Synthesis and Stereoselective Functionalization of Sulfur-Containing Silyl Heterocycles

Synthesis and Stereoselective Functionalization of Sulfur-Containing Silyl Heterocycles

2-Silylated five-membered heterocycles can be easily accessed through reaction of bromo(methoxy)methylsilane and dithiols, mercapto amines, and mercapto alcohols. Further reaction of the obtained silylated heterocycles with electrophiles under fluoride ion conditions afford an easy functionalization...

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Bibliographic Details
Published in:Phosphorus, sulfur, and silicon and the related elements Vol. 180; no. 5-6; pp. 1297 - 1302
Main Authors: Degl'Innocenti, Alessandro, Capperucci, Antonella, Castagnoli, Giulio, Malesci, Irene, Nocentini, Tiziano
Format: Journal Article
Language:English
Published: Taylor & Francis Group 01-05-2005
Subjects:
Fluoride ion
organosilanes
stereoselectivity
thiaheterocycles
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Summary:2-Silylated five-membered heterocycles can be easily accessed through reaction of bromo(methoxy)methylsilane and dithiols, mercapto amines, and mercapto alcohols. Further reaction of the obtained silylated heterocycles with electrophiles under fluoride ion conditions afford an easy functionalization of such molecules.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426500590912222