Conformation of diethylglyoxime in uranyl complexes

• Published in: Russian journal of inorganic chemistry Vol. 61; no. 12; pp. 1522 - 1529
• Main Authors: Beirakhov, A. G., Orlova, I. M., Rotov, A. V., Il’in, E. G., Goeva, L. V., Surazhskaya, M. D., Churakov, A. V., Mikhailov, Yu. N.
• Format: Journal Article
• Language: English
• Published: Moscow Pleiades Publishing 01-12-2016; Springer Nature B.V
• Subjects: Bridging; Chemistry; Chemistry and Materials Science; Coordination Compounds; Inorganic Chemistry; Ligands; Synthesis; Uranium dioxide; X ray diffraction
• ISSN: 0036-0236; 1531-8613
• DOI: 10.1134/S0036023616120032

New complexes of uranyl with diethylglyoxime have been synthesized and studied. A feature of these complexes is the tetradentate bridging coordination of the ligand in both
cis
- and
trans
-conformations. The structure of organic ligand C
6
H
12
N
2
O
2
and binuclear complex (CN
3
H
6
)
4
[(UO
2
)
2
(C
6
H
10
N
2
O
2
)(CO
3
)(C
2
O
4
)
2
] ∙ H
2
O have been determined by X-ray diffraction.