPs) is accomplished using readily available metallic precursors through their reduction with... |
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SubjectTerms | 4-nitrophenol reduction Acetone Alloys Catalysis Heat treatment Iridium base alloys Metallic nanoparticles Nanoparticles Nitrophenol Platinum Platinum base alloys PtIr alloy nanoparticles Solid state physics X ray photoelectron spectroscopy |
Title | Facile obtaining of Iridium(0), Platinum(0) and Platinum(0)-Iridium(0) alloy nanoparticles and the catalytic reduction of 4-nitrophenol |
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