Facile obtaining of Iridium(0), Platinum(0) and Platinum(0)-Iridium(0) alloy nanoparticles and the catalytic reduction of 4-nitrophenol

The obtaining of Pt(0), Ir(0), and Pt(0)-Ir(0) nanoparticles (NPs) is accomplished using readily available metallic precursors through their reduction with NaBH4 in solid state. Byproducts are removed by water/acetone washes and the influence of a final heat treatment step whether using air or nitro...

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Published in:Materials chemistry and physics Vol. 201; pp. 289 - 296
Main Authors: Ramírez-Crescencio, Fermín, Redón, Rocío, Herrera-Gomez, Alberto, Gomez-Sosa, Gustavo, Bravo-Sanchez, Mariela, Fernandez-Osorio, Ana-Leticia
Format: Journal Article
Language:English
Published: Lausanne Elsevier B.V 01-11-2017
Elsevier BV
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Abstract The obtaining of Pt(0), Ir(0), and Pt(0)-Ir(0) nanoparticles (NPs) is accomplished using readily available metallic precursors through their reduction with NaBH4 in solid state. Byproducts are removed by water/acetone washes and the influence of a final heat treatment step whether using air or nitrogen is compared with untreated samples. Characterization by PXRD shows NPs with diameters >10 nm and satisfactory results for unheated samples. Further analysis by XPS, TEM, and catalytic reduction of 4-nitrophenol provides evidence to confirm the presence of zero-valent NPs and the formation of an alloy in the Pt(0)-Ir(0). [Display omitted] •Pt(0), Ir(0), and Pt(0)-Ir(0) alloy NPs are readily obtained in a solventless and aerobic process at room temperature.•XRD and TEM analysis demonstrate nanometric size particles with crystalline structure.•XPS studies show energy shifts attributable to the formation of a Pt(0)-Ir(0) alloy.•Specific reactivity on 4-nitrophenol reduction allows determining characteristic features for the synthesized NPs.
AbstractList The obtaining of Pt(0), Ir(0), and Pt(0)-Ir(0) nanoparticles (NPs) is accomplished using readily available metallic precursors through their reduction with NaBH4 in solid state. Byproducts are removed by water/acetone washes and the influence of a final heat treatment step whether using air or nitrogen is compared with untreated samples. Characterization by PXRD shows NPs with diameters >10 nm and satisfactory results for unheated samples. Further analysis by XPS, TEM, and catalytic reduction of 4-nitrophenol provides evidence to confirm the presence of zero-valent NPs and the formation of an alloy in the Pt(0)-Ir(0).
The obtaining of Pt(0), Ir(0), and Pt(0)-Ir(0) nanoparticles (NPs) is accomplished using readily available metallic precursors through their reduction with NaBH4 in solid state. Byproducts are removed by water/acetone washes and the influence of a final heat treatment step whether using air or nitrogen is compared with untreated samples. Characterization by PXRD shows NPs with diameters >10 nm and satisfactory results for unheated samples. Further analysis by XPS, TEM, and catalytic reduction of 4-nitrophenol provides evidence to confirm the presence of zero-valent NPs and the formation of an alloy in the Pt(0)-Ir(0). [Display omitted] •Pt(0), Ir(0), and Pt(0)-Ir(0) alloy NPs are readily obtained in a solventless and aerobic process at room temperature.•XRD and TEM analysis demonstrate nanometric size particles with crystalline structure.•XPS studies show energy shifts attributable to the formation of a Pt(0)-Ir(0) alloy.•Specific reactivity on 4-nitrophenol reduction allows determining characteristic features for the synthesized NPs.
Author Herrera-Gomez, Alberto
Fernandez-Osorio, Ana-Leticia
Gomez-Sosa, Gustavo
Redón, Rocío
Ramírez-Crescencio, Fermín
Bravo-Sanchez, Mariela
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  givenname: Ana-Leticia
  surname: Fernandez-Osorio
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Keywords Metallic nanoparticles
PtIr alloy nanoparticles
4-nitrophenol reduction
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    fullname: Zeng
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Snippet The obtaining of Pt(0), Ir(0), and Pt(0)-Ir(0) nanoparticles (NPs) is accomplished using readily available metallic precursors through their reduction with...
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SubjectTerms 4-nitrophenol reduction
Acetone
Alloys
Catalysis
Heat treatment
Iridium base alloys
Metallic nanoparticles
Nanoparticles
Nitrophenol
Platinum
Platinum base alloys
PtIr alloy nanoparticles
Solid state physics
X ray photoelectron spectroscopy
Title Facile obtaining of Iridium(0), Platinum(0) and Platinum(0)-Iridium(0) alloy nanoparticles and the catalytic reduction of 4-nitrophenol
URI https://dx.doi.org/10.1016/j.matchemphys.2017.08.006
https://www.proquest.com/docview/1968402554
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